公开(公告)号：KR790000806B1

公开(公告)日：1979-07-12

申请号：KR740004211

申请日：1974-12-05

Applicant: STANDARD OIL CO OHIO

Inventor： SERGE R DOLHYJ ,  MILBERGER E C ,  NOEL J BREMER

Abstract: Maleic anhydride(I) was manufd. from butane by oxidn. over catalysts of high life and of the type VaPbVcOx (a,b = 0.1-10, c = 0.01-5, X = Numbers of O atom which satisfy the atomic value of other atoms) Thus, 33.6g V2O5 in 438ml concentrated HCl was treated with 31.3g VO2(C2H3O2) 2HO2, refluxed 1hr, treated with H3PO4, refluxed, dried, and used at 482≦̸C to prepare I in 47-50% yield from a 1:100 butane air mixt.

公开(公告)号：JPH11241225A

公开(公告)日：1999-09-07

申请号：JP35358898

申请日：1998-12-11

Applicant: STANDARD OIL CO OHIO

Inventor： JORKASKY RICHARD J ,  PERCEC ELENA SIMONA ,  LI GEORGE S

IPC: D01D5/30 ,  D01F8/08

Abstract: PROBLEM TO BE SOLVED: To obtain a conjugate filament having high nitrile content, excellent in processability and useful for woven or knitted fabric, nonwoven fabric, or the like by including plural specific polymers arranged in core-sheath configuration. SOLUTION: This conjugate filament having high nitrile content comprises two or more kinds of polymers arranged in sheath/core configuration. The sheath polymer is selected from the group consisting of an acrylonitrile olefinic unsaturated polymer composed of 50-95 wt.% acrylonitrile monomer and 5-50 wt.% olefinic unsaturated monomer such as methyl methacrylate, an organic polymer such as a polypropylene and a combination thereof. The sheath component content is 99-1%, preferably 90-10% based on the filament. The core polymer is selected from the group consisting of the above acrylonitrile olefin-based unsaturated polymer, the above organic polymer and a combination thereof, but the core polymer is different in the composition from the sheath polymer. The core component content is 1-99%, preferably 10-90% and is thermally stable.

公开(公告)号：JPH11169715A

公开(公告)日：1999-06-29

申请号：JP24879898

申请日：1998-09-02

Applicant: STANDARD OIL CO OHIO

Inventor： SURESH DEV DHANARAJ ,  CHRISTOS PAPARIZOS ,  SEELY MICHAEL J ,  FRIEDRICH MARIA STRADA ,  DRENSKI TAMA LEE

IPC: B01J23/00 ,  B01J23/31 ,  B01J23/76 ,  B01J23/84 ,  B01J23/843 ,  B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/192 ,  B01J27/199 ,  B01J37/00 ,  B01J37/08 ,  C01C3/02 ,  C01G53/00 ,  C07B61/00 ,  C07C253/18 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

Abstract: PROBLEM TO BE SOLVED: To obtain a new ammoxidation catalyst which increases yield of hydrogen cyanide by-product formed during preparation of acrylonitrile while acrylonitrile formation level is kept at substantially the same level. SOLUTION: A catalyst compsn. contg. a compound body of catalyst oxide of iron, bismuth, molybdenum and calcium and characterized by the formula Aa Bb Cc Dd Fee Bif Mo12 Ox (wherein A is at least one of Li, Na, K, Rb and Cs or a mixture thereof; B is at least one of Mg, Mn, Ni, Co, Ag, Pb, Re, Cd and Zn or a mixture thereof; C is at least one of Ce, Cr, Al, Sb, P, Ge, La, Sn, V and W or a mixture thereof; D is at least one of Ca, Sr, Ba or a mixture thereof; and a=0.01-1.0; b and e=1.0-10; c, d and f=0.1-5.0 and x is determined by conditions of atomic values of other existing elements), is provided.

