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    31.
    发明专利
    未知

    公开(公告)号：DE1769765A1

    公开(公告)日：1971-09-16

    申请号：DE1769765

    申请日：1968-07-10

    Applicant: HOECHST AG

    Inventor： MAUZ OTTO DR ,  PRINZ EBERHARD DR

    IPC: C08K5/134 ,  C08K5/372 ,  C08F29/02

    Abstract: 1,238,600. Bis-phenol-A derivatives. FARBWERKE HOECHST A.G. 10 July, 1969 [10 July, 1968], No. 34772/69. Heading C2C. [Also in Division C3] Tetraphenols of formula where R 1 is H or C 1-4 alkyl and n is 1 or 2 may be prepared by esterifying the diol bis [4-(#- hydroxyethoxy) phenyl] dimethyl methane with the corresponding acid, or with acetoacetic acid or levulinic acid and phenol or a substituted phenol. In examples (1) bis[3,3-(4 1 -hydroxy- 3 1 -t. butylphenyl) butanoic acid ester of bis (#- hydroxyethyl) dioxydiphenyl dimethyl methane is prepared by reacting o-t. butylphenol with the acetoacetic acid ester of said diol and (2) bis [4,4-(4 1 -hydroxy-3 1 -sec. butylphenyl)] pentanoic acid ester of said diol is prepared by esterification of the diol with the acid in xylene in the presence of p-toluenesulphonic acid as catalyst.

    32.
    发明专利
    未知

    公开(公告)号：DE1769764A1

    公开(公告)日：1971-09-16

    申请号：DE1769764

    申请日：1968-07-10

    Applicant: HOECHST AG

    Inventor： MAUZ OTTO DR ,  PRINZ EBERHARD DR

    IPC: C07F9/40 ,  C08K5/372 ,  C08K5/5333 ,  C08F29/02

    Abstract: 1,224,108. Stabilizing polyolefins. FARBWERKE HOECHST A.G. 10 July, 1969 [10 July, 1968], No. 34771/69. Heading C3P. [Also in Division C2] Moulding compositions comprise a polyolefin and 0À005 to 5 weight per cent of each component of a stabilizer composition of (a) and (b) in a weight ratio of (a) to (b) of 1: 9 to 9 :1, wherein (a) is a phosphorus containing bisphenol of formula where R is hydrogen or C 1-4 alkyl and R 1 and R 2 are C 2-20 alkyl or phenyl; and (b) is R 3 -S-S-R 4 , where R 3 and R 4 are C 8-20 alkyl. Specified polyolefins are polyethylene, polypropylene, polybutene and poly-4-methylpentene; The compositions may be moulded to form bottles, machine parts, pipes and fibres. Examples describe the stabilizing of polypropylene with di-(ootadecyl) disulphide.

    CROSS-LINKED POLYMERS, PROCESS FOR THEIR MANUFACTURE AND USE THEREOF
    34.
    发明专利
    CROSS-LINKED POLYMERS, PROCESS FOR THEIR MANUFACTURE AND USE THEREOF 未知

    公开(公告)号：DE3476405D1

    公开(公告)日：1989-03-02

    申请号：DE3476405

    申请日：1984-12-06

    Applicant: HOECHST AG

    Inventor： MAUZ OTTO DR ,  NOETZEL SIEFRIED DR ,  NEUMANN BERNHARD DR

    IPC: A61K38/46 ,  A61K39/00 ,  A61K39/44 ,  A61K47/00 ,  A61K47/32 ,  B01D15/08 ,  B01J20/26 ,  B01J20/281 ,  B01J20/285 ,  C08F2/00 ,  C08F2/18 ,  C08F8/00 ,  C08F8/12 ,  C08F16/02 ,  C08F16/32 ,  C08F18/02 ,  C08F22/18 ,  C08F26/00 ,  C08F26/10 ,  C08F216/06 ,  C08F216/12 ,  C08F218/00 ,  C08F218/02 ,  C08F218/04 ,  C08F218/08 ,  C08F226/06 ,  C08J9/224 ,  C12N11/08 ,  G01N30/88 ,  G01N33/543

