公开(公告)号：CA1086325A

公开(公告)日：1980-09-23

申请号：CA258387

申请日：1976-08-04

Applicant: STANDARD OIL CO OHIO

Inventor： SURESH DEV D ,  BREMER NOEL J ,  GRASSELLI ROBERT K

IPC: C07D307/60 ,  B01J23/00 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25

Abstract: Catalysts comprising the combined oxides of vanadium and at least one element selected from the group consisting of boron, niobium, tantalum, antimony, tungsten and chromium have been found to be especially effective in the oxidation of n-butane, n-butenes and butadiene, or a mixture thereof with molecular oxygen in the vapor phase to yield maleic anhydride. The catalysts of the present invention may be further promoted with additional elements to enhance activity, stability and selectivity. The reaction with n-butane gives an especially pure product in good yield and selectivity.

公开(公告)号：CS200531B2

公开(公告)日：1980-09-15

申请号：CS639978

申请日：1978-10-03

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  WHITE JAMES F ,  MILBERGER ERNEST C

IPC: C07D307/60

公开(公告)号：RO72507A

公开(公告)日：1980-05-15

申请号：RO9366778

申请日：1978-03-29

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  BREMER NOEL J ,  WONG EUNICE K T

IPC: C07D307/60 ,  B01J21/06 ,  B01J27/00 ,  B01J27/18 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  C07C57/14 ,  B01J23/76

Abstract: Vanadium-free catalysts consisting essentially of oxides of titanium and phosphorus have been found to be especially effective in the oxidation of n-butane, n-butenes and 1,3-butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in good yield and selectivity.

公开(公告)号：NO781155A

公开(公告)日：1978-10-05

申请号：NO781155

申请日：1978-04-03

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  BREMER NOEL J ,  WONG EUNICE K T

IPC: C07D307/60 ,  B01J21/06 ,  B01J27/00 ,  B01J27/18 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  C07C

CPC classification number: B01J21/063 ,  B01J27/1802 ,  C07C51/215 ,  C07C51/25 ,  C07C51/252 ,  C07C57/145

公开(公告)号：MY132015A

公开(公告)日：2007-09-28

申请号：MYPI9502771

申请日：1995-09-19

Applicant: STANDARD OIL CO

Inventor： BREMER NOEL J ,  TROTT LOUIS R ,  WOODBURY DAVID R

IPC: B01J27/28 ,  B01J8/08 ,  B01J27/198 ,  B01J38/00 ,  C07C51/215 ,  C07C57/145 ,  C10G11/18

Abstract: THE PRESENT INVENTION RELATES TO IMPROVEMENTS OF FLUID BED CATALYSTS. MORE PARTICULARLY, THE PRESENT INVENTION RELATES TO IMPROVEMENTS OF FLUID BED OXIDATION CATALYSTS USEFUL IN THE PREPARATION OF MALEIC ANHYDRIDE FROM C4 HYDROCARBONS, INCLUDING N-BUTANE. THE PRESENT INVENTION INCLUDES A PROCESS OF CONTACTING A FLUID BED CATALYST WITH A REACTIVATING AGENT IN A CATALYST STANDPIPE. THE PRESENT INVENTION ALSO PROVIDES A CATALYST CONTAINING THE MIXED OXIDES OF VANADIUM AND PHOSPHORUS, TREATED USING THE ABOVE PROCESS. THE PRESENT INVENTION FURTHER PROVIDES A PROCESS FOR PRODUCING MALEIC ANHYDRIDE, UTILIZING THE CATALYST PREPARED USING THE ABOVE PROCESS. THE PRESENT INVENTION ADDITIONALLY PROVIDES FOR A REACTOR STANDPIPE, UTILIZED FOR REGENERATING CATALYST ACCORDING TO THE ABOVE PROCESS.

