公开(公告)号：PT97218B

公开(公告)日：1998-07-31

申请号：PT9721891

申请日：1991-04-01

Applicant: BASF AG

Inventor： BRUECKMANN RALF ,  SCHOEPKE HOLGER ,  WIRTH THOMAS ,  HARTMANN JUERGEN

IPC: C08F2/08 ,  C08F2/06 ,  C08F2/24 ,  C08F2/30 ,  C08F2/44 ,  C08F220/10 ,  C08F220/12 ,  C08F261/04 ,  C08L33/06 ,  C09D151/00 ,  D06M15/263 ,  D06M15/333

Abstract: Copolymers suitable for use as temporary surface protection for two- or three-dimensional structures and as sizing agents are based on C1-C8-alkyl acrylates and/or methacrylates and are obtainable by free radical emulsion or solution polymerization of A) from 50 to 95% by weight of a C1-C8-alkyl acrylate or methacrylate, B) from 5 to 20% by weight of an unsaturated carboxylic acid or anhydride, C) from 0 to 20% by weight of further water-soluble comonomer, and D) from 0 to 10% by weight of other comonomer in the presence of E) from 2 to 60 parts by weight of a polyvinyl alcohol per 100 parts by weight of the monomer mixture of A) to D).

公开(公告)号：AU679836B2

公开(公告)日：1997-07-10

申请号：AU1575595

申请日：1995-01-23

Applicant: BASF AG

Inventor： LEUBE HARTMANN F ,  WIRTH THOMAS ,  LAWRENZ DIRK

IPC: C08F257/02 ,  C08F265/00 ,  C08F265/04 ,  C08F265/06 ,  C09J151/00 ,  D21H17/34 ,  D21H19/20 ,  D21H19/58

Abstract: PCT No. PCT/EP95/00224 Sec. 371 Date Aug. 5, 1996 Sec. 102(e) Date Aug. 5, 1996 PCT Filed Jan. 23, 1995 PCT Pub. No. WO95/21294 PCT Pub. Date Aug. 10, 1995Binders for papercoating slips which permit uniform printability contain a polymer prepared by the seed procedure and comprising from 1 to 49% by weight of a polymer seed A) having a glass transition temperature of from -80 DEG to +25 DEG C. and based on esters of acrylic acid or methacrylic acid, and from 51 to 99% by weight of ethylenically unsaturated monomers B), from 10 to 100% by weight of which monomers are butadiene, the polymer seed A being added before or during the polymerization of the ethylenically unsaturated monomers.

公开(公告)号：FI961679A

公开(公告)日：1996-04-17

申请号：FI961679

申请日：1996-04-17

Applicant: BASF AG

Inventor： WIRTH THOMAS ,  NISSLER HARALD ,  STURM BERTHOLD ,  LAWRENZ DIRK ,  SCHULER BERNHARD

IPC: C09D109/00 ,  C09D109/10 ,  C09D113/02 ,  C09D121/00 ,  C09D133/04 ,  C09D133/06 ,  D21H19/44 ,  D21H19/58 ,  D21H ,  C08L

Abstract: PCT No. PCT/EP94/02034 Sec. 371 Date Mar. 29, 1996 Sec. 102(e) Date Mar. 29, 1996 PCT Filed Jun. 22, 1994 PCT Pub. No. WO95/11342 PCT Pub. Date Apr. 27, 1995Papers which are coated with a paper coating slip based on a binder containing A) from 1 to 49% by weight of polymers based on esters of acrylic acid or of methacrylic acid with a C4-C12-alkanol, having a glass transition temperature of from -80 DEG to +25 DEG C., and B) from 51 to 99% by weight of polymers based on butadiene, the stated weights being based on the sum A)+B), are used for offset printing.

