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公开(公告)号：KR101139864B1
公开(公告)日：2012-05-02
申请号：KR1020110085584
申请日：2011-08-26
Applicant: 제일모직주식회사
Abstract: 본 발명은 하기 화학식 1로 표시되는 새로운 인계 화합물, 그 제조방법을 제공한다. 하기 화학식 1로 표시되는 인계 화합물을 적용한 열가소성 수지 조성물은 난연성이 우수하고, 가공이나 연소 시 유독가스를 발생시키지 않아 친환경적이다.
[화학식 1]
상기 화학식 1에서, R
1 및 R
2 는 서로 독립적으로 C
1 -C
6 의 알킬기 또는 아릴기이고, m은 1 내지 3의 정수임.-
公开(公告)号：KR101098415B1
公开(公告)日：2011-12-23
申请号：KR1020080124486
申请日：2008-12-09
Applicant: 제일모직주식회사
CPC classification number: C08K5/5317 , C07F9/4021 , C08L55/02 , C08L2666/14
Abstract: 상기화학식 1에서, R및 R는서로독립적으로 C-C의알킬기또는아릴기이고, m은 1 내지 3의정수임.
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公开(公告)号：KR101004674B1
公开(公告)日：2011-01-04
申请号：KR1020080098437
申请日：2008-10-08
Applicant: 제일모직주식회사
IPC: C07F9/6587 , C07F9/547 , C08L25/08 , C08K5/5337
Abstract: 본 발명은 하기 화학식 1로 표시되는 대칭성 환형 인계 화합물, 그 제조방법 및 이를 포함한 난연성 스티렌계 수지 조성물을 제공한다. 하기 화학식 1로 표시되는 대칭성 환형 인계 화합물을 적용한 스티렌계 수지 조성물은 난연성이 우수하고, 가공이나 연소 시 할로겐화 가스를 발생시키지 않아 친환경적이며, 뛰어난 충격강도를 갖는다.
[화학식 1]
상기 화학식 1에서, R
1 및 R
2 는 서로 독립적으로 수소, C
1 ∼C
6 의 알킬기 또는 C
6 ∼C
20 의 아릴기이다.
대칭성 환형 인계 화합물, 스티렌계 수지, 폴리페닐렌 에테르 수지-
44.发明公开
公开(公告)号：KR1020100077509A
公开(公告)日：2010-07-08
申请号：KR1020080135464
申请日：2008-12-29
Applicant: 제일모직주식회사
IPC: C09K21/12
Abstract: PURPOSE: A diphenoxyphosphoryl flame retardant is provided to obtain excellent flame retardant property, to be environment-friendly used without using a halogen retardant when a resin is processed or combusted, and to enable a user to easily handle the diphenoxyphosphoryl flame retardant due to solid phase. CONSTITUTION: A diphenoxyphosphoryl flame retardant is marked as a chemical formula 1. In the chemical formula 1, R1 and R2 are hydrogen or an alkyl group with C1-C6 and n is integer of 0-5. A method for manufacturing the diphenoxyphosphoryl flame retardant includes a step of reacting a compound of a chemical formula 2 with a diketone compound of a chemical formula 3. In the chemical formula 2, R1 and R2 are hydrogen or the alkyl group with C1-C6.
Abstract translation: 目的：提供二苯氧基磷酰基阻燃剂，以获得优异的阻燃性能，在树脂加工或燃烧时不使用卤素阻燃剂而环保使用，并且使用户能够容易地处理由固相产生的二苯氧基磷酰基阻燃剂 。 构成：二苯氧基磷酰基阻燃剂被标记为化学式1.在化学式1中，R 1和R 2是氢或具有C 1 -C 6的烷基，n是0-5的整数。 二苯氧基磷酰基阻燃剂的制造方法包括使化学式2的化合物与化学式3的二酮化合物反应的步骤。在化学式2中，R 1和R 2是氢或与C 1 -C 6的烷基。
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公开(公告)号：KR100850802B1
公开(公告)日：2008-08-06
申请号：KR1020070117959
申请日：2007-11-19
Applicant: 제일모직주식회사
IPC: C08L25/02 , C08K5/5373 , C08L71/10
CPC classification number: C08L51/04 , C08K5/51 , C08K5/523 , C08K5/5357 , C08L71/12 , C08L2666/22
Abstract: A nonhalogenated flame retardant resin composition is provided to improve the stability to fire, environmental friendliness and impact strength and to enhance molding property by reducing the amount of a polyphenylene ether resin. A nonhalogenated flame retardant resin composition comprises 100 parts by weight of a base resin which comprises 80-99 parts by weight of an aromatic vinyl-based resin, and 1-20 parts by weight of a polyphenylene ether resin; and 0.5-30 parts by weight of a cyclic t-butyl phosphonate compound. Preferably the cyclic t-butyl phosphonate compound is represented by the formula 1, wherein R1 and R2 are H, a C1-C6 alkyl group or a C6-C10 aryl group. Preferably the aromatic vinyl-based resin is a polymer of rubber and an aromatic monoalkenyl monomer; and the polyphenylene ether resin is poly(2,6-dimethyl-1,4-phenylene) ether.
