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公开(公告)号:FR2740776B1
公开(公告)日:1998-08-28
申请号:FR9613318
申请日:1996-10-31
Applicant: BASF MAGNETICS GMBH
Inventor: WUNSCH THOMAS , KRESS RIA , LOCH WERNER , LEHNER AUGUST , KOHL ALBERT , SCHNEIDER NORBERT , BURKHART UWE
IPC: C08K3/08 , C08G18/10 , C08G18/32 , C08G18/38 , C08G18/64 , C08G18/72 , C08K3/22 , C08L75/00 , C08L75/04 , C09D5/23 , C09D175/00 , C09D175/04 , G11B5/702 , C09D7/00 , G11B5/62
Abstract: Hydroxyl-containing polyurethanes I are composed essentially of a) a diisocyanate of 6 to 30 carbon atoms (component II), b) a component III comprising alpha ) an aliphatic diol of 2 to 20 carbon atoms or beta ) an aromatic-aliphatic or aromatic-cycloaliphatic diol of 8 to 30 carbon atoms having nonphenolic hydroxyl groups as hydroxyl groups of the diol and c) a polyhydric alcohol having at least 3 hydroxyl groups, 3 to 18 carbon atoms and nonphenolic hydroxyl groups as hydroxyl groups of the alcohol (component IV), the amounts of components II to IV being such that the total number of nonphenolic hydroxyl groups is from 1.1 to 5.0 per isocyanate group of II. The polyurethanes can be used as binders or binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
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公开(公告)号:GB2286192B
公开(公告)日:1998-04-29
申请号:GB9500515
申请日:1995-01-11
Applicant: BASF MAGNETICS GMBH , EMTEC MAGNETICS GMBH
Inventor: BRODT GREGOR , WUENSCH THOMAS , LEHNER AUGUST , KOHL ALBERT
Abstract: A material suitable as crosslinking binder component for pigment-containing coatings and having an average molecular weight of from 25,000 to 150,000, obtainable by reacting a polyurethane comprising a diol having a molecular weight between 400 and 4,000, an aliphatic or cycloaliphatic diol of 2-18 carbon atoms, an aromatic diol of 8-36 carbon atoms, a trihydric or polyhydric alcohol of 3-18 carbon atoms, a polyhydric alcohol of 3-40 carbon atoms containing a tertiary amino group, and a diisocyanate of 3-34 carbon atoms with a compound containing one or more hydroxyl groups and one or more amino groups reactive toward isocyanate groups. The materials may be used as crosslinkable binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
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公开(公告)号:GB2285985B
公开(公告)日:1998-04-29
申请号:GB9500467
申请日:1995-01-11
Applicant: BASF MAGNETICS GMBH , EMTEC MAGNETICS GMBH
Inventor: BRODT GREGOR , LEHNER AUGUST , LINDNER ALFRED , GRAF HERMANN , BOBRICH MICHAEL , KRESS RIA , SCHNEIDER NORBET , KOHL ALBERT , LOCH WERNER
IPC: C08G18/65 , C08F2/38 , C08F8/30 , C08F8/32 , C08G18/10 , C08G18/62 , C08G18/78 , C09D5/23 , C09D7/45 , C09D17/00 , C09D175/04 , C09K23/00 , C09K23/52 , G11B5/70 , G11B5/702 , C08G18/83
Abstract: Polymeric materials (I) are obtainable by reacting 1. a polymer II comprising a) from 80 to almost 100 mol % of a C1-C25-alkyl ester of an alpha , beta -unsaturated carboxylic acid, b) from 0 to 20 mol % of a further monomer, c) tetrahydrofuran hydroperoxide as polymerization initiator and, if required, d) a further polymerization initiator and/or regulator by means of which the majority of the polymer chains of the polymer II are terminated at one of their ends by a hydroxyl group, 2. with a polyfunctional isocyanate III to give a reaction product IV, the amount of isocyanate groups being from 1.2 to 3.0 mol per mol of hydroxyl groups of II, and 3. reacting IV with ammonia or with a compound V which has an amino function reactive toward isocyanates. The polymeric materials can be used as dispersing resins for pigment-containing coatings, in particular for the production of magnetic recording materials.