公开(公告)号：JPH1135542A

公开(公告)日：1999-02-09

申请号：JP18375097

申请日：1997-07-09

Applicant: STANDARD OIL CO OHIO

Inventor： MARK CLARK SESA ,  PAUL ALAN JACOBSON ,  RICHARD LEE WAPELHORST

IPC: B01J39/04 ,  C07C253/34 ,  C07C255/03

Abstract: PROBLEM TO BE SOLVED: To obtain a highly purified acetonitrile applicable to chromatography in a few process and a low cost by subjecting crude acetonitrile as a by-product in producing acrylonitrile to distillation and an ion exchange resin treatment. SOLUTION: The objective compound is obtained by distilling crude CH3 CN by using three distilling columns having overhead reflux loops of respectively having a reflux ratio higher than (3:1), (3.4:1) and (6.4:1), in turn, under >=1 atm., to remove HCN and generating a bottom product containing (A) a CH3 CN/ water azeotropic mixture and water, separating the component A to (B) a CH3 CN/water azeotropic mixture having a higher CH3 CN concentration and a bottom product containing water under =1 atm., then generating a CH3 CN/water azeotropic mixture containing substantially whole amount of water derived from the component B, a bottom product containing CH3 CN and heavy organic compounds, and a side stream containing (C) a highly purified CH3 CN, thus purifying the component C by an acidic ion exchange resin.

公开(公告)号：JPH1129542A

公开(公告)日：1999-02-02

申请号：JP16301897

申请日：1997-06-19

Applicant: STANDARD OIL CO OHIO

Inventor： JAMES FRANK BRAZDIL JR ,  KENNITH PAUL KECKLER ,  RICHARD PAUL HAUSER

IPC: C07C253/24 ,  C07C253/34 ,  C07C255/08

Abstract: PROBLEM TO BE SOLVED: To provide a process for recovering and regenerating ammonia contained in an effluent liquid obtained from a reaction zone for producing a corresponding aliphatic nitrile by reacting ammonia and oxygen with a paraffin. SOLUTION: This process for recovering un-reacted ammonia from an effluent liquid of a reaction vessel obtained from a reaction zone thereof used for producing acrylonitrile or methacrylonitrile, includes a process for quenching the effluent liquid from the reaction vessel with an aqueous solution of ammonium phosphate, in which the ratio of ammonium ion to phosphate ion is between approximately 0.7 to 1.3, preferably approximately 0.9 to 1.2.

公开(公告)号：JPH09314125A

公开(公告)日：1997-12-09

申请号：JP13397296

申请日：1996-05-28

Applicant: STANDARD OIL CO OHIO

Inventor： NOERU JIEI BUREMAA ,  GEERII BUI GOEDEN ,  DEIBITSUDO AARU UTSUDOBARII

IPC: C02F1/02 ,  B01D53/86 ,  B01J23/89 ,  C02F1/58 ,  C07C255/08

公开(公告)号：JPH0838899A

公开(公告)日：1996-02-13

申请号：JP3416295

申请日：1995-02-22

Applicant: STANDARD OIL CO OHIO

Inventor： PATORISHIA REI BURAMU ,  RARII MAIKERU SAAJIYAKU ,  MAIKERU FURANSHISU REMANSUKII ,  KURISUTOSU PAPARIZOSU ,  MAAKU ANSONII PEPERA

IPC: B01J23/63 ,  B01J23/44 ,  B01J23/52 ,  B01J23/58 ,  B01J23/66 ,  B01J23/89 ,  B01J37/00 ,  B01J37/02 ,  C07B61/00 ,  C07C67/04 ,  C07C67/055 ,  C07C69/15

Abstract: PURPOSE: To obtain a catalyst useful for preparation of vinyl acetate by milling a fixed bed catalyst precursor comprising Pd-Au, or the like, supported on a fixed bed catalyst support with a fluid bed catalyst binder to form a slurry, drying the slurry, and impregnating the obtained microspheroidal particles with a solution of alkali metal salt. CONSTITUTION: A slurry is formed by milling a fixed bed catalyst precursor comprising Pd-M (M is Au, Ba, Cd, Bi, Cu, Mn, Fe, Co, Ce, U or their mixtures) on a fixed support (example, silica sphere) with a fluid bed catalyst binder (for example, aqueous slurry of inactive support such as silica). The slurry is dried to form microspheroidal particles of a solid fluid bed catalyst precursor, and the particles are arbitrarily impregnated with a solution of alkali metal salt to form a fluid bed catalyst. The catalyst has a structure of Pd-M-A (A is an alkali metal, M is a present in the range of 0 - about 5 wt.%, and A is present in the range of 0 - about 10 wt.%).