公开(公告)号：AU1575595A

公开(公告)日：1995-08-21

申请号：AU1575595

申请日：1995-01-23

Applicant: BASF AG

Inventor： LEUBE HARTMANN F ,  WIRTH THOMAS ,  LAWRENZ DIRK

IPC: C08F257/02 ,  C08F265/00 ,  C08F265/04 ,  C08F265/06 ,  C09J151/00 ,  D21H17/34 ,  D21H19/20 ,  D21H19/58

Abstract: PCT No. PCT/EP95/00224 Sec. 371 Date Aug. 5, 1996 Sec. 102(e) Date Aug. 5, 1996 PCT Filed Jan. 23, 1995 PCT Pub. No. WO95/21294 PCT Pub. Date Aug. 10, 1995Binders for papercoating slips which permit uniform printability contain a polymer prepared by the seed procedure and comprising from 1 to 49% by weight of a polymer seed A) having a glass transition temperature of from -80 DEG to +25 DEG C. and based on esters of acrylic acid or methacrylic acid, and from 51 to 99% by weight of ethylenically unsaturated monomers B), from 10 to 100% by weight of which monomers are butadiene, the polymer seed A being added before or during the polymerization of the ethylenically unsaturated monomers.

公开(公告)号：CA2461948C

公开(公告)日：2011-03-15

申请号：CA2461948

申请日：2002-09-30

Applicant: BASF AG

Inventor： GASCHLER WOLFGANG ,  SCHAEDLER VOLKER ,  MANDERS LAMBERTUS ,  WIRTH THOMAS ,  KROENER HUBERTUS

IPC: C08F212/08 ,  C08F2/38 ,  C08F220/04 ,  C08F220/44 ,  C08F236/06 ,  C08F236/10 ,  C08F291/00 ,  C09D5/02 ,  C09D109/06 ,  C09D109/08 ,  C09D125/10 ,  D21H17/35 ,  D21H19/58

Abstract: The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by means of radical aqueous emulsion polymerisation of a monomer mixture M containing styrene, butadiene, and optionally up to 30 wt. %, in relation to 100 wt. % of monomers, of ethylenically unsaturated comonomers other than styrene and butadiene. The reaction is carried out in a polymerisation vessel according to a monomer supply method, in the presence of a regulator system comprising, in relation to 100 wt. % of monomers, between 0.02 and 0.5 wt. % of at least one hydrocarbon KW having between 6 and 20 C atoms and being selected from compounds forming a pentadienyl radical or a 1-phenylallyl radical by means of abstraction of a hydrocarbon atom, an .alpha.-methylstyrene dimer, and between 0.3 and 2 wt. % of an organic compound S with at least one SH group. The inventive method is characterised in that at least 30 %, preferably at least 50 %, especially at least 80 %, and ideally the entire amount (or more than 95 %) of the hydrocarbon KW is present in the polymerisation vessel.

公开(公告)号：CA2461672C

公开(公告)日：2011-03-15

申请号：CA2461672

申请日：2002-09-30

Applicant: BASF AG

Inventor： MANDERS LAMBERTUS ,  WIRTH THOMAS ,  GASCHLER WOLFGANG ,  KROENER HUBERTUS

IPC: C08F212/08 ,  C08F2/38 ,  C08F236/06

Abstract: The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by carrying out a radical aqueous emulsion polymerization of a monomer mixture M containing: 40 to 80 wt. % of styrene depicted as Monomer M1; 20 to 60 wt. % of butadiene depicted as monomer M2, and; 0 to 40 wt. %, with regard to 100 wt. % of the monomers, of ethylenically unsaturated comonomers M3 that differ from styrene and butadiene. The polymerization is carried out according to a monomer feeding method in the presence of 0.05 to 0.5 wt. %, with regard to 100 wt. % of the monomers, of at least one hydrocarbon KW selected among compounds having 6 to 20 C atoms that form a pentadienyl radical or a 1-phenylallyl radical when a hydrogen atom is abstracted, and the .alpha.-methylstyrene dimer. The inventive method is characterized in that the monomers to be polymerized are introduced within three hours of the polymerization reaction.

