公开(公告)号：CA2477487A1

公开(公告)日：2005-02-16

申请号：CA2477487

申请日：2004-08-16

Applicant: DEGUSSA

Inventor： DOWE ANDREAS ,  WURSCHE ROLAND ,  BARTZ WILFRIED ,  BAUMANN FRANZ-ERICH ,  GOERING RAINER ,  HIMMELMANN MARTIN

IPC: C08J7/14 ,  C08G69/04 ,  C08G69/16 ,  C08G69/18 ,  C08G69/28 ,  C08G69/48 ,  C08G73/02 ,  C08J3/20 ,  C08K5/098 ,  C08K5/109 ,  C08L77/00 ,  C08L77/02 ,  C08G69/02 ,  C08K5/49

Abstract: Disclosed is a process for increasing a molecular weight of polyamide, which comprises: (A) providing polyamide or a molding composition containing the polyamide and at least one other ingredient, wherein the polyamide contains from 5 to 500 ppm of phosphorous in the form of an acidic compound resulting from a catalyst employed in preparation of the polyamide; and (B) heating the polyamide or the molding composition in the presence of (i) a compound having at least two carbonate units and (ii) a salt of a weak acid in an amount of from 0.001 to 10% by weight based on the polyamide, under conditions effective to increase the molecular weight of the polyamide. By this process, the molecular weight of a wide variety of polyamides may be increased.

公开(公告)号：CA2474992A1

公开(公告)日：2005-01-18

申请号：CA2474992

申请日：2004-07-16

Applicant: DEGUSSA

Inventor： BAUMANN FRANZ-ERICH ,  BARTZ WILFRIED ,  HIMMELMANN MARTIN ,  FARGES OLIVIER

IPC: C08L77/06 ,  B29C45/00 ,  B29C47/00 ,  B29C49/04 ,  C08L23/08 ,  C08L33/14 ,  C08L53/00 ,  C08L77/12 ,  C08L79/00 ,  C08L77/00 ,  B29C49/00 ,  C08L71/00

Abstract: A molding composition, comprising: I. from 97 to 80 parts by weight of a polyetheramide based on a linear aliphatic diamine having from 6 to 14 carbon atoms, a linear aliphatic or aromatic dicarboxylic acid having from 6 to 14 carbon atoms, and a polyetherdiamine which has at least 3 carbon atoms per ether oxygen and has primary amino groups at the chain ends, and II. from 3 to 20 parts by weight of a rubber containing functional groups, each per 100 parts by weight of a total of components I. and II., is suitable for extrusion of moldings such as flexible pipes. The molding composition is resistant to hydrolysis and heat and has high melt viscosity and the resulting moldings, without an external plasticizer, have long-lasting flexibility and good low-temperature impact strength.

公开(公告)号：DE10201903A1

公开(公告)日：2003-07-31

申请号：DE10201903

申请日：2002-01-19

Applicant: DEGUSSA

Inventor： BAUMANN FRANZ-ERICH ,  HIMMELMANN MARTIN ,  BARTZ WILFRIED ,  FARGES OLIVIER

IPC: C08G69/40 ,  C08L23/08 ,  C08L33/06 ,  C08L33/24 ,  C08L77/00 ,  C08L77/06 ,  C08L77/12 ,  C08J5/02 ,  B60T17/04 ,  B60R16/00 ,  B60K11/00 ,  B60K15/01 ,  B60S1/48 ,  B60H1/00 ,  B62D5/06

Abstract: A molding composition comprises (wt.%): (A) a polyetheramide (99.9-95) based on a linear 6-12C aliphatic diamine, a linear 6-12C aliphatic or aromatic dicarboxylic acid and a primary amine-terminated polyetherdiamine with at least3C per ether oxygen atom; and (B) a copolymer (0.1-5) containing acid anhydride or epoxide units (0.8-20). A molding composition comprises (wt.%): (A) a polyetheramide (99.9-95) based on a linear 6-12C aliphatic diamine, a linear 6-12C aliphatic or aromatic dicarboxylic acid and a primary amine-terminated polyetherdiamine with at least3C per ether oxygen atom; and (B) a copolymer (0.1-5) containing: (i) acrylate units of formula (I) (0-85); (ii) imide units of formula (II) (0-80); (iii) acrylic acid units of formula (III) (0-15); (iv) acid anhydride or epoxide units of formula (IVA) or (IVB) respectively (0.8-20); and (v) 0-95% hydrocarbon units of formula (V) (0-95). Alkyl = 1-6C alkyl; R1 - R7 = H, CnH2n+1 or phenyl; m = 0 or 1; and n = 1-6.