公开(公告)号：JPH0753494A

公开(公告)日：1995-02-28

申请号：JP2171494

申请日：1994-02-21

Applicant: STANDARD OIL CO OHIO

Inventor： UIRUFURIIDO JII SHIYOU ,  KENISU ERU BITSUGURAA ,  RUISU AARU TOROTSUTO ,  SUTEIIBU JIEI MIKO ,  BUINSENTO JII RAIRINGU ,  MAIKERU JIEI SHIIRI ,  DEBU DEII SURETSUSHIYU ,  MARIA ESU FURIIDORITSUKU ,  POORU II BOTSUTO ,  EDOWAADO JIEI SOTSUKERU ,  ARUBAATO AARU SHIYUUKI JIYUNIA ,  KENISU PII KETSUKURAA ,  FURANKU JIEI KOKUYANSHIKU ,  SUTEIIBUN JIEI ROU

IPC: B01J23/88 ,  B01D53/58 ,  C01C3/02 ,  C07B61/00 ,  C07C5/08 ,  C07C253/24 ,  C07C253/26 ,  C07C253/32 ,  C07C255/00 ,  C07C255/08

公开(公告)号：JPH0747271A

公开(公告)日：1995-02-21

申请号：JP103491

申请日：1991-01-09

Applicant: STANDARD OIL CO OHIO

Inventor： DEBU DEII SURETSUSHIYU ,  MARIA ESU FURIIDORITSUKU ,  MAIKERU JIEI SHIIRII

IPC: B01J23/88 ,  B01J23/887 ,  B01J27/186 ,  B01J27/19 ,  B01J27/192 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

Abstract: PURPOSE: To provide high activity for preparation of unsatd. nitriles at a temp. lower than the conventionally used temp. by using a catalyst having the specified structure during ammoxidation of olefins into unsatd. nitriles. CONSTITUTION: Olefin selected from the group consisting of propylene, isobutylene and mixtures thereof is reacted with molecular oxygen contg. gas and ammonia in the gas phase at a temp. of about 260-600 deg.C at an increased pressure in the presence of an oxide catalyst, to convert it into corresponding acrylonitrile, methacrylonitrile and mixtures thereof. During which, the reaction is carried out in the presence of the catalyst having the formula: Aa Kb CSc Mgd Nie Fef Big Mo12 Ox (A is Co, Mn, Cr, P, Sb, Te, Na, Ce, W or mixtures thereof, a is a number of 0-5, b is a number of 0-0.4, c is a number of 0-0.4, provided that the total of b and c is 0.1-0.4, d-g are each 0.2-10, x is a number determined by valencies of other elements present).

公开(公告)号：JPH0615170A

公开(公告)日：1994-01-25

申请号：JP7187993

申请日：1993-03-30

Applicant: STANDARD OIL CO OHIO

Inventor： JIEEMUZU FURANKU BURATSUJIRU ,  IAN REIMONDO RITORU ,  JIYOSEFU BURAIAN HEIZEN

IPC: B01J23/14 ,  B01J23/22 ,  B01J37/02 ,  B01J37/08 ,  C07B61/00 ,  C07C253/24 ,  C07C255/07 ,  C07F7/22

Abstract: PURPOSE: To provide a method for preparing a superior oxidation catalyst contg. vanadium, antimony and tin in their oxide states without using any tin oxide sol. CONSTITUTION: This preparation method for oxidation catalyst contg. vanadium, antimony and tin in their oxide states comprises a procedure for making an aq. slurry of a mixture of source batch materials comprising compounds of the elements to be included in the final catalyst, the subsequent drying and heat-calcining procedures for making an active catalyst, wherein a stannous salt of a 1-18C acyclic, monocarboxylic acid contg. no ethylenic or acetylenic carbon-to-carbon unsaturation bond is used as the source batch material for tin.