公开(公告)号：DE2702606A1

公开(公告)日：1978-07-27

申请号：DE2702606

申请日：1977-01-22

Applicant: STANDARD OIL CO OHIO

Inventor： DOLHYJ SERGE R ,  MILBERGER ERNEST C

IPC: B01J23/28 ,  B01J23/30 ,  C07C51/25 ,  C07D307/60 ,  C07C51/32 ,  C07C57/04

Abstract: Oxidn. catalyst YaSbbMocVdZeOx (I) is used for the improved synthesis of maleic anhydride from 1,3-butadiene and molecular oxygen (II) at 250-600 degrees C. In (I), Y is Li and/or Ce; Z is W, Mg, Al or Ni as the metal or its oxide; a and d = 0.01-1.0; b and c = 1-9; e = 0-1; x = a number which satisfies the valence requirements of the other elements present. Improved yields of clean maleic anhydride and a decreased amt. of waste by-prods. are obtd. by using (I). In an example, 1,3-butadiene and air were passed over Lio.1sbMo3Vo.1Ox + W degrees 0.06 in a stainless steel tube. The heating jacket around the tube was at 360-371 degrees C and the contact time was 3.3 secs.

公开(公告)号：RO62806A

公开(公告)日：1978-05-15

申请号：RO7503173

申请日：1973-06-05

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  DOLHYJ SERGE R

IPC: B01J23/16

公开(公告)号：DE2720652A1

公开(公告)日：1977-12-01

申请号：DE2720652

申请日：1977-05-07

Applicant: STANDARD OIL CO OHIO

Inventor： DOLHYJ SERGE R ,  EVANS SANDRA R ,  MILBERGER ERNEST C

IPC: C07D307/60 ,  B01J23/00 ,  B01J23/22 ,  B01J23/28 ,  B01J27/00 ,  B01J27/199 ,  B01J37/02 ,  C07B61/00 ,  C07C51/31

Abstract: Very desirable temperature control and selectivity are obtained in the oxidation of benzene to maleic anhydride using an oxidation catalyst of an essentially inert support of at least 20 microns containing on its outer surface a coating of a catalytically active oxide material or a catalytically active oxide material and an oxide support.

公开(公告)号：CA1014572A

公开(公告)日：1977-07-26

申请号：CA163202

申请日：1973-02-08

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D ,  MILBERGER ERNEST C

IPC: C07C27/14 ,  B01J21/00 ,  B01J23/00 ,  B01J23/28 ,  B01J23/30 ,  B01J23/31 ,  B01J23/32 ,  B01J23/88 ,  B01J23/887 ,  B01J27/00 ,  B01J27/057 ,  C07B61/00 ,  C07C27/00 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C47/20 ,  C07C47/22 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C07D307/79 ,  C07D307/80 ,  C07D307/82 ,  C07D307/83 ,  C07D307/92 ,  C07D333/60 ,  C07D333/68 ,  D06L3/12

公开(公告)号：CA1202950A

公开(公告)日：1986-04-08

申请号：CA414316

申请日：1982-10-27

Applicant: STANDARD OIL CO OHIO

Inventor： BLUM PATRICIA R ,  MILBERGER ERNEST C ,  NICHOLAS MARK L ,  ZOCK PATRICIA A

IPC: C07D307/60 ,  B01J27/14 ,  B01J27/198 ,  B01J27/28 ,  B01J37/16 ,  B01J38/30 ,  C07B61/00 ,  C07C51/215

Abstract: A process for activating fluid bed catalysts useful for producing maleic anhydride from 4 carbon atom hydrocarbons is provided including contacting the fluidized catalyst containing the mixed oxides of vanadium and phosphorus with oxygen and a reducing gas at least partially combustible with oxygen at elevated temperatures sufficient to cause such combustion, wherein the molar ratio of reducing gas to oxygen is below the stoichiometric ratio required for complete combustion of the reducing gas. Also provided are catalysts activated by the process of the invention, as well as a process for producing maleic anhydride utilizing the catalysts thus activated.

公开(公告)号：CA1178264A

公开(公告)日：1984-11-20

申请号：CA389300

申请日：1981-11-03

Applicant: STANDARD OIL CO OHIO

Inventor： BLUM PATRICIA R ,  MILBERGER ERNEST C ,  BREMER NOEL J ,  DRIA DENNIS E

IPC: C07D307/60 ,  B01J23/22 ,  B01J27/18 ,  B01J27/198 ,  C01B25/37 ,  C01B25/45 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  B01J27/14

Abstract: The present invention provides a process for the preparation of oxidation catalysts containing mixed oxides of vanadium and phosphorus, which catalysts are particularly effective in the oxidation of n-butane, n-butanes, 1.3-butadiene of a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce high yields of maleic anhydride with good selectivity. A vanadium compound is introduced into a liquid medium, a mixed phosphorus component comprising orthophosphoric acid and pyrophosphoric acid is added to the liquid medium, reduction of at least a portion of the vanadium to a +4 valence state is effected either prior to or subsequent to the addition of the mixed phosphorus component, and the resulting vanadium-phosphorus oxide catalyst precursor is recovered, dried and calcined.

公开(公告)号：MX145572A

公开(公告)日：1982-03-08

申请号：MX17297678

申请日：1978-04-03

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  BREMER NOEL J ,  WONG EUNICE K T

IPC: C07D307/60 ,  B01J21/06 ,  B01J27/00 ,  B01J27/18 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  C07C51/20

Abstract: Vanadium-free catalysts consisting essentially of oxides of titanium and phosphorus have been found to be especially effective in the oxidation of n-butane, n-butenes and 1,3-butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in good yield and selectivity.

公开(公告)号：RO71796A

公开(公告)日：1981-08-17

申请号：RO8067674

申请日：1974-12-03

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  MILBERGER ERNEST C ,  DOLHYJ SERGE R

IPC: C07D307/60 ,  B01J23/22 ,  B01J27/00 ,  B01J27/198 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  C07C57/14

Abstract: Catalysts containing the oxides of vanadium, phosphorus and uranium have been found to be especially effective in the oxidation of n-butane, n-butenes and butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in high yield.

公开(公告)号：CS200530B2

公开(公告)日：1980-09-15

申请号：CS639878

申请日：1978-10-03

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  WHITE JAMES F ,  MILBERGER ERNEST C

IPC: C07D307/60

公开(公告)号：CS194698B2

公开(公告)日：1979-12-31

申请号：CS228978

申请日：1977-05-02

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID G ,  TERRILL DAVID B ,  MILBERGER ERNEST C ,  WOODBURY DAVID R ,  DOLHYJ SERGE R

IPC: B01J23/16 ,  C07C57/04