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公开(公告)号:BR112013004599A2
公开(公告)日:2016-07-05
申请号:BR112013004599
申请日:2011-08-24
Applicant: BASF SE
Inventor: LAWRENZ DIRK , EVSTATIEVA ELITSA , GARLICHS FLORIAN , BALDAMUS JENS , MINDERHOUD JOHANNES JAN-BESSEL , BASSLER PETER
IPC: C08F2/38 , C08F212/08 , C08F236/10 , C09D5/02 , D21H19/48
Abstract: dispersão polimérica aquosa, processo para preparar uma dispersão polimérica aquosa, uso do polímero, tira de revestimento de papel,e, papel ou cartão. a invenção diz respeito polimérica aquosa contendo um polímero, que pode ser produzida por uma polimerização em emulsão radicalmente iniciada de monômeros radicalmente polimerizáveis etilenicamente insaturados, em que a polimerização dos monômeros é realizada na presença de uma composição reguladora de peso molecular específica. a composição reguladora de peso molecular contém pelo menos um éster de ácido mercaptoalquilcarboxílico de um ácido carboxílico c a c e pelo menos um composto oligomérico de fórmula r¹-x-(a-s) -a-y-r², em que r¹ e r² denotam h ou ch -(ch -c(=o)-, x e y denotam um átomo de oxigênio ou um átomo de enxofre, a denota um grupo de alquileno c a c divalente , e n denota um número de 1 a 8. a invenção ainda diz respeito a um método para produzir a dispersão polimérica aquosa. a dispersão polimérica pode ser usada como um aglutinante, adesivo, agente de dimensionamento para fibras, para produzir revestimentos ou para produzir compostos de revestimento de pepel.
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公开(公告)号:CA2944970A1
公开(公告)日:2015-10-15
申请号:CA2944970
申请日:2015-04-07
Applicant: BASF SE
Inventor: VELING NICO , JIMENEZ GARCIA LUCIA , LAWRENZ DIRK
Abstract: The invention relates to a process for preparing an aqueous dispersion of a polymer P, which comprises the emulsion polymerization of vinyl acetate, an acrylate monomer, which is a C1-C10 alkyl acrylate or a C1-C10 methacrylate, an a,ß-ethlyenically unsaturated C3-C8 carboxylic acid, glycidyl methacrylate or glycidyl acrylate, optionally an ethylenically unsaturated sulfonic acid and optionally an ethylenically unsaturated other monomer. Furthermore, the aqueous polymer dispersion obtainable from this process and a powder form thereof are disclosed. They are useful for a paper coating slip containing one of the aforementioned forms. A paper or a cardboard, which is coated with the paper coating slip, shows surface strength, which is expressed by a good dry pick resistance, a good wet pick resistance or good offset test results. The aqueous polymer dispersion or the powder form thereof is furthermore useful as a binder.
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公开(公告)号:ES2538370T3
公开(公告)日:2015-06-19
申请号:ES11724644
申请日:2011-06-14
Applicant: BASF SE
Inventor: SCHMIDT-THÜMMES JÜRGEN , EVSTATIEVA ELITSA , MOREL AURELIE , LAWRENZ DIRK , SEYFFER HERMANN
IPC: C08F220/18 , C08F2/22 , C08F212/08 , D21H19/58
Abstract: Dispersión polimérica acuosa que puede obtenerse mediante polimerización en emulsión iniciada por radicales de (a) de 19,9 a 80 partes en peso al menos de un compuesto vinilaromático, (b) de 19,9 a 80 partes en peso al menos de un monómero de acrilato seleccionado de acrilatos de alquilo C1 a C10 y metacrilatos de alquilo C1 a C10, (c) de 0,1 a 10 partes en peso al menos de un ácido etilénicamente insaturado y (d) de 0 a 20 partes en peso al menos de otro monómero etilénicamente insaturado, ascendiendo la suma de las partes en peso de los monómeros (a), (b), (c) y (d) a 100, y realizándose la polimerización en emulsión en medio acuoso en presencia de iniciadores que forman radicales, látex de semilla así como al menos un compuesto de hidrato de carbono en forma de un almidón degradado.
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公开(公告)号:BRPI0818356A2
公开(公告)日:2015-04-07
申请号:BRPI0818356
申请日:2008-10-06
Applicant: BASF SE
Inventor: EVSTATIEVA ELITSA , SCHMIDT-THÜMMES JÜRGEN , LAWRENZ DIRK , MINDERHOUD JOHANNES JAN-BESSEL , ARENS GUILLERMO
IPC: C08F251/02 , C08F2/22 , C08L25/10 , C08L51/02 , C09D151/02 , D21H19/54 , D21H19/58 , D21H21/16
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公开(公告)号:CA2700059C
公开(公告)日:2015-01-20
申请号:CA2700059
申请日:2008-10-06
Applicant: BASF SE
Inventor: EVSTATIEVA ELITSA , SCHMIDT-THUMMES JURGEN , LAWRENZ DIRK , MINDERHOUD JOHANNES JAN-BESSEL , ARENS GUILLERMO
IPC: C08F251/02 , C08F2/22 , C08L25/10 , C08L51/02 , C09D151/02 , D21H19/54 , D21H19/58 , D21H21/16
Abstract: Aqueous polymer dispersions based on copolymers formed from vinyl-aromatics and conjugated aliphatic dienes having a mean particle size of from 80 to 150 nm are obtainable by free-radically initiated emulsion copolymerization of (a) from 19.9 to 80 parts by weight of at least one vinylaromatic compound, (b) from 19.9 to 80 parts by weight of at least one conjugated aliphatic diene, (c) from 0.1 to 10 parts by weight of at least one ethylenically unsaturated acid and (d) from 0 to 20 parts by weight of at least one other monoethylenically unsaturated monomer, where the sum of the parts by weight of monomers (a), (b), (c) and (d) is always 100, in an aqueous medium in the presence of at least one degraded starch with an intrinsic viscosity .eta. of less than 0.07 dl/g, using at least 0.9% by weight, based on all of the monomers used, of initiators selected from peroxodisulphates, peroxosulphates, azo initiators, organic peroxides, organic hydroperoxides and hydrogen peroxide, wherein at least 30% by weight of the initiators are initially charged in the aqueous medium together with the degraded starch and the monomers and the remaining initiators are metered into this initial charge under polymerization conditions. Processes for preparing this dispersion by emulsion polymerization of the monomers (a), (b), (c) and optionally (d) in the presence of a degraded starch with an intrinsic viscosity .eta. of less than 0.07 dl/g, where a portion of the initiator is initially charged together with the aqueous solution of the degraded starch in the reactor, and the remaining initiator and the monomers are metered in under polymerization conditions, and the use of the aqueous polymer dispersions as binders, adhesives, sizes for fibres or for producing coatings.