公开(公告)号：NO20030255A

公开(公告)日：2003-07-21

申请号：NO20030255

申请日：2003-01-17

Applicant: DEGUSSA

Inventor： HIMMELMANN MARTIN ,  BARTZ WILFRIED ,  BAUMANN FRANZ-ERICH ,  FARGES OLIVIER

IPC: C08G69/40 ,  C08L23/08 ,  C08L33/06 ,  C08L33/24 ,  C08L77/00 ,  C08L77/06

CPC classification number: C08L77/00 ,  C08G69/40 ,  C08L23/08 ,  C08L33/06 ,  C08L33/064 ,  C08L33/068 ,  C08L33/24 ,  C08L77/06 ,  Y10T428/13 ,  Y10T428/1352 ,  Y10T428/139 ,  Y10T428/1397 ,  C08L2666/06 ,  C08L33/00 ,  C08L23/00

公开(公告)号：BR0106163A

公开(公告)日：2002-08-13

申请号：BR0106163

申请日：2001-12-19

Applicant: DEGUSSA

Inventor： BARTZ WILFRIED ,  RIES HANS ,  SCHMITZ GUIDO ,  HAEGER HARALD

IPC: B32B27/08 ,  B32B27/28 ,  B32B27/34 ,  C08L77/00 ,  C08L77/02 ,  C08L77/06 ,  F16L9/12

Abstract: A layered composite which includes the following layers (I) and (II), wherein layer (I) includes (a) from 0 to 80 part by weight of at least one particular polyamide; (b) from 0 to 100 parts by weight of at least one polyamine-polyamide copolymer; and (c) from 0 to 80 parts by weight of at least one particular polyamide which is different from (a), wherein various monomer units are present in at least 20 parts by weight of the entirety of (a) and (b) and various other monomer units are present in at least 20 parts by weight of the entirety of (b) and (c); and layer (II) includes at least one ethylene-vinyl alcohol copolymer.

公开(公告)号：DE10064338A1

公开(公告)日：2002-06-27

申请号：DE10064338

申请日：2000-12-21

Applicant: DEGUSSA

Inventor： HAEGER HARALD ,  SCHMITZ GUIDO ,  RICHTER RALF ,  BARTZ WILFRIED ,  BAUMANN FRANZ-ERICH ,  HIMMELMANN MARTIN ,  OENBRINK GEORG

IPC: C08J5/00 ,  C08G69/00 ,  C08G73/02 ,  C08L77/02 ,  C08L77/06 ,  C08L79/02 ,  C08G69/36 ,  C08J5/02 ,  B32B1/08 ,  B29C49/00

Abstract: A molding composition of at least 50% by weight of a polyamine-polyamide copolymer obtained from 0.05 to 2.5% by weight of a polyamine having at least 4 nitrogen atoms and having a viscosity of at least 5 000 Pa.s at 250° C. and at a shear rate of 0.1 l/s, and having a viscosity ratio of at least 7 at 250° C., when the melt viscosities at shear rates of 0.1 l/s and 100 l/s are compared with one another, has high melt stiffness and is easy to cut, and performs well in blow molding.

