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公开(公告)号：WO0234389A2
公开(公告)日：2002-05-02
申请号：PCT/US0147826
申请日：2001-10-25
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES
IPC: C07C45/50 , C07F9/6574 , C08G79/04 , C08G83/00 , B01J31/00
CPC classification number: C08G83/003 , C07C45/50 , C07F9/65744 , C07F9/65746 , C08G79/04 , Y02P20/582 , C07C47/02
Abstract: The invention relates to dendritic macromolecules and their use in metaldentritic macroligand complex catalyzed processes, for example, hydroformylation. The use of metal dendritic macroligand complex catalysts in such processes faciliates the separation of desired product from catalyst, for example, by membrane filtration.
Abstract translation: 本发明涉及树枝状大分子及其在金属微粒大分子配位体配合物催化过程（例如加氢甲酰化）中的用途。 在这种方法中使用金属树枝状大环配合物催化剂促进了所需产物与催化剂的分离，例如通过膜过滤。
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公开(公告)号：WO0168252A3
公开(公告)日：2003-09-04
申请号：PCT/US0108181
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT
IPC: B01J31/40 , B01J31/00 , B01J38/00 , C07B61/00 , C07B63/00 , C07C29/136 , C07C31/20 , C07C67/31 , C07C67/313 , C07C67/58 , C07C69/675 , C07C69/716 , C07C227/02 , C07C227/08 , C07C229/08 , C07C45/50
CPC classification number: C07B63/00 , C07C67/58 , Y02P20/582 , C07C69/716
Abstract: This invention relates to a process for separating one or more orgnnophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a polar solvent and a nonpolar solvent by phase separation wherein (i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ration Ef3 which is a value greater than about 2.5.
Abstract translation: 本发明涉及一种从包含一种或多种未反应的不饱和酯反应物，金属 - 有机磷配位体配合物催化剂，任选地，一种或多种反应产物流体的反应产物流体中分离一种或多种磷配体降解产物，一种或多种反应副产物和一种或多种甲酰酯产物的方法 所述一种或多种有机磷配体降解产物，所述一种或多种反应副产物，所述一种或多种产物，极性溶剂和非极性溶剂通过相分离，其中（i）极性相对于有机磷配体的选择性 对于一种或多种产物，由分配系数比Ef1表示，该分配系数比Ef1大于约2.5，（ii）极性相对于一种或多种有机磷配体降解产物的有机磷配体的选择性为 由大于约2.5的值的分配系数比Ef2表示，a （iii）相对于一种或多种反应副产物，极性相对有机磷配体的选择性由分配系数比例Ef3表示，该分配系数比值大于约2.5。
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公开(公告)号：WO0168249A3
公开(公告)日：2002-03-28
申请号：PCT/US0108156
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAY MIN , MAHER JOHN MICHAEL
CPC classification number: C07C45/50 , C07B63/00 , Y02P20/582 , C07C47/02
Abstract: This invention relates to a process for separating one or moer organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphous ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more polar solvents and one or more nonpolar solvent by phase separation wherein (i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Efl which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
Abstract translation: 本发明涉及一种从连续生成的反应产物流体中分离一种或更多的有机磷配体降解产物，一种或多种反应副产物和一种或多种产物的方法，所述反应产物流体包含一种或多种未反应的反应物，金属有机磷配体络合物催化剂， 有机磷配体，所述一种或多种有机磷配体降解产物，所述一种或多种反应副产物，所述一种或多种产物，一种或多种极性溶剂和一种或多种非极性溶剂通过相分离，其中（i）极性相的选择性为 有机磷配体相对于一种或多种产物的分配系数比Efl表示为大于约2.5的值，（ii）极性相对于有机磷配体相对于一种或多种有机磷配体的选择性 降解产物由大于的值的分配系数比Ef2表示 约为2.5，（iii）相对于一种或多种反应副产物，极性相对有机磷配体的选择性由分配系数比Ef3表示，该分配系数比Ef3是大于约2.5的值。
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公开(公告)号：WO0168250A3
公开(公告)日：2002-01-31
申请号：PCT/US0108173
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
IPC: B01D11/04 , B01J23/46 , B01J31/18 , B01J31/24 , B01J31/40 , B01J38/00 , C07B61/00 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/19 , C07F9/02
CPC classification number: C07C45/50 , C07B63/00 , Y02P20/582 , C07C47/02
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organosphosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
Abstract translation: 本发明涉及从连续生成的反应产物流体中分离一种或多种有机磷配体降解产物，一种或多种反应副产物和一种或多种产物，所述反应产物流体包含一种或多种未反应的反应物，金属 - 有机磷配体络合物催化剂， 有机磷配体，所述一种或多种有机磷配体降解产物，所述一种或多种反应副产物，所述一种或多种产物，一种或多种非极性溶剂和一种或多种极性溶剂通过相分离，其中（i）非极性相的选择性为 相对于一种或多种产物的有机磷配体由分配系数比Ef1表示，分配系数比Ef1是大于约2.5的值，（ii）非极性相对有机磷配体相对于一种或多种有机磷配体的选择性 降解产物由分配系数比Ef2表示，分配系数比Ef2是值gre 高于约2.5，以及（iii）非极性相对于一种或多种反应副产物的有机磷配体的选择性由大于约2.5的值的分配系数比Ef3表示。
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公开(公告)号：US6362367B2
公开(公告)日：2002-03-26
申请号：US6367598
申请日：1998-04-21
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BRAITHWAITE JOHN , BRYANT DAVID ROBERT , MILLER DAVID JAMES , LOGSDON JOHN EARL
IPC: B01J10/00 , B01J19/00 , B01J19/18 , B01J19/20 , C07C51/235 , C07C51/265 , C07C53/126 , C07C51/21
CPC classification number: C07C51/265 , B01J19/006 , B01J19/0066 , B01J19/0073 , B01J19/1875 , B01J2219/00058 , B01J2219/00085 , B01J2219/00763 , B01J2219/00774 , B01J2219/00779 , C07C51/235 , Y02P20/149 , Y02P20/582
Abstract: This invention relates to a process for producing one or more organic acids in high purity which process comprises (i) oxidizing in a liquid oxidation reactor one or more organic liquids with essentially pure oxygen or oxygen-enriched air containing at least about 50% oxygen, at a temperature sufficiently stable to prevent cycling of reaction rate, to produce a crude reaction product fluid, and (ii) refining said crude reaction product fluid to give said one or more organic acids in high purity. The oxidation temperature is preferably controlled to within about ±3° C. of a target temperature. The organic acids described herein is useful in a variety of applications, such as intermediates in the manufacture of chemical compounds, pharmaceutical manufacture and the like.