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公开(公告)号:AU2011267134A1
公开(公告)日:2013-01-10
申请号:AU2011267134
申请日:2011-06-14
Applicant: BASF SE
Inventor: SCHMIDT-THUMMES JURGEN , EVSTATIEVA ELITSA , MOREL AURELIE , LAWRENZ DIRK , SEYFFER HERMANN
IPC: C08F220/18 , C08F2/22 , C08F212/08 , D21H19/58
Abstract: Aqueous polymer dispersions and processes for preparing them are described. The polymer dispersions can be obtained by free-radically initiated emulsion polymerization of from 19.9 to 80 parts by weight of vinylaromatic compounds, from 19.9 to 80 parts by weight of acrylate monomers selected from among C1‑C10-alkyl acrylates and C1-C10-alkyl methacrylates, from 0.1 to 10 parts by weight of ethylenically unsaturated acids and from 0 to 20 parts by weight of other ethylenically unsaturated monomers, wherein the emulsion polymerization is carried out in an aqueous medium in the presence of free-radical-forming initiators, seed latex and at least one carbohydrate compound in the form of a degraded starch. The polymer dispersions are particularly suitable for producing paper coating compositions.
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公开(公告)号:ES2365262T3
公开(公告)日:2011-09-27
申请号:ES08837528
申请日:2008-10-06
Applicant: BASF SE
Inventor: EVSTATIEVA ELITSA , SCHMIDT-THUEMMES JUERGEN , LAWRENZ DIRK , MINDERHOUD JOHANNES JAN-BESSEL , ARENS GUILLERMO
IPC: C08F212/08 , C08F2/24 , C08F220/06 , C08F222/02 , C08F236/10 , C08L3/02 , C09D125/14 , C09J125/14 , D21H19/44
Abstract: Dispersiones acuosas de polímeros sobre la base de copolimerizados de compuestos vinilaromáticos y dienos alifáticos conjugados, caracterizadas porque presentan un tamaño medio de partículas de 80 a 150 nm y se pueden obtener a través de la copolimerización por emulsión de iniciación radical de (a) 19,9 a 80 partes en peso de, al menos, un compuesto vinilaromático, (b) 19,9 a 80 partes en peso de, al menos, un dieno alifático conjugado, (c) 0,1 a 10 partes en peso de, al menos, un ácido insaturado etilénicamente y (d) 0 a 20 partes en peso de, al menos, un monómero monoetilénicamente insaturado adicional, en donde la suma de las partes en peso de los monómeros (a), (b), (c) y (d) alcanza siempre el 100 % en peso, en un medio acuoso, en presencia de, al menos, un almidón desintegrado con una viscosidad intrínseca ηi de menos de 0,07 dl/g, utilizando, al menos 0,9 % en peso, en relación a la cantidad total de monómeros utilizada, de iniciadores seleccionados entre peroxodisulfatos, peroxosulfatos, azoiniciadores, peróxidos orgánicos, hidroperóxidos orgánicos y peróxido de hidrógeno, en donde al menos 30 % en peso de los iniciadores se disponen junto con el almidón desintegrado en el medio acuoso, y los monómeros, así como los iniciadores restantes son dosificados a este preparado en condiciones de polimerización.
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公开(公告)号:DE502008002766D1
公开(公告)日:2011-04-14
申请号:DE502008002766
申请日:2008-09-11
Applicant: BASF SE
Inventor: KOPLIN TOBIAS JOACHIM , REIMERS OLIVER , NORD SIMON , LAWRENZ DIRK , BIRKERT OLIVER , GEISSLER ULRIKE
IPC: C09D129/04 , C08J3/00 , C08L101/00 , C09D5/22
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公开(公告)号:AU2009319065A1
公开(公告)日:2010-06-03
申请号:AU2009319065
申请日:2009-11-20
Applicant: BASF SE
Inventor: EVSTATIEVA ELITSA , SCHMIDT-THUMMES JURGEN , LAWRENZ DIRK
IPC: C08F251/00 , C08B31/00 , C08F251/02 , C08F279/02 , C08F279/04 , C08L51/02 , C08L55/02 , C09D151/02 , C09D155/02 , D21H19/54 , D21H19/58
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