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公开(公告)号:DE4235783A1
公开(公告)日:1994-04-28
申请号:DE4235783
申请日:1992-10-23
Applicant: BASF AG
Inventor: STRECKER BEATE DR , WOLF HELMUT , WOLF GERHARD DR , OFTRING ALFRED DR , BECHTOLSHEIMER HANS-HEINRICH D , HERTEL DIETER
IPC: C07C231/02 , C07C233/18 , C07H5/06
Abstract: N-alkanoyl-polyhydroxyalkylamines having the formula (I), in which Z stands for the polyhydroxyalkyl residue of a mono- or oligo saccharide; R stands for hydrogen or C1-C8-alkyl and R stands for C1-C21-alkyl are prepared by reaction of polyhydroxyalkylamines having the formula (II): Z-NH-R , with carboxylic acid alkyl esters having the formula (III), in which R stands for a C1-C4-alkyl residue, in the presence of a basic catalyst. For that purpose, (a) the total amount of the ester (III) is taken, is heated up to the reaction temperature and the amine (II) is precisely added thereto as a molten mass while the reaction is in progress, the resulting alcohol represented by the formula R -OH being continuously distilled away; (b) the reaction is carried out at a temperature from 55 to 110 DEG C; and (c) the reaction is carried out in the absence of organic solvents.
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公开(公告)号:DE4404728A1
公开(公告)日:1995-08-17
申请号:DE4404728
申请日:1994-02-16
Applicant: BASF AG
Inventor: OFTRING ALFRED DR , STRECKER BEATE DR , OETTER GUENTER DR , SCHMIDT RICHARD PROF DR , KLOTZ WOLFGANG , WULFF HENDRIK
IPC: A01N43/04 , A61K8/00 , A61K8/60 , A61K31/70 , A61Q5/02 , A61Q19/00 , A61Q19/10 , C07H15/04 , C11D1/16 , C11D1/66 , C11D1/68 , A61K7/50 , A61K7/075
Abstract: 1-(2'-hydroxy- and 2'-sulphatoalkyl)glycosides have the formula (I), in which X stands for a hydroxyl or sulphate group having the formula OSO3M, in which M stands for hydrogen, an alkali metal or ammonium cation that may be substituted by organic rests; R stands for a C6 to C30 alkyl or alkylene rest; and Gly stands for the rest of a monosaccharide acetalised in position 1 by the above grouping. The glycosides (I) are useful as surfactants or emulsifiers in washing, cleaning or body care products.
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公开(公告)号:DE4445931A1
公开(公告)日:1996-06-27
申请号:DE4445931
申请日:1994-12-22
Applicant: BASF AG
Inventor: POTTHOFF-KARL BIRGIT DR , STRECKER BEATE DR , BAUR RICHARD DR , OETTER GUENTER DR , OFTRING ALFRED DR
IPC: C07C229/12 , C07C229/22 , C07C229/24 , C11D3/33 , D06M13/342 , D21C9/10 , G03C5/38 , G03C5/44 , C11D1/04
Abstract: Hydroxyalkylaminocarboxylic acids have the general formula (I), in which R is hydrogen, a C1-C4 alkyl residue or a group having the formulas -CHR -CH(OH)-R or -CH2)n-COOM, in which n equals 1 to 4; R and R represent independently from each other hydrogen, a phenyl residue or an alkyl or alkenyl residue that may in addition bear phenoxy groups, carboxylic acid C1-C4-alkyl ester groups or ester groups derived from triglycerides based on unsaturated C10-C22 fatty acids and may be interrupted by non-adjacent oxygen atoms, the sum of all C atoms from both residues R and R being at least 4; A is a linear or branched C1-C6 alkylene group that may in addition bear a hydroxyl group and/or a group having the formula COOM, and R and A may form together with the N atom a 5- or 6-membered ring; and M is hydrogen, alkaline metal, ammonium or substituted ammonium. These hydroxyalkylaminocarboxylic acids are useful as complexing agents for alkaline earth and heavy metal ions.