Abstract translation: 本发明涉及一种制备高纯度的一种或多种有机酸的方法，该方法包括（i）在液体氧化反应器中氧化具有至少约50％氧气的基本上纯氧或富氧空气的一种或多种有机液体， 在足够稳定的温度下以防止反应速率的循环，以产生粗反应产物流体，和（ii）精制所述粗反应产物流体以产生高纯度的所述一种或多种有机酸。 氧化温度优选控制在目标温度的约±3℃内。 本文所述的有机酸可用于各种应用，例如化学化合物的制造中的中间体，药物制造等。
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Patent Agency Ranking
公开(公告)号：ES2247797T3
公开(公告)日：2006-03-01
申请号：ES99918722
申请日：1999-04-20
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： BRAITHWAITE JOHN , BRYANT DAVID ROBERT , MILLER DAVID JAMES , LOGSDON JOHN EARL
IPC: B01J10/00 , B01J19/00 , B01J19/18 , B01J19/20 , C07C51/235 , C07C51/265 , C07C53/126 , C07C53/02 , C07C53/08 , C07C53/122 , C07C53/124 , C07C55/14 , C07C57/32 , C07C57/30 , C07C63/06 , C07C63/16 , C07C63/24 , C07C63/26 , C07C59/64
Abstract: Un procedimiento para producir al menos un ácido orgánico de elevada pureza, procedimiento que comprende oxidar, en un reactor de oxidación para líquidos, al menos un líquido orgánico con oxígeno esencialmente puro o aire enriquecido en oxígeno que contiene al menos 50% de oxígeno para producir un producto de reacción bruto fluido, y refinar dicho producto de reacción bruto fluido para proporcionar al menos dicho ácido orgánico de elevada pureza, en el que dicho reactor de oxidación para líquidos comprende: a) una vasija del reactor tubular verticalmente posicionada que tiene un tubo hueco de aspiración en su centro y tubos de intercambio de calor en el espacio anular entre el tubo hueco de aspiración y la pared exterior de la vasija del reactor, teniendo dicha vasija del reactor un espacio superior por encima y una cámara de mezcla hueca por debajo de dicho tubo hueco de aspiración y dichos tubos de intercambio de calor; b) medios impulsores posicionados dentro de dicho tubo hueco de aspiración y adaptados para provocar el flujo rápido del líquido orgánico hacia abajo a través del tubo hueco de aspiración hacia la cámara de mezcla inferior y rápidamente hacia arriba a través de dichos tubos de intercambio de calor como una dispersión sustancialmente uniforme y hacia dicho espacio superior en la vasija del reactor; c) una cámara superior posicionada por encima de y en comunicación fluida con dicha vasija del reactor, teniendo dicha cámara superior un espacio de vapor por encima de un nivel de líquido deseado; d) al menos un deflector de confinamiento de gas generalmente horizontal dispuesto entre dicha cámara superior y dicha vasija de reacción de tal forma que el espacio de vapor por encima del nivel de líquido en dicha cámara superior se mantiene por debajo tanto de LOV y LFL, estando formado dicho deflector de confinamiento de gas por un agujero central para permitir que dichos medios de impulsión se extiendan generalmente concéntricamente a través de dicho agujero en dicho deflector de confinamiento de gas.
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公开(公告)号：AT314335T
公开(公告)日：2006-01-15
申请号：AT01922386
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more polar solvents and one or more nonpolar solvents by phase separation wherein (i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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公开(公告)号：BR0109217A
公开(公告)日：2004-03-30
申请号：BR0109217
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT
IPC: B01J31/40 , B01J31/00 , B01J38/00 , C07B61/00 , C07B63/00 , C07C29/136 , C07C31/20 , C07C67/31 , C07C67/313 , C07C67/58 , C07C69/675 , C07C69/716 , C07C227/02 , C07C227/08 , C07C229/08
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a polar solvent and a nonpolar solvent by phase separation wherein(i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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公开(公告)号：BR0109216A
公开(公告)日：2002-12-03
申请号：BR0109216
申请日：2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
IPC: B01D11/04 , B01J23/46 , B01J31/18 , B01J31/24 , B01J31/40 , B01J38/00 , C07B61/00 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/19 , C07F9/02 , B01J31/00
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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公开(公告)号：NO20024357D0
公开(公告)日：2002-09-12
申请号：NO20024357
申请日：2002-09-12
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT
IPC: B01J31/00 , B01J31/40 , B01J38/00 , C07B61/00 , C07B63/00 , C07C29/136 , C07C31/20 , C07C67/31 , C07C67/313 , C07C67/58 , C07C69/675 , C07C69/716 , C07C227/02 , C07C227/08 , C07C229/08 , B01J
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a polar solvent and a nonpolar solvent by phase separation wherein(i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
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