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公开(公告)号:FR2740776A1
公开(公告)日:1997-05-09
申请号:FR9613318
申请日:1996-10-31
Applicant: BASF MAGNETICS GMBH
Inventor: WUNSCH THOMAS , KRESS RIA , LOCH WERNER , LEHNER AUGUST , KOHL ALBERT , SCHNEIDER NORBERT , BURKHART UWE
IPC: C08K3/08 , C08G18/10 , C08G18/32 , C08G18/38 , C08G18/64 , C08G18/72 , C08K3/22 , C08L75/00 , C08L75/04 , C09D5/23 , C09D175/00 , C09D175/04 , G11B5/702 , C09D7/00 , G11B5/62
Abstract: Hydroxyl-containing polyurethanes I are composed essentially of a) a diisocyanate of 6 to 30 carbon atoms (component II), b) a component III comprising alpha ) an aliphatic diol of 2 to 20 carbon atoms or beta ) an aromatic-aliphatic or aromatic-cycloaliphatic diol of 8 to 30 carbon atoms having nonphenolic hydroxyl groups as hydroxyl groups of the diol and c) a polyhydric alcohol having at least 3 hydroxyl groups, 3 to 18 carbon atoms and nonphenolic hydroxyl groups as hydroxyl groups of the alcohol (component IV), the amounts of components II to IV being such that the total number of nonphenolic hydroxyl groups is from 1.1 to 5.0 per isocyanate group of II. The polyurethanes can be used as binders or binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
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公开(公告)号:DE19516784A1
公开(公告)日:1996-11-14
申请号:DE19516784
申请日:1995-05-11
Applicant: BASF MAGNETICS GMBH
Inventor: BRODT GREGOR , WEINGART FRANZ , LEHNER AUGUST , KOHL ALBERT , KRESS RIA , SCHELBLE JOSEF , SCHNEIDER NORBERT
IPC: C08G18/10 , C08G18/62 , C08G18/65 , C08G18/83 , C08L75/00 , C08L101/00 , C08L101/12 , C09D5/23 , G11B5/702 , G11B5/73 , C08L75/04 , C09D17/00
Abstract: Polymeric materials (I), suitable for use as dispersing resins, are obtd. by reacting (1) a polymer (II) of (a) 80-100 mole% (1-25C alkyl)-ester of an alpha , beta -unsatd. carboxylic acid, (b) 0-20 mole% other comonomer(s) and (c) a starter and/or regulator to produce OH end gps. on most of the polymer chains with (2) a polyfunctional isocyanate (III) to give a prod. (IV), using a mole ratio of (NCO gps.):(OH gps. in II) = 1.2-3.9, and (3) reacting (IV) with (a) a cpd. contg. NCO-reactive gps., with a ratio of 2-7 moles reactive gps. per mole free NCO gps. in (IV), and then reacting the prod. obtd. (VI) with a cpd. (VII) which reacts with the free reactive gps. to introduce acid gps., or (b) a NCO-reactive cpd. (VIII) which itself enables the introduction of acid gps. Also claimed is (i) this process as such, (ii) pigment prepns. contg. a pigment (pref. a magnetic pigment) and material (I), and (iii) magnetic recording materials contg. magnetic pigments treated with (I).
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公开(公告)号:GB2285807A
公开(公告)日:1995-07-26
申请号:GB9500512
申请日:1995-01-11
Applicant: BASF MAGNETICS GMBH
Inventor: WUENSCH THOMAS , BRODT GREGOR , KRESS RIA , SCHNEIDER NORBERT , KOHL ALBERT , LEHNER AUGUST , BALZ WERNER
IPC: C08G18/12 , C08G18/61 , C08G18/65 , C08G18/66 , C09D5/23 , C09D175/00 , C09D175/04 , G11B5/702
Abstract: Polymeric materials (I) having an average molecular weight from 4000 to 30,000 are obtainable by reacting 1) A polyurethane (II) comprising a) 1 mol of a diol (III) having an average molecule weight of from 400 to 4000, b) from 0.3 to 9 mol of an aliphatic or cycloaliphatic diol (IV) of 2 to 18 carbon atoms, c) from 0.3 to 9 mol of an aromatic diol (V) of 8 to 30 carbon atoms, d) from 0.01 to 1 mol of a trihydric alcohol (VI) of 3 to 18 carbon atoms, e) from 0.001 to 1 mol of a polyhydric alcohol (VII) of 3 to 14 carbon atoms which contains a tertiary amino group and f) an amount of a diisocyanate (VIII) of 6 to 30 carbon atoms such that the molar ratio of the isocyanate groups to the total number of hydroxyl groups in (III) to (VII) is from 1.05:1 to 1.4:1 with 2) a compound (IX) which contains one or more hydroxyl groups and one or more amino groups reactive toward isocyanate groups, the amount of (IX) being such that the number of reactive amino groups corresponds to the number of isocyanate groups in the polyurethane (II). The materials may be used as crosslinkable binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
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公开(公告)号:DE4233388A1
公开(公告)日:1994-04-07
申请号:DE4233388
申请日:1992-10-05
Applicant: BASF MAGNETICS GMBH
Inventor: LEHNER AUGUST , SCHNEIDER NORBERT , BALZ WERNER DR , LENZ WERNER DR , BOBRICH MICHAEL DR , KOHL ALBERT
IPC: C09D5/23 , C09D133/04 , C09D133/16 , G11B5/702 , G11B5/708 , G11B5/62
Abstract: Magnetic recording substrate comprises a non-magnetic substrate material supporting at least one applied magnetic layer contg. at least 30 wt% ferromagnetic chromium dioxide finely divided in a polymer binding agent and other standard. The content of 0.1-8 wt% (w.r.t. CrO2) perfluoropolyacrylate having a softening pt. greater than 110 deg.C in the magnetic layer. ADVANTAGE - The recording substrates show improved stability to chemical degradation and no less in mechanical properties at high or varying temps. whilst showing no deterioration in magnetic properties.
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