公开(公告)号：CA2357510C

公开(公告)日：2010-04-06

申请号：CA2357510

申请日：2001-09-20

Applicant: BASF AG

Inventor： SCHADLER VOLKER ,  MANDERS LAMBERTUS ,  ETTL ROLAND ,  WIRTH THOMAS

IPC: C08F212/08 ,  C08F2/22 ,  C08F2/38 ,  C08F212/10 ,  C08F236/10 ,  D21H17/35 ,  D21H19/36 ,  D21H19/58

Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M comprising - styrene, - butadiene, and if desired - up to 30% by weight, per 100% by weight of monomers, of ethylenically unsaturated comonomers other than styrene and butadiene; by a monomer feed technique, said process comprising supplying to the polymerization reaction in the course thereof a regulator system comprising, based on 100% by weight of monomers, - from 0.02 to 0.4% by weight of terpinolene and - from 0.5 to 2% by weight of an organic compound S containing at least one SH group.

公开(公告)号：AT327266T

公开(公告)日：2006-06-15

申请号：AT02777269

申请日：2002-09-30

Applicant: BASF AG

Inventor： MANDERS LAMBERTUS ,  WIRTH THOMAS ,  GASCHLER WOLFGANG ,  KROENER HUBERTUS

IPC: C08F2/38 ,  C08F212/08 ,  C08F236/06

Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC selected from compounds having 6 to 20 carbon atoms which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and from alpha-methylstyrene dimer comprises supplying the monomers to be polymerized to the polymerization reaction over the course of 3 hours.

公开(公告)号：CA2174233C

公开(公告)日：2004-03-30

申请号：CA2174233

申请日：1994-06-22

Applicant: BASF AG

Inventor： WIRTH THOMAS ,  NISSLER HARALD ,  STURM BERTHOLD ,  LAWRENZ DIRK ,  SCHULER BERNHARD

IPC: C09D109/00 ,  C09D109/10 ,  C09D113/02 ,  C09D121/00 ,  C09D133/04 ,  C09D133/06 ,  D21H19/44 ,  D21H19/58 ,  B41M1/36

Abstract: The invention concerns the use, for offset printing, of paper coated with a binder-based coating compound containing A) 1 to 49 % by wt. of polymers mad e from esters of acrylic or methacrylic acid with C4-C12 alkanols and having a glass transition temperature of -80 to +25 ~C, and B) 51 to 99 % by wt. of butadiene polymers, the weights being relative to the total of A and B.

公开(公告)号：CA2461947A1

公开(公告)日：2003-04-10

申请号：CA2461947

申请日：2002-09-30

Applicant: BASF AG

Inventor： SCHAEDLER VOLKER ,  GASCHLER WOLFGANG ,  MANDERS LAMBERTUS ,  KROENER HUBERTUS ,  WIRTH THOMAS

IPC: C08F2/22 ,  C08F2/38 ,  C08F212/00 ,  C08F212/08 ,  C08F236/00 ,  C08F236/10 ,  C08F291/00 ,  C08F236/06

Abstract: The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by the radical aqueous emulsion-polymerisation of a monom er mixture M, containing: between 40 and 80 wt. % styrene as monomer M1; betwee n 20 and 60 wt. % butadiene as monomer M2 and between 0 and 40 wt. %, (in relation to l00 wt. % monomers), of ethylenically unsaturated comonomers M3 that differ from styrene and butadiene, according to a monomer feed process in the presence of between 0.05 and 0.5 wt. %, (in relation to l00 wt. % monomers), of at least one hydrocarbon KW comprising between 6 and 20 C atom s, selected from compounds, which form a pentadienyl or a 1-phenylallyl radical during the abstraction of a hydrogen atom, or from .alpha.-methylstyrene dimers. Said method is characterised in that at least 30 % of the hydrocarbo n KW is already present in the polymerisation vessel and the residual quantity of the hydrocarbon KW is fed to the polymerisation reaction during the cours e of the latter.