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公开(公告)号:DE4433977A1
公开(公告)日:1996-03-28
申请号:DE4433977
申请日:1994-09-23
Applicant: BASF AG
Inventor: STRECKER BEATE DR , OFTRING ALFRED DR , HERTEL DIETER , SCHUH GEORG
IPC: C07B61/00 , C07C231/02 , C07C233/47 , C07C303/22 , C07C303/32 , C07C309/15 , C07C231/12 , C07C309/21
Abstract: In order to produce N-acylamino carboxylic and N-acylaminosulphonic acids and their alkaline metal salts from industrial alkaline metal salts of aminocarboxylic or aminosulphonic acids with an active content from 50 to 95 % by weight, in relation to the solid content of the industrial alkaline metal salts, and from carboxylic acid alkyl esters, (a) a suspension of solid water-free industrial alkaline metal salts of aminocarboxylic or aminosulphonic acids in carboxylic acid alkyl esters is prepared; (b) the suspension is made to react by admixture of more than 30 and up to 150 % by moles of strong bases into the alkaline metal salts of N-acylaminocarboxylic or N-acylaminosulphonic acids; and (c) if desired free N-acylaminocarboxylic or N-acylaminosulphonic acids are produced therefrom in the usual manner by admixture of acids.
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公开(公告)号:DE4336247A1
公开(公告)日:1995-04-27
申请号:DE4336247
申请日:1993-10-22
Applicant: BASF AG
Inventor: STRECKER BEATE DR , OETTER GUENTER DR , OFTRING ALFRED DR , PERNER JOHANNES DR , BAUR RICHARD DR , SCHWENDEMANN VOLKER DR , KAHMEN MARTIN AUS DEM DR , REIF WOLFGANG DR
IPC: C11D1/72 , A01N25/30 , A61K47/18 , C07C231/02 , C07C233/18 , C07C233/20 , C09D17/00 , C09K8/035 , C09K8/28 , C09K23/00 , C09K23/42 , C11D1/52 , C23G5/00 , B01F17/42 , C09K7/02 , A61K7/48 , A61K7/06
Abstract: PCT No. PCT/EP94/03354 Sec. 371 Date Apr. 22, 1996 Sec. 102(e) Date Apr. 22, 1996 PCT Filed Oct. 12, 1994 PCT Pub. No. WO95/11225 PCT Pub. Date Apr. 27, 1995The use of endgroup-capped fatty amide alkoxylates IR1-CO-NH-(CH2)n-O-(AO)x-R2(I)where R1 is C5-C21-alkyl or -alkenyl, R2 is C1-C4-alkyl, A is C2-C4-alkylene, n is 2 or 3, and x has a value from 1 to 6, as nonionic surfactants or emulsifiers in detergents, cleaners or body care compositions, as surface-active substances for industrial applications in electroplating, in the photographic industry, in petroleum production, in the pharmaceutical industry, in plant feeding and in crop protection formulations, and as surface-active substances in the production of emulsions and pigment and plastic dispersions.
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公开(公告)号:DE59400924D1
公开(公告)日:1996-12-05
申请号:DE59400924
申请日:1994-02-25
Applicant: BASF AG
Inventor: BAUER GERHARD DR , AYDIN ORAL DR , STRECKER BEATE DR , OFTRING ALFRED DR
Abstract: Compound of the formula in which R and R independently of one another are C1-C10-alkyl, C1-C10-alkoxy-C5-C10-cycloalkyl or a C5-C10-aryl radical which can also contain 1 to 3 non-adjacent nitrogen, oxygen or sulphur atoms as hetero atoms in the carbon chain or carbon ring and which can be substituted by 1 to 3 C1-C4-alkyl or -alkoxy groups, R or R can represent a hydrogen atom, or R and R together form a bridge of 2 to 14 carbon atoms, it being possible for some of the carbon atoms also to be part of an aromatic ring system, A represents an n-valent organic radical, and n is an integer equal to or greater than 2.
