公开(公告)号：ID26625A

公开(公告)日：2001-01-25

申请号：ID20001464

申请日：1999-02-01

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： ARGYROPOULOS JOHN N ,  BRYANT DAVID ROBERT ,  MORRISON DONALD LEE ,  STOCKMAN KENNETH ELWOOD ,  ABATJOGLOU ANTHONY GEORGE

IPC: B01J31/18 ,  B01J31/40 ,  C07B63/00 ,  C07C45/50 ,  C07C45/80 ,  C07C49/92 ,  C07C51/373 ,  C07C51/48 ,  C07C59/147 ,  C07F9/02 ,  C07F9/50 ,  C07F9/655 ,  C07F9/6574

Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a polar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a nonpolar solvent to obtain by phase separation a polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said polar solvent and a nonpolar phase comprising said one or more products and nonpolar solvent, and (2) recovering said nonpolar phase from said polar phase; wherein said organophosphorus ligand has a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 10, and said one or more products have a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 0.5.

公开(公告)号：CZ20002802A3

公开(公告)日：2000-12-13

申请号：CZ20002802

申请日：1999-02-01

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： ARGYROPOULOS JOHN N ,  BRYANT DAVID ROBERT ,  MORRISON DONALD LEE ,  STOCKMAN KENNETH ELWOOD ,  ABATJOGLOU ANTHONY GEORGE

IPC: B01J31/18 ,  B01J31/40 ,  C07B63/00 ,  C07C45/50 ,  C07C45/80 ,  C07C49/92 ,  C07C51/373 ,  C07C51/48 ,  C07C59/147 ,  C07F9/02 ,  C07F9/50 ,  C07F9/655 ,  C07F9/6574

Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a polar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a nonpolar solvent to obtain by phase separation a polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said polar solvent and a nonpolar phase comprising said one or more products and nonpolar solvent, and (2) recovering said nonpolar phase from said polar phase; wherein said organophosphorus ligand has a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 10, and said one or more products have a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 0.5.

公开(公告)号：CZ20002800A3

公开(公告)日：2000-12-13

申请号：CZ20002800

申请日：1999-02-01

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： ARGYROPOULOS JOHN N ,  BRYANT DAVID ROBERT ,  MORRISON DONALD LEE ,  STOCKMANN KENNETH ELWOOD

IPC: B01J31/18 ,  B01J31/40 ,  C07B63/00 ,  C07C45/50 ,  C07C45/80 ,  C07C47/02 ,  C07C51/373 ,  C07C51/48 ,  C07C59/147 ,  C07F9/02 ,  C07F9/144 ,  C07F9/145 ,  C07F9/50 ,  C07F9/6574

Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a nonpolar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a polar solvent to obtain by phase separation a non-polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said nonpolar solvent and a polar phase comprising said one or more products and polar solvent, and (2) recovering said polar phase from said nonpolar phase; wherein said organophosphorus ligand has a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 5, and said one or more products have a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 0.5.

公开(公告)号：AU722459B2

公开(公告)日：2000-08-03

申请号：AU1328797

申请日：1996-12-05

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： BRYANT DAVID ROBERT ,  NICHOLSON JAMES CLAIR ,  BUNNING DONALD LEROY ,  EISENSCHMID THOMAS CARL ,  MORRISON DONALD LEE

IPC: C07B61/00 ,  B01J19/18 ,  B01J27/18 ,  B01J31/02 ,  B01J31/18 ,  B01J31/22 ,  B01J31/40 ,  B01J38/74 ,  C07C45/49 ,  C07C45/50 ,  C07C47/02 ,  C07C51/00 ,  C07C51/255 ,  C07C51/265 ,  C07C51/42 ,  C07C51/43 ,  C07C63/00 ,  C07C63/15 ,  C07C63/26 ,  C07F9/02 ,  C07F9/141 ,  C07F9/145 ,  C07F9/50 ,  C07F9/6571 ,  C07F9/6574 ,  C07F15/00 ,  F04D25/08 ,  F04D29/28

Abstract: This invention relates to a process which comprises reacting one or more reactants in the presence of a metal-organophosphite ligand complex catalyst and dissolved water and optionally free organophosphite ligand to produce a reaction product fluid comprising one or more products, wherein said process is conducted in the presence of carbon dioxide in an amount sufficient not to effect substantial degradation of any said organophosphite ligand and/or substantial deactivation of said metal-organophosphite ligand complex catalyst.

公开(公告)号：AU2569299A

公开(公告)日：1999-08-16

申请号：AU2569299

申请日：1999-02-01

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： ARGYROPOULOS JOHN N ,  BRYANT DAVID ROBERT ,  MORRISON DONALD LEE ,  STOCKMAN KENNETH ELWOOD ,  ABATJOGLOU ANTHONY GEORGE

IPC: B01J31/18 ,  B01J31/40 ,  C07B63/00 ,  C07C45/50 ,  C07C45/80 ,  C07C49/92 ,  C07C51/373 ,  C07C51/48 ,  C07C59/147 ,  C07F9/02 ,  C07F9/50 ,  C07F9/655 ,  C07F9/6574

Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a polar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a nonpolar solvent to obtain by phase separation a polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said polar solvent and a nonpolar phase comprising said one or more products and nonpolar solvent, and (2) recovering said nonpolar phase from said polar phase; wherein said organophosphorus ligand has a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 10, and said one or more products have a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 0.5.