公开(公告)号：MX9602020A

公开(公告)日：1997-11-29

申请号：MX9602020

申请日：1996-05-29

Applicant: STANDARD OIL CO

Inventor： BREMER NOEL J ,  GOEDEN GARY V ,  WOODBURY DAVID R

IPC: C08F06/10

Abstract: Un proceso para la destruccion de residuos orgánicos y amoníaco proveniente de agua residual de una planta de acrilonitrilo, que comprende poner en contacto agua residual volatilizada con un catalizador a temperatura elevada para convertir los compuestos orgánicos volátiles y el amoníaco en una mezcla que comprende hidrogeno, nitrogeno y dioxido de carbono los cuales se separan y eliminan de la corriente, produciendo una corriente acuosa purificada, substancialmente libre de compuesto orgánico y de amoníaco.

公开(公告)号：ZA964252B

公开(公告)日：1996-12-04

申请号：ZA964252

申请日：1996-05-27

Applicant: STANDARD OIL CO OHIO

Inventor： GOEDEN GARY V ,  BREMER NOEL J ,  WOODBURY DAVID R

IPC: C02F20060101 ,  C02F

公开(公告)号：CA1197229A

公开(公告)日：1985-11-26

申请号：CA431131

申请日：1983-06-24

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  DRIA DENNIS E ,  BLUM PATRICIA R ,  MILBERGER ERNERST C ,  NICHOLAS MARK L

IPC: C07D307/60 ,  B01J27/198 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25

Abstract: ATTRITION RESISTANT MICROSPHEROIDAL FLUID BED CATALYSTS CONTAINING THE MIXED OXIDES OF VANADIUM AND PHOSPHORUS A process is provided for the preparation of attrition resistant, microspheroidal fluid bed catalysts comprising the mixed oxides of vanadium and phosphorus in which a vanadium phosphorus mixed oxided catalyst precursor is densified, comminuted, formed into fluidizable particles and calcined under fluidization-type conditions. The present invention further provides the attrition resistant fluidizable catalysts prepared by the inventive process, and further provides a process for utilizing such attrition resistant catalysts in the production of maleic anhydride in the vapor phase by the oxidation of 4 carbon atom hydrocarbons.

公开(公告)号：CA1157455A

公开(公告)日：1983-11-22

申请号：CA380215

申请日：1981-06-19

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  DRIA DENNIS E

IPC: C07D307/60 ,  B01J23/22 ,  B01J27/18 ,  B01J27/198 ,  C01B25/37 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  B01J27/14

Abstract: The present invention provides a process for the preparation of oxidation catalysts containing mixed oxides of vanadium and phosphorus, which catalysts are particularly effective in the oxidation of n-butane, n-butanes, 1,3-butadiene or a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce high yields of maleic anhydride with good selectivity. A vanadium compound is introduced into an olefinic oxygenated organic liquid medium, a phosphorus-containing compound is added to the medium, reduction of at least a portion of the vanadium to a +4 valence state is effected either prior to or subsequent to the addition of the phosphorus-containing compound, and the resulting vanadium-phosphorus oxide catalyst precursor is recovered, dried and calcined.

公开(公告)号：CA1150232A

公开(公告)日：1983-07-19

申请号：CA370280

申请日：1981-02-06

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  BREMER NOEL J ,  DRIA DENNIS E

IPC: C07D307/60 ,  B01J23/00 ,  B01J23/22 ,  B01J27/18 ,  B01J27/198 ,  C01B25/37 ,  C07B61/00 ,  C07C51/215

Abstract: The present invention provides improved oxidation catalysts containing mixed oxides of vanadium and phosphorus and the method for the preparation thereof, which catalysts are particularly effective in the oxidation of n-butane, nbutenes, 1,3-butadiene or a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce excellent yields of maleic anhydride with very good selectivity. At least one vanadium compound, a substantial portion of which is in the pentavalent state, and at least one phosphorus-containing compound is added to an organic liquid medium capable of reducing at least a portion of the vanadium to a +4 valence state, to form a reaction mixture. Partial reduction of the vanadium is effected in the presence of the phosphorus-containing compound and a highly ordered and uniform mixed vanadium phosphorus oxide-containing catalyst precursor is formed.