公开(公告)号：ES2364095T3

公开(公告)日：2011-08-24

申请号：ES07848013

申请日：2007-12-10

Applicant: BASF SE

Inventor： SIRCH TILMAN ,  STEINIGER MICHAEL ,  MAAS STEFFEN ,  RITTINGER STEFAN ,  SCHLITTER STEPHAN ,  GUIXA GUARDIA MARIA ,  SPENGEMAN TODD ,  ANDRESS JEFFREY

IPC: C07C45/75 ,  C07C29/141 ,  C07C31/20 ,  C07C31/22 ,  C07C31/24 ,  C07C47/19

Abstract: Procedimiento para la obtención de compuestos de polimetilol de la fórmula (I) (HOCH2)2-C-R2 en la que R significan respectivamente, de manera independiente entre sí, otro grupo metilol o un grupo alquilo con 1 hasta 22 átomos de carbono o un grupo arilo o un grupo aralquilo con 6 hasta 22 átomos de carbono, por medio de la condensación de aldehídos con 2 hasta 24 átomos de carbono, en una reacción de aldolización, con formaldehído, con empleo de aminas terciarias a título de catalizador, para formar los alcanales de la fórmula (II) en la que R tienen, respectivamente, de manera independiente entre sí el significado que ha sido indicado más arriba, y su hidrogenación subsiguiente, caracterizado porque la reacción de aldolización se lleva a cabo con una solución acuosa de formaldehído con un contenido en ácido fórmico con un valor

公开(公告)号：BR112012032211A2

公开(公告)日：2016-11-29

申请号：BR112012032211

申请日：2011-06-28

Applicant: BASF SE

Inventor： SCHNEIDER DANIEL ,  KAIBEL GERD ,  TELES JOAQUIM HENRIQUE ,  PICKENÄCKER KARIN ,  MOHL KLAUS-DIETER ,  SCHÄFER MARTIN ,  PACIELLO ROCCO ,  RITTINGER STEFAN ,  SCHAUB THOMAS

IPC: C07C51/50 ,  C07C51/44 ,  C07C53/02

Abstract: processo para obter ácido fórmico. a invenção refere-se a um método para obter ácido fórmico pela separação térmica de um fluxo contendo ácido fórmico e uma amina terciária (i), em que um fluxo líquido que contém ácido fórmico e uma amina terciária (i) em uma proporção molar de 0,5 a 5 é produzido pela combinação de amina terciária (i) e uma fonte de ácido fórmico, 10% a 100% em peso dos componentes secundários contidos em dito fluxo são separados, e ácido fórmico é removido por destilação do fluxo de líquido resultante em um dispositivo de destilação em uma temperatura de fundo de 100ºc a 300º c e uma pressão de 30 hpa abs a 3.000 hpa abs, em que o produto de fundo do dispositivo de destilação é separado em duas fases líquidas e a fase líquida superior é retornada para a fonte de ácido fórmico e a fase líquida inferior é retornada para separação dos componentes secundários e/ou para o dispositivo de destilação.

公开(公告)号：BRPI1006870A2

公开(公告)日：2016-03-15

申请号：BRPI1006870

申请日：2010-01-07

Applicant: BASF SE

Inventor： STEINIGER MICHAEL ,  RITTINGER STEFAN ,  MAAS STEFFEN ,  SCHLITTER STEPHAN ,  SIRCH TILMAN

IPC: C07C45/75 ,  C07C29/141 ,  C07C45/82

公开(公告)号：SG11201503223RA

公开(公告)日：2015-06-29

申请号：SG11201503223R

申请日：2013-11-26

Applicant: BASF SE

Inventor： SCHNEIDER DANIEL ,  MOHL KLAUS-DIETER ,  SCHÄFER MARTIN ,  PASCHOLD JÜRGEN ,  TELES JOAQUIM HENRIQUE ,  RITTINGER STEFAN

IPC: C07C67/36 ,  C07C69/06

Abstract: The invention relates to a method for producing methyl formate by carbonylating methanol with carbon monoxide in a carbonylation reactor in the presence of a catalyst system containing alkali formate and alkali alcoholate, thereby obtaining a reaction mixture (RG) which contains methyl formate, alkali formate, alkali alcoholate and optionally unreacted methanol and unreacted carbon monoxide and which is removed from the carbonylation reactor. The reaction mixture (RG) contains at least 0.5 wt.% alkali alcoholate, based on the total weight of the reaction mixture (RG), and the molar ratio of alkali formate to alkali alcoholate in the reaction mixture (RG) is greater than 1.

公开(公告)号：ZA201305411B

公开(公告)日：2014-10-29

申请号：ZA201305411

申请日：2013-07-18

Applicant: BASF SE

Inventor： SCHAUB THOMAS ,  FRIES DONATA MARIA ,  PACIELLO ROCCO ,  MOHL KLAUS-DIETER ,  SCHAFER MARTIN ,  RITTINGER STEFAN ,  DECKERT PETRA ,  BASSLER PETER

IPC: C07C20060101

Abstract: The invention relates to a method for producing formic acid by reacting carbon dioxide (1) with hydrogen (2) in a hydrating reactor (I) in the presence of a catalyst comprising an element from the 8th, 9th, or 10th group of the periodic system; a tertiary amine containing at least twelve carbon atoms per molecule; and a polar solvent comprising one or more monoalcohols selected from methanol, ethanol, propanols, and butanols, forming formic acid / amine adducts as intermediate products, which are subsequently thermally split, wherein a tertiary amine having a boiling point at least 5°C higher than formic acid is used, and wherein a reaction mixture comprising the polar solvent, the formic acid / amine adducts, the tertiary amine, and the catalyst forms from the reaction in the hydrating reactor (I) and is discharged as a discharge (3) from the reactor.