公开(公告)号：ZA9900775B

公开(公告)日：1999-08-02

申请号：ZA9900775

申请日：1999-02-01

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： ARGYROPOULOS JOHN N ,  MORRISON DONALD LEE ,  ABATJOGLOU ANTHONY GEORGE ,  BRYANT DAVID ROBERT ,  STOCKMAN KENNETH ELWOOD

IPC: B01J31/18 ,  B01J31/40 ,  C07B63/00 ,  C07C45/50 ,  C07C45/80 ,  C07C49/92 ,  C07C51/373 ,  C07C51/48 ,  C07C59/147 ,  C07F9/02 ,  C07F9/50 ,  C07F9/655 ,  C07F9/6574 ,  C07B ,  C07C

CPC classification number: B01J31/0267 ,  B01J31/0259 ,  B01J31/185 ,  B01J31/2208 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/2457 ,  B01J31/2495 ,  B01J31/4015 ,  B01J31/4046 ,  B01J31/4053 ,  B01J2231/32 ,  B01J2231/321 ,  B01J2231/52 ,  B01J2231/641 ,  B01J2531/822 ,  C07C45/50 ,  C07C45/80 ,  C07C51/48 ,  C07F9/025 ,  Y02P20/582 ,  Y02P20/584 ,  C07C47/02

公开(公告)号：CA2239696A1

公开(公告)日：1997-06-12

申请号：CA2239696

申请日：1996-12-05

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： NICHOLSON JAMES CLAIR ,  BUNNING DONALD LEROY ,  BRYANT DAVID ROBERT ,  EISENSCHMID THOMAS CARL ,  MORRISON DONALD LEE

IPC: C07B61/00 ,  B01J19/18 ,  B01J27/18 ,  B01J31/02 ,  B01J31/18 ,  B01J31/22 ,  B01J31/40 ,  B01J38/74 ,  C07C45/49 ,  C07C45/50 ,  C07C47/02 ,  C07C51/00 ,  C07C51/255 ,  C07C51/265 ,  C07C51/42 ,  C07C51/43 ,  C07C63/00 ,  C07C63/15 ,  C07C63/26 ,  C07F9/02 ,  C07F9/141 ,  C07F9/145 ,  C07F9/50 ,  C07F9/6571 ,  C07F9/6574 ,  C07F15/00 ,  F04D25/08 ,  F04D29/28 ,  C07D333/22 ,  C07C47/228 ,  C07C47/277 ,  C07C67/347 ,  C07D209/46 ,  C07C69/716

Abstract: This invention relates to a process which comprises reacting one or more reactan ts in the presence of a metal-organophosphite ligand complex catalyst and dissolved water and optionally free organophosphite ligand to produce a reaction product fluid comprising or more products, wherein said process is conducted in the presence of carbon dioxide in an amount sufficient not to effect substantial degradetion of any said organophosphite ligand and/or substantial deactivation of said metal -organophosphite ligand complex catalyst.

公开(公告)号：AT348658T

公开(公告)日：2007-01-15

申请号：AT01916655

申请日：2001-03-14

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： ARGYROPOULOS JOHN NICHOLAS ,  KANEL JEFFREY SCOTT ,  TULCHINSKY MICHAEL LEO ,  MILLER DAVID JAMES ,  MORRISON DONALD LEE ,  FOLEY PAUL ,  BRYANT DAVID ROBERT

IPC: B01J31/40 ,  B01J31/00 ,  B01J38/00 ,  C07B61/00 ,  C07B63/00 ,  C07C29/136 ,  C07C31/20 ,  C07C67/31 ,  C07C67/313 ,  C07C67/58 ,  C07C69/675 ,  C07C69/716 ,  C07C227/02 ,  C07C227/08 ,  C07C229/08

Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a polar solvent and a nonpolar solvent by phase separation wherein(i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.

公开(公告)号：CA2319780C

公开(公告)日：2006-05-23

申请号：CA2319780

申请日：1999-02-01

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： MORRISON DONALD LEE ,  ARGYROPOULOS JOHN N ,  ABATJOGLOU ANTHONY GEORGE ,  BRYANT DAVID ROBERT ,  STOCKMAN KENNETH

IPC: B01J31/18 ,  C07C59/147 ,  B01J31/40 ,  C07B63/00 ,  C07C45/50 ,  C07C45/80 ,  C07C49/92 ,  C07C51/373 ,  C07C51/48 ,  C07F9/02 ,  C07F9/50 ,  C07F9/655 ,  C07F9/6574

Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a polar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a nonpolar solvent to obtain by phase separation a polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said polar solvent and nonpolar phase comprising said one or more products and nonpolar solvent, an d (2) recovering said nonpolar phase from said polar phase; wherein said organophosphorus ligand has a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 10, and said one or more products have a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 0.5.

公开(公告)号：AT256097T

公开(公告)日：2003-12-15

申请号：AT99903511

申请日：1999-02-01

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： ARGYROPOULOS JOHN N ,  BRYANT DAVID ROBERT ,  MORRISON DONALD LEE ,  STOCKMAN KENNETH ELWOOD

IPC: B01J31/18 ,  B01J31/40 ,  C07B63/00 ,  C07C45/50 ,  C07C45/80 ,  C07C47/02 ,  C07C51/373 ,  C07C51/48 ,  C07C59/147 ,  C07F9/02 ,  C07F9/144 ,  C07F9/145 ,  C07F9/50 ,  C07F9/6574

Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a nonpolar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a polar solvent to obtain by phase separation a non-polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said nonpolar solvent and a polar phase comprising said one or more products and polar solvent, and (2) recovering said polar phase from said nonpolar phase; wherein said organophosphorus ligand has a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 5, and said one or more products have a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 0.5.