公开(公告)号：ES2093963T3

公开(公告)日：1997-01-01

申请号：ES93908869

申请日：1993-04-01

Applicant: BASF AG

Inventor： WOLF GERHARD ,  OFTRING ALFRED ,  SCHUH GEORG ,  WOLF HELMUT ,  ALT RUDOLF ,  BECHTOLSHEIMER HANS-HEINRICH

IPC: C07H15/04

Abstract: PCT No. PCT/EP93/00791 Sec. 371 Date Sep. 15, 1994 Sec. 102(e) Date Sep. 15, 1994 PCT Filed Apr. 1, 1993 PCT Pub. No. WO93/21196 PCT Pub. Date Oct. 28, 1993The preparation of alkyl glycosides by reaction of aqueous glycoses having a water content of 10-80% by weight with aliphatic primary alcohols having from 5 to 30 C atoms is described, in which (a) the alcohols and the glycoses are employed in a molar ratio of 2:1 to 10:1, (b) 0.1-5% by weight, based on the amount of the glycoses employed, of the acidic form of an anionic surfactant is used as the acidic catalyst having emulsifying properties, (c) 1-30% by weight, based on the amount of the glycoses employed, of alkyl glycosides is used as a further emulsifier, (d) the aqueous glycose is preheated to 50 DEG -90 DEG C. and the preheated aqueous solution of the glycose is metered with effective mixing into the reaction mixture of alcohol, acidic catalyst and emulsifier in such a manner that an emulsion is formed, (e) the reaction is carried out at from 100 DEG to 150 DEG C. and from 10 to 100 mbar, the water introduced into the reaction mixture and the water formed by the reaction being continuously removed by distillation, (f) after the reaction has ended, the acidic catalyst is neutralized by addition of a base such that the resulting mixture has a pH of 8-10, then (g) the excess alcohol is removed by distillation at from 0.01 to 10 mbar down to a residual content of less than 5% by weight, based on the amount of alkyl glycoside present, and (h) the reaction mixture is bleached at pH 8-10 after conversion into an aqueous paste having a content of from 30 to 70% by weight of alkyl glycoside using a compound eliminating active oxygen.

公开(公告)号：DE4235783A1

公开(公告)日：1994-04-28

申请号：DE4235783

申请日：1992-10-23

Applicant: BASF AG

Inventor： STRECKER BEATE DR ,  WOLF HELMUT ,  WOLF GERHARD DR ,  OFTRING ALFRED DR ,  BECHTOLSHEIMER HANS-HEINRICH D ,  HERTEL DIETER

IPC: C07C231/02 ,  C07C233/18 ,  C07H5/06

Abstract: N-alkanoyl-polyhydroxyalkylamines having the formula (I), in which Z stands for the polyhydroxyalkyl residue of a mono- or oligo saccharide; R stands for hydrogen or C1-C8-alkyl and R stands for C1-C21-alkyl are prepared by reaction of polyhydroxyalkylamines having the formula (II): Z-NH-R , with carboxylic acid alkyl esters having the formula (III), in which R stands for a C1-C4-alkyl residue, in the presence of a basic catalyst. For that purpose, (a) the total amount of the ester (III) is taken, is heated up to the reaction temperature and the amine (II) is precisely added thereto as a molten mass while the reaction is in progress, the resulting alcohol represented by the formula R -OH being continuously distilled away; (b) the reaction is carried out at a temperature from 55 to 110 DEG C; and (c) the reaction is carried out in the absence of organic solvents.

公开(公告)号：CA2124071A1

公开(公告)日：1993-10-28

申请号：CA2124071

申请日：1993-04-01

Applicant: BASF AG

Inventor： WOLF GERHARD ,  OFTRING ALFRED ,  SCHUH GEORG ,  WOLF HELMUT ,  ALT RUDOLF ,  BECHTOLSHEIMER HANS-HEINRICH ,  HERTEL DIETER

IPC: C07H15/04

Abstract: The preparation of alkyl glycosides by reaction of aqueous glycoses having a water content of 10 - 80% by weight with aliphatic primary alcohols having from 5 to 30 C atoms is described, in which (a) the alcohols and the glycoses are employed in a molar ratio of 2:1 to 10:1, (b) 0.1 - 5% by weight, based on the amount of the glycoses employed, of the acidic form of an anionic surfactant is used as the acidic catalyst having emulsifying properties, (c) 1 - 30% by weight, based on the amount of the glycoses employed, of alkyl glycosides is used as a further emulsifier, (d) the aqueous glycose is preheated to 50 - 90.degree.C and the preheated aqueous solution of the glycose is metered with effective mixing into the reaction mixture of alcohol, acidic catalyst and emulsifier in such a manner that an emulsion is formed, (e) the reaction is carried out at from 100 to 150.degree.C and from 10 to 100 mbar, the water introduced into the reaction mixture and the water formed by the reaction being continuously removed by distillation, (f) after the reaction has ended, the acidic catalyst is neutralized by addition of a base such that the resulting mixture has a pH of 8 - 10, then (g) the excess alcohol is removed by distillation at from 0.01 to 10 mbar down to a residual content of less than 5% by weight, based on the amount of alkyl glycoside present, and (h) the reaction mixture is bleached at pH 8 - 10 after conversion into an aqueous paste having a content of from 30 to 70% by weight of alkyl glycoside using a compound eliminating active oxygen.

公开(公告)号：DE3361231D1

公开(公告)日：1985-12-19

申请号：DE3361231

申请日：1983-08-11

Applicant: BASF AG

Inventor： LORENZ KLAUS DR ,  BALZER WOLF-DIETER DR ,  WOLF HELMUT ,  TRIESELT WOLFGANG DR ,  BUSSE GERD

IPC: C07H15/04

Abstract: Alkylglucosides are prepared by acetalization of glucose with an equivalent amount or an excess of a C3-C5-alkanol in the presence of an acidic catalyst by a method wherein the acetalization is carried out in the presence of an alkali metal salt of a boric acid used in an amount which is equivalent to or in excess of the amount of the catalyst. The alkylglucosides obtained can be used directly, for example as solubilizers, in particular in the cosmetic sector, or can be reacted further to give higher alkylglucosides.

公开(公告)号：DE1669739A1

公开(公告)日：1971-06-16

申请号：DE1669739

申请日：1967-11-10

Applicant: BASF AG

Inventor： MEYER FERDINAND DR ,  SCHWECKENDIEK WALTER DR ,  WOLF HELMUT

IPC: C08J3/21 ,  C08G37/28