    Abstract: For the contracting states : BE, CH, DE, FR, GB, IT, LI, LU, NL, SE 1. A crosslinked polymer in the form of beads which substantially comprises vinyl acylate units and units of a crosslinking agent which has the formulae see diagramm : EP0150350,P12,F1 and/or see diagramm : EP0150350,P12,F2 where R1 and R2 in the formula (I) can be identical or different and each denotes vinyl-, 1-acyloxyvinyl, allyl- or 2-acyloxyallyl, A represents a divalent hydrocarbon radical of 2 to 8 carbon atoms, B in the formula (II) stands for a divalent hydrocarbon radical of 1 to 8 carbon atoms and X denotes acyloxy, the amount of theses crosslinking agent units accounting for 1 to 60 % by weight of the polymer, the acyloxy groups of the vinyl acylate units being present as such or having been partially or completely replaced by hydroxyl groups, and the average particle size of the beads being 20 to 800 mu m and the mean pore diameter being 2 to 10,000 nm. For the contracting state AT 1. A process for preparing a crosslinked polymer in the form of beads by copolymerizing vinyl acylate with a crosslinking agent and, if propriate, a further monomer copolymerizable with the vinyl acylate in ther presence of a dispersion medium and if desired partially or completely hydrolyzing the resulting polymer, wherein the crosslinking agent has the formulae see diagramm : EP0150350,P12,F1 and/or see diagramm : EP0150350,P12,F2 where R1 and R2 in the formula (I) can be identical or different and each denotes vinyl-, 1-acyloxyvinyl, allyl- or 2-acyloxyallyl, A represents a divalent hydrocarbon radical of 2 to 8 carbon atoms, B in the formula (II) stands for a divalent hydrocarbon radical of 1 to 8 carbon atoms and X denotes acyloxy, and the beads obtained have an average particle size of 10 to 800 mu m and an average pore diameter of 2 to 10,000 nm.

    37.
    发明专利
    未知

    公开(公告)号：BR8406380A

    公开(公告)日：1985-10-08

    申请号：BR8406380

    申请日：1984-12-12

    Applicant: HOECHST AG

    Inventor： MAUZ OTTO DR ,  NOETZEL SIEGFRIED DR ,  NEUMANN BERNHARD DR

    IPC: A61K38/46 ,  A61K39/00 ,  A61K39/44 ,  A61K47/00 ,  A61K47/32 ,  B01D15/08 ,  B01J20/26 ,  B01J20/281 ,  B01J20/285 ,  C08F2/00 ,  C08F2/18 ,  C08F8/00 ,  C08F8/12 ,  C08F16/02 ,  C08F16/32 ,  C08F18/02 ,  C08F22/18 ,  C08F26/00 ,  C08F26/10 ,  C08F216/06 ,  C08F216/12 ,  C08F218/00 ,  C08F218/02 ,  C08F218/04 ,  C08F218/08 ,  C08F226/06 ,  C08J9/224 ,  C12N11/08 ,  G01N30/88 ,  G01N33/543 ,  C08J3/24 ,  C08K5/21 ,  C08K5/11

    Abstract: For the contracting states : BE, CH, DE, FR, GB, IT, LI, LU, NL, SE 1. A crosslinked polymer in the form of beads which substantially comprises vinyl acylate units and units of a crosslinking agent which has the formulae see diagramm : EP0150350,P12,F1 and/or see diagramm : EP0150350,P12,F2 where R1 and R2 in the formula (I) can be identical or different and each denotes vinyl-, 1-acyloxyvinyl, allyl- or 2-acyloxyallyl, A represents a divalent hydrocarbon radical of 2 to 8 carbon atoms, B in the formula (II) stands for a divalent hydrocarbon radical of 1 to 8 carbon atoms and X denotes acyloxy, the amount of theses crosslinking agent units accounting for 1 to 60 % by weight of the polymer, the acyloxy groups of the vinyl acylate units being present as such or having been partially or completely replaced by hydroxyl groups, and the average particle size of the beads being 20 to 800 mu m and the mean pore diameter being 2 to 10,000 nm. For the contracting state AT 1. A process for preparing a crosslinked polymer in the form of beads by copolymerizing vinyl acylate with a crosslinking agent and, if propriate, a further monomer copolymerizable with the vinyl acylate in ther presence of a dispersion medium and if desired partially or completely hydrolyzing the resulting polymer, wherein the crosslinking agent has the formulae see diagramm : EP0150350,P12,F1 and/or see diagramm : EP0150350,P12,F2 where R1 and R2 in the formula (I) can be identical or different and each denotes vinyl-, 1-acyloxyvinyl, allyl- or 2-acyloxyallyl, A represents a divalent hydrocarbon radical of 2 to 8 carbon atoms, B in the formula (II) stands for a divalent hydrocarbon radical of 1 to 8 carbon atoms and X denotes acyloxy, and the beads obtained have an average particle size of 10 to 800 mu m and an average pore diameter of 2 to 10,000 nm.

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