Abstract translation: 提供非卤代阻燃树脂组合物以提高耐火稳定性，环境友好性和冲击强度，并通过减少聚苯醚树脂的量来提高成型性能。 非卤代阻燃树脂组合物包含100重量份的基础树脂，其包含80-99重量份的芳族乙烯基类树脂和1-20重量份的聚苯醚树脂; 和0.5-30重量份的环状叔丁基膦酸酯化合物。 优选地，环状叔丁基膦酸酯化合物由式1表示，其中R 1和R 2是H，C 1 -C 6烷基或C 6 -C 10芳基。 优选地，芳族乙烯基类树脂是橡胶和芳族单烯基单体的聚合物; 聚苯醚树脂为聚（2,6-二甲基-1,4-亚苯基）醚。
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Patent Agency Ranking
公开(公告)号：KR100778010B1
公开(公告)日：2007-11-28
申请号：KR1020060135848
申请日：2006-12-28
Applicant: 제일모직주식회사
Abstract: A nonhalogenated flame retardant styrene-based resin composition, a pellet obtained by extruding the composition, and an exterior material of an electronic device molded from the composition are provided to improve weather resistance, moldability and environmental friendliness by using no halogen-based flame retardant and reducing the amount of polyphenylene ether. A resin composition comprises 100 parts by weight of a base resin which comprises 80-95 wt% of a styrene-based resin and 5-20 wt% of a polyphenylene ether resin; 1-25 parts by weight of a pentaerythritol diphosphonate represented by the formula 1; and 1-25 parts by weight of an organic phosphorus-based compound, wherein R1 is a C1-C12 alkyl group, an aryl group, an alkyl-substituted aryl group, or an aralkyl group. The organic phosphorus-based compound is at least one selected from the group consisting of an alkyl phosphinic acid metal salt compound represented by the formula 2 (wherein R is a C1-C6 alkyl group, a cyclic alkyl group, or a C6-C10 aryl group; M is Al, Zn or Ca; and n is 2 or 3), an aromatic phosphate compound represented by the formula 3 (wherein R3, R4 and R5 are independently H or a C1-C4 alkyl group; X is a C6-C20 aryl group substituted or unsubstituted with an alkyl group derived from resorcinol, hydroquinol or bisphenol A; and n is 0-4), and a phosphazene compound represented by the formula 4 or 5.
Abstract translation: 提供非卤代阻燃苯乙烯基树脂组合物，通过挤出组合物获得的颗粒和由该组合物模制的电子器件的外部材料，以通过使用不含卤素阻燃剂来改善耐候性，成型性和环境友好性， 减少聚苯醚的用量。 树脂组合物包含100重量份的基础树脂，其包含80-95重量％的苯乙烯基树脂和5-20重量％的聚苯醚树脂; 1-25重量份由式1表示的季戊四醇二膦酸盐; 和1-25重量份的有机磷系化合物，其中R1是C1-C12烷基，芳基，烷基取代的芳基或芳烷基。 有机磷系化合物是选自由式2表示的烷基次膦酸金属盐化合物（其中R是C1-C6烷基，环状烷基或C6-C10芳基）的至少一种 基团; M为Al，Zn或Ca; n为2或3），由式3表示的芳族磷酸酯化合物（其中R3，R4和R5独立地为H或C1-C4烷基; X为C6- C20芳基取代或未取代，与衍生自间苯二酚，氢醌或双酚A的烷基，n为0-4）和由式4或5表示的磷腈化合物。
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公开(公告)号：KR100654525B1
公开(公告)日：2006-12-05
申请号：KR1020050134991
申请日：2005-12-30
Applicant: 제일모직주식회사
IPC: C07F9/32
Abstract: A salt of carboxyethyl phosphinate ester is provided to show excellent flame retardant property, improved heat-stability and moisture absorbing property by esterifying carboxy phosphinic acid and then preparing a salt compound thereof. The salt of carboxyethyl phosphinate ester is represented by the formula(I), where R1 is C1-6 alkyl, C6-12 aryl or alkyl substituted C6-12 aryl, R2 is C1-6 alkyl, C6-12 aryl or alkyl substituted C6-12 aryl, n is an integer from 1 to 3, and M is a metal selected from the group consisting of Al, Zn, Ca, Ba and Mg or an amine-based compound selected from the group consisting of ammonium, melamine and melum. The flame retardant thermoplastic resin composition comprises a thermoplastic resin and 0.1-50 parts by weight of the salt of carboxyethyl phosphinate ester regarding 100 parts by weight of the thermoplastic resin.