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公开(公告)号:DE4433976A1
公开(公告)日:1996-03-28
申请号:DE4433976
申请日:1994-09-23
Applicant: BASF AG
Inventor: STRECKER BEATE DR , OFTRING ALFRED DR , HERTEL DIETER , SCHUH GEORG
IPC: C07C231/24 , C07C231/12 , C07C233/47 , C07C303/22 , C07C303/44 , C07C309/15 , C07C309/21
Abstract: The proposed method of producing free N-acyl amino-carboxylic and sulphonic acids from their alkali metal salts produced without solvents involves precipitation with aqueous acids. This is done by adding to the alkali metal salts a quantity of the appropriate free N-acyl amino-carboxylic and sulphonic acids equivalent to 5-100 wt % of the quantity of alkali metal salts before mixing with the aqueous acids.
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公开(公告)号:DE4306392A1
公开(公告)日:1994-09-08
申请号:DE4306392
申请日:1993-03-02
Applicant: BASF AG
Inventor: BAUER GERHARD DR , AYDIN ORAL DR , STRECKER BEATE DR , OFTRING ALFRED DR
IPC: C07C251/54 , C08F8/30 , C08J3/24 , C08K5/32 , C08K5/33 , C08L33/06 , C09J11/06 , C08L29/12 , C08L29/00 , C09J129/00 , C09D129/00 , C09D133/04 , C09D131/02 , C09D125/00 , C09D133/18 , C09D127/06
Abstract: Compound of the formula in which R and R independently of one another are C1-C10-alkyl, C1-C10-alkoxy-C5-C10-cycloalkyl or a C5-C10-aryl radical which can also contain 1 to 3 non-adjacent nitrogen, oxygen or sulphur atoms as hetero atoms in the carbon chain or carbon ring and which can be substituted by 1 to 3 C1-C4-alkyl or -alkoxy groups, R or R can represent a hydrogen atom, or R and R together form a bridge of 2 to 14 carbon atoms, it being possible for some of the carbon atoms also to be part of an aromatic ring system, A represents an n-valent organic radical, and n is an integer equal to or greater than 2.
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公开(公告)号:DE4227894A1
公开(公告)日:1994-02-24
申请号:DE4227894
申请日:1992-08-22
Applicant: BASF AG
Inventor: WOLF GERHARD DR , BAUR RICHARD DR , SEELMANN-EGGEBERT HANS-PETER D , SCHWENDEMANN VOLKER DR , STRECKER BEATE DR , OFTRING ALFRED DR
IPC: C02F1/66 , C09K23/00 , C09K23/22 , C09K23/32 , C09K23/42 , C02F1/58 , B01F17/42 , B01F17/22 , B01F17/32
Abstract: Process for the reduction of organic components in effluent from processes using pH-sensitive surfactants for washing textiles or for cleaning rough surfaces, comprises treating the waste with acids to deactivate the surfactants and then separating the obtd. organic phase from the inorg. phase. The process is useful for removing pH-sensitive surfactants of formula (I)-(VI). USE/ADVANTAGE - The process is esp. useful for treating effluent from the laundry, foodstuffs, dairy, brewing or drinks industries. The need for expensive treatments such as partial evaporation, flotation or filtration is eliminated.
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公开(公告)号:ES2093997T3
公开(公告)日:1997-01-01
申请号:ES94102863
申请日:1994-02-25
Applicant: BASF AG
Inventor: BAUER GERHARD DR , AYDIN ORAL DR , STRECKER BEATE DR , OFTRING ALFRED DR
Abstract: Compound of the formula in which R and R independently of one another are C1-C10-alkyl, C1-C10-alkoxy-C5-C10-cycloalkyl or a C5-C10-aryl radical which can also contain 1 to 3 non-adjacent nitrogen, oxygen or sulphur atoms as hetero atoms in the carbon chain or carbon ring and which can be substituted by 1 to 3 C1-C4-alkyl or -alkoxy groups, R or R can represent a hydrogen atom, or R and R together form a bridge of 2 to 14 carbon atoms, it being possible for some of the carbon atoms also to be part of an aromatic ring system, A represents an n-valent organic radical, and n is an integer equal to or greater than 2.
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