3-SUBSTITUTED PYRIDINE DERIVATIVES AND FUNGICIDAL COMPOSITIONS

    公开(公告)号:NZ236622A

    公开(公告)日:1992-06-25

    申请号:NZ23662290

    申请日:1990-12-21

    Applicant: BASF AG

    Abstract: 3-Substituted pyridines I … …… … (X = OH; Y = -O-CHO, -O-CO-W R , -O-SO2-W R or X + Y = -O-CH(W R )-O-, O CH(O W R )-O-, -O-C-(W R )(O-W R )-O-; W -W = direct bond, -CH2-, -CH2-CH2, -CH(CH3)-, -CH2O-, -CH2S-; R -R = optionally cycloalkyl-substituted C1-C6-alkyl, C1-C6-haloalkyl, C3-C8-cycloalkyl which is optionally substituted by 1-3 alkyl radicals, or C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, optionally substituted phenyl or naphthyl, optionally substituted 5-/6-membered heteroaryl having 1 to 3 hetero atoms; … R is additionally H when X + Y = -O-CH(W R )-O-, -O-CH(O-W R )-O- or -O-C(W R )(O-W R )-O- and W2 = direct bond), … with the exception of cis-1-(2,4-dichlorophenyl)-2-(pyrid-3-yl)- 1,2-epoxypropane, trans-1-(2,4-dichlorophenyl)-2-(pyrid-3-yl)- 1,2-epoxypropane, 1-(2,4-dichlorophenyl)-2-(pyrid-3-yl)- 1,2-epoxybutane and 2,4-dichloro- alpha -[1-hydroxy-1-(pyrid-3-yl)ethyl]- benzyl methanesulphonate … and the N-oxides and phytophysiologically acceptable salts with mineral acids, and metal complexes of I. … The compounds I are suitable as fungicides.

    PLANT PROTECTING PREPARATIVES CONTAINING BETA-PICOLINE DERIVATIVES AND PROCESS FOR PRODUCING SAID ACTIVE SUVBSTANCES

    公开(公告)号:HU911896D0

    公开(公告)日:1991-12-30

    申请号:HU189691

    申请日:1991-06-06

    Applicant: BASF AG

    Abstract: Beta-picoline derivs. (I) and their N-oxides and addn. salts are new. In (I), A = CR1R2; R1, R2 = H, 1-6C alkyl, 2-6C alkenyl or 2-6C alkynyl; or R1+R2 = 2-6C n-alkylene; B = CH2, CHOR3, CHR4 or C=NOR5; R3 = H, 1-6C alkyl, 1-6C haloalkyl, 3-8C cycloalkyl, 3-6C alkenyl, 2-6C acyl or phenyl, benzyl or benzoyl opt. mono-, di- or tri-substd. in the ring by 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, 1-4C haloalkoxy, halogen, cyano or nitro; R4 = H, F, Cl, Br or I; R5 = H, 1-6C alkyl, 1-6C haloalkyl, 3-7C cycloalkyl, 3-6C alkenyl or aryl-1-4C alkyl opt. mono-, di- or tri-substd. in the aryl ring by 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, halogen, cyano or nitro; Ar = phenyl or naphthyl opt. mono-, di- or tri-substd. by halogen, 1-6C alkyl, 1-4C alkoxy, 1-4C haloalkyl, 1-4C haloalkoxy, phenyl, phenoxy, halophenyl, halophenoxy or benzyloxy; except 1-phenyl-3-(3-pyridyl) propan-1-one (IA). The use of cpd. (IA), which is known from J. Org. Chem. 43 (1978), 3396 and Arch. Pharm. 307 (1974), 550, for the control of fungi is also claimed. Further, intermediates (II) are claimed except where A = CH2 or CH(CH3). 3 Cpds. (I), e.g., 2-ethyl-1-(4-fluorophenyl) -2-(pyridyl-3-methyl)butan-1-ol, are specifically claimed.

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