公开(公告)号：NO20016312A

公开(公告)日：2002-06-24

申请号：NO20016312

申请日：2001-12-21

Applicant: DEGUSSA

Inventor： BARTZ WILFRIED ,  SCHMITZ GUIDO ,  HAEGER HARALD ,  RIES HANS

IPC: B32B27/08 ,  B32B27/28 ,  B32B27/34 ,  C08L77/00 ,  C08L77/02 ,  C08L77/06

CPC classification number: B32B27/34 ,  B32B1/02 ,  B32B1/08 ,  B32B3/28 ,  B32B27/08 ,  B32B27/28 ,  B32B27/306 ,  B32B27/32 ,  B32B2250/03 ,  B32B2250/24 ,  B32B2250/40 ,  B32B2270/00 ,  B32B2272/00 ,  B32B2307/202 ,  B32B2307/308 ,  B32B2307/50 ,  B32B2307/714 ,  B32B2307/7242 ,  B32B2307/7244 ,  B32B2307/7265 ,  B32B2323/04 ,  B32B2331/04 ,  B32B2377/00 ,  B32B2439/40 ,  B32B2439/70 ,  B32B2597/00 ,  B32B2605/08 ,  C08L77/00 ,  C08L77/02 ,  C08L77/06 ,  Y10T428/1352 ,  Y10T428/1379 ,  Y10T428/139 ,  Y10T428/1393 ,  Y10T428/31725 ,  Y10T428/31732 ,  Y10T428/3175

公开(公告)号：NO20016311L

公开(公告)日：2002-06-24

申请号：NO20016311

申请日：2001-12-21

Applicant: DEGUSSA

Inventor： HIMMELMANN MARTIN ,  SCHMITZ GUIDO ,  OENBRINK GEORG ,  HAEGER HARALD ,  BARTZ WILFRIED ,  RICHTER RALF ,  BAUMANN FRANZ-ERICH

IPC: C08J5/00 ,  C08G69/00 ,  C08G73/02 ,  C08L77/02 ,  C08L77/06 ,  C08L79/02 ,  C08L77/00 ,  B32B27/34

Abstract: A molding composition of at least 50% by weight of a polyamine-polyamide copolymer obtained from 0.05 to 2.5% by weight of a polyamine having at least 4 nitrogen atoms and having a viscosity of at least 5 000 Pa.s at 250° C. and at a shear rate of 0.1 l/s, and having a viscosity ratio of at least 7 at 250° C., when the melt viscosities at shear rates of 0.1 l/s and 100 l/s are compared with one another, has high melt stiffness and is easy to cut, and performs well in blow molding.

公开(公告)号：NO20016311A

公开(公告)日：2002-06-24

申请号：NO20016311

申请日：2001-12-21

Applicant: DEGUSSA

Inventor： HIMMELMANN MARTIN ,  SCHMITZ GUIDO ,  OENBRINK GEORG ,  HAEGER HARALD ,  BARTZ WILFRIED ,  RICHTER RALF ,  BAUMANN FRANZ-ERICH

IPC: C08J5/00 ,  C08G69/00 ,  C08G73/02 ,  C08L77/02 ,  C08L77/06 ,  C08L79/02 ,  B32B27/34 ,  C08L77/00

CPC classification number: C08G73/028 ,  C08L79/02 ,  Y10T428/1352 ,  Y10T428/31725 ,  Y10T428/31732

公开(公告)号：CA2351152A1

公开(公告)日：2001-12-23

申请号：CA2351152

申请日：2001-06-21

Applicant: DEGUSSA

Inventor： OENBRINK GEORG ,  HAGER HARALD ,  BARTZ WILFRIED ,  BAUMANN FRANZ-ERICH ,  SCHMITZ GUIDO

IPC: B60S5/02 ,  B60K15/01 ,  B60K15/03 ,  C08J5/00 ,  C08L23/08 ,  C08L53/02 ,  C08L77/00 ,  C08L77/02 ,  C08L77/06 ,  F16K27/00 ,  C08L35/00 ,  C08L51/04

Abstract: A molding which comprises the following components: I. from 60 to 96.5% parts by weight of polyamide, II. from 3 to 39.5 parts by weight of an impact- modifying component which contains anhydride groups, III. from 0.5 to 20 parts by weight of a copolymer which contains units of the monomers a) .alpha.-olefin, b) acrylic compound, and also c) olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline or oxazinone, where the total of the parts by weight of components I, II and III is 100, and where moreover the polyamide has an excess of amino end groups, has improved low- temperature impact strength, even if the molding composition also comprises a plasticizer.