33.
    发明专利
    未知

    公开(公告)号:DE102004051647A1

    公开(公告)日:2006-07-06

    申请号:DE102004051647

    申请日:2004-10-22

    Applicant: BASF AG

    Abstract: Copolymers prepared by a process comprising free-radical polymerizing: (a) more than 15 to 40% by weight of at least one monoethylenically unsaturated carboxylic acid; (b) 30 to less than 85% by weight of ethyl methacrylate; and (c) 0 to 50% by weight of at least one additional free-radically polymerizable monomer other than the at least one monoethylenically unsaturated carboxylic acid and ethyl methacrylate; wherein the total amount of (a), (b) and (c) equals 100% by weight; with the proviso that where the process comprises a solution polymerization, (a) consists of acrylic acid and methacrylic acid, and (c) is an ester of (meth)acrylic acid and an aliphatic C 8 -C 18 -alcohol, then the ester of (meth)acrylic acid and an aliphatic C 8 -C 18 -alcohol is not present in an amount of 5 to 40% by weight; and with the proviso that where (c) is selected from the group consisting of N-vinylpyrrolidone, N-vinylcaprolactam and mixtures thereof; then the N-vinylpyrrolidone, N-vinylcaprolactam or mixture thereof is present in an amount of less than 5% by weight.

    35.
    发明专利
    未知

    公开(公告)号:DE59911338D1

    公开(公告)日:2005-01-27

    申请号:DE59911338

    申请日:1999-08-25

    Applicant: BASF AG

    Abstract: A process for reducing the amount of residual monomer in aqueous polymer dispersions operates by aftertreatment with an initiator system essentially comprisinga) from 0.001 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion,a1) of an oxidizing agent where R1 is hydrogen or a C1-C8-alkyl or a C6-C12-aryl group, and/ora2) of a compound which in aqueous medium releases hydrogen peroxide, andb) from 0.005 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion,b1) of an alpha-hydroxycarbonyl compound where R2 and R3 independently of one another are hydrogen and/or a C1-C12-alkyl group which may contain functional groups and/or may be olefinically unsaturated, or R2 and R3 optionally, by way of methylene groups, form a ring structure which may contain functional groups and/or may be olefinically unsaturated, and/orb2) of a compound which in aqueous medium releases such alpha-hydroxycarbonyl compounds, andc) advantageously, catalytic amounts of a polyvalent metal ion which is able to exist in a plurality of valence states.

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