Abstract translation: 提供羧乙基次膦酸酯的盐以通过酯化羧基次膦酸然后制备它们的盐化合物显示优异的阻燃性，改善的热稳定性和吸湿性。 羧乙基次膦酸酯的盐由式（I）表示，其中R 1为C 1-6烷基，C 6-12芳基或烷基取代的C 6-12芳基，R 2为C 1-6烷基，C 6-12芳基或烷基取代的C 6 -12芳基，n是1至3的整数，M是选自Al，Zn，Ca，Ba和Mg的金属或选自铵，三聚氰胺和甜菜碱的基于胺的化合物 。 阻燃热塑性树脂组合物包含热塑性树脂和相对于100重量份热塑性树脂0.1重量份〜50重量份的羧乙基次膦酸酯的盐。
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公开(公告)号：KR101459123B1
公开(公告)日：2014-11-12
申请号：KR1020110127937
申请日：2011-12-01
Applicant: 제일모직주식회사
CPC classification number: C09K21/14
Abstract: 본 발명은 하기 화학식 1로 표시되는 폴리포스포네이트로서, 산가가 5.5 KOH mg/g 이하인 것을 특징으로 한다:
[화학식 1]
(상기 식에서, A는 단일 결합, C
1 -C
5 의 알킬렌, C
1 -C
5 의 알킬리덴, C
5 -C
6 의 시클로알킬리덴, -S- 또는 -SO
2 -이고, R은 치환 또는 비치환된 C
6 -C
20 인 아릴기 또는 C
6 -C
20 인 치환 또는 비치환된 아릴옥시기이고, R
1 및 R
2 는 각각 독립적으로 치환 또는 비치환된 C
1 내지 C
6 알킬기, 치환 또는 비치환된 C
3 내지 C
6 사이클로알킬기, 치환 또는 비치환된 C
6 내지 C
12 의 아릴기 또는 할로겐 원자이며, a 및 b는 각각 독립적으로 0 내지 4의 정수, n은 1 내지 500의 정수임.)-
公开(公告)号：KR1020140084827A
公开(公告)日：2014-07-07
申请号：KR1020120154753
申请日：2012-12-27
Applicant: 제일모직주식회사
Abstract: The present invention relates to a flame retardant polycarbonate resin composition comprising: a polycarbonate resin (A); a sulfonic acid metallic salt compound (B); a hollow aluminum silicate compound (C); a fluorinated polyolefin based resin (D); and an inorganic phosphate compound (E). The flame retardant polycarbonate resin composition improves optical permeability and flame retardancy in thin film formation by minimizing a fluorinated polyolefin based resin (D) content by using the hollow aluminum silicate compound (C) and improves yellowing due to the hollow aluminum silicate compound (C) by using the inorganic phosphate compound (E).
Abstract translation: 本发明涉及一种阻燃聚碳酸酯树脂组合物，其包含：聚碳酸酯树脂（A）; 磺酸金属盐化合物（B）; 中空硅酸铝化合物（C）; 氟化聚烯烃类树脂（D）; 和无机磷酸盐化合物（E）。 阻燃聚碳酸酯树脂组合物通过使用中空硅酸铝化合物（C）使氟化聚烯烃类树脂（D）含量最小化并改善由于中空硅酸铝化合物（C）引起的黄变，从而提高薄膜形成中的透光性和阻燃性， 通过使用无机磷酸盐化合物（E）。
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公开(公告)号：KR101332439B1
公开(公告)日：2013-11-25
申请号：KR1020100136081
申请日：2010-12-27
Applicant: 제일모직주식회사
IPC: C07F9/6574 , C09K21/12 , C08K5/529 , C08L69/00
Abstract: 본 발명은 하기 화학식 1의 인계 화합물의 제조방법에 있어서, 알킬렌 옥사이드로 후처리하여 산가를 개선한 것을 특징으로 한다:
[화학식 1]
(상기에서, R은 C
4 -C
10 의 알킬기, C
6 -C
20
아릴기, C
6 -C
20
알킬 치환 아릴기, CC
6 -C
20 아르알킬기이고, n은 0 또는 1임).
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