公开(公告)号：BRPI0808032A2

公开(公告)日：2014-06-17

申请号：BRPI0808032

申请日：2008-02-25

Applicant: BASF SE

Inventor： SIRCH TILMAN ,  STEINIGER MICHAEL ,  MAAS STEFFEN ,  RITTINGER STEFAN ,  SCHLITTER STEPHAN

IPC: C07C29/141 ,  C07C45/75 ,  C07C45/82 ,  C07C47/19

Abstract: The preparation of hydroxypivalaldehyde is effected by aldolizing isobutyraldehyde with formaldehyde and subsequently working up the resulting reaction effluent by distillation, wherein the reaction effluent is fed to a distillation column which is operated at a top pressure in the range from 0.5 to 1.5 bar and in which a two-stage condensation is provided in the top region, in which the vapors are first conducted into a partial condenser operated at a temperature in the range from 50 to 80° C., whose condensate is recycled at least partly into the distillation column, and in which the vapors uncondensed in the partial condenser are fed to a downstream condenser operated at a temperature in the range from −40 to +30° C., whose condensate is at least partly discharged.

公开(公告)号：CA2838907A1

公开(公告)日：2013-01-10

申请号：CA2838907

申请日：2012-06-27

Applicant: BASF SE

Inventor： SCHAUB THOMAS ,  FRIES DONATA MARIA ,  PACIELLO ROCCO ,  BASSLER PETER ,  SCHAFER MARTIN ,  RITTINGER STEFAN

IPC: C07C51/02 ,  C07C51/15

Abstract: Process for the preparation of formic acid by reacting carbon dioxide with hydrogen in a hydrogenation reactor in the presence of a catalyst comprising an element from the 8th, 9th or 10th group of the Periodic Table of the Elements, of a tertiary amine and of a polar solvent, with formation of formic acid-amine adducts, which are then cleaved thermally to give formic acid and tertiary amine.

公开(公告)号：CA2821642A1

公开(公告)日：2012-06-28

申请号：CA2821642

申请日：2011-12-15

Applicant: BASF SE

Inventor： SCHAUB THOMAS ,  FRIES DONATA MARIA ,  PACIELLO ROCCO ,  MOHL KLAUS-DIETER ,  SCHAFER MARTIN ,  RITTINGER STEFAN ,  DECKERT PETRA ,  BASSLER PETER

IPC: C07C51/15 ,  C07C53/02

Abstract: The invention relates to a method for producing formic acid by reacting carbon dioxide (1) with hydrogen (2) in a hydrating reactor (I) in the presence of a catalyst comprising an element from the 8th, 9th, or 10th group of the periodic system; a tertiary amine containing at least twelve carbon atoms per molecule; and a polar solvent comprising one or more monoalcohols selected from methanol, ethanol, propanols, and butanols, forming formic acid / amine adducts as intermediate products, which are subsequently thermally split, wherein a tertiary amine having a boiling point at least 5°C higher than formic acid is used, and wherein a reaction mixture comprising the polar solvent, the formic acid / amine adducts, the tertiary amine, and the catalyst forms from the reaction in the hydrating reactor (I) and is discharged as a discharge (3) from the reactor.

公开(公告)号：SG171403A1

公开(公告)日：2011-07-28

申请号：SG2011037611

申请日：2009-12-07

Applicant: BASF SE

Inventor： SIRCH TILMAN ,  STEINIGER MICHAEL ,  MAAS STEFFEN ,  RITTINGER STEFAN ,  SCHLITTER STEPHAN

Abstract: METHOD FOR PURIFYING POLYMETHYLOLSAbstractThe present invention relates to a process for distilling an aqueous plymethylolmixture which comprises a polymethylol of the formula (I)[err]in which each R is independently a further methylol group or an alkyl group having 1 to12 carbon atoms of an aryl or aralkyl group having 6 to 22 carbon atoms, a tertiaryamine, water and the adduct of tertiary amine and tomic acid(amine fumate), whichcomprises performing the distillation in a distillation column which is connected at thebottom to an evaporator, the bottom temperature being above the evaporationtemperature of the monoester of formic acid and polymethylol(polymethylol furmate)which forms during distillation. The present invention further relates to a composition comprising polymethylol and 1 to 10 000 ppm by weight of polymethylol formate, and tothe use thereof.No suitable drawings.

公开(公告)号：BRPI0708286A2

公开(公告)日：2011-05-24

申请号：BRPI0708286

申请日：2007-02-23

Applicant: BASF SE

Inventor： MAAS STEFFAN ,  JOHANN THORSTEN ,  KOCH MICHAEL ,  SIRCH TILMAN ,  SCHLITTER STEPHAN ,  RITTINGER STEFAN ,  STEINIGER MICHAEL

IPC: C07C29/141 ,  C07C31/20

Abstract: A process for catalytically hydrogenating methylolalkanals of the general formula in which R1 and R2 are each independently a further methylol group or an alkyl group having from 1 to 22 carbon atoms or an aryl or aralkyl group having from 6 to 33 carbon atoms, in the liquid phase over a hydrogenation catalyst, which comprises setting a pH of from 7.0 to 9.0 in the hydrogenation effluent by adding at least one tertiary amine, an inorganic base or an inorganic or organic acid to the hydrogenation feed.