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41.发明授权황화수소 광분해용 금속산화물계 광촉매와 클라우스공정을 대체하는 상기 촉매를 이용한 황화수소의 광분해방법 失效用于硫化氢光催化分解的新型金属氧化物基光催化剂和使用光催化剂的克劳斯加工取代方法
公开(公告)号：KR100598862B1
公开(公告)日：2006-07-10
申请号：KR1020040083366
申请日：2004-10-19
Applicant: 한국화학연구원
IPC: B01J23/00 , B01J23/755 , B01J23/16
Abstract: 본 발명은 황화수소 광분해용 금속산화물계 광촉매와 클라우스 공정을 대체하는 상기 촉매를 이용한 황화수소의 광분해 방법에 관한 것으로서, 더욱 상세하게는 밴드갭 에너지(band gap energy)가 2.3 ∼ 4.3 eV 범위이고 광에 의한 부식 저항성 및 광흡수율이 향상되어 황화수소의 분해능을 가진 신규의 금속산화물계 광촉매와, 그리고 기존의 황화수소를 물과 황으로 분해하는 클라우스 공정과는 전혀 다른 개념의 것으로 상기한 금속산화물계 광촉매의 황화수소에 대한 우수한 광분해 활성을 이용하여 황화수소로부터 청정에너지원인 수소를 직접 생산하는 새로운 개념의 황화수소의 광분해 방법에 관한 것이다.
금속산화물계 광촉매, 황화수소, 광분해-
公开(公告)号：KR100549402B1
公开(公告)日：2006-02-03
申请号：KR1020030032547
申请日：2003-05-22
Applicant: 한국화학연구원
Abstract: 본 발명은 인듐 포스파이드(InP)의 나노입자 양자점의 제조 방법에 관한 것으로서, 하기의 화학식 VII 및 VIII의 두 단계반응 방법으로 제조되어지는 것을 특징으로 하며, 본 발명을 통하여 제조공정이 단순화되고, 안정적이며 폭발의 위험성이 없는 물질을 사용하여 인듐포스파이드(InP) 나노입자 양자점을 선택적으로 제조할 수 있게 되었다.
인듐포스파이드, 양자점, 나노입자, 백린, 인듐클로라이드-
43.发明授权이온이 첨가된 신규 산화티타늄계 화합물 박막 광전극 및 그 제조방법 그리고 이를 이용한 광전류 발생방법 失效이온이첨가된신규산화티타늄계화합물박막광전극및그제조방법그리고이를이용한광전류발생방
公开(公告)号：KR100398747B1
公开(公告)日：2003-09-19
申请号：KR1019990043232
申请日：1999-10-07
Applicant: 한국화학연구원
IPC: H01M6/36
Abstract: PURPOSE: Provided is a thin-film photoelectrode made of ion-added titanium oxide compound which is used for converting light energy to electric energy. And a method for preparing the same and a method for generating photoelectrical current using the same are also provided. CONSTITUTION: The thin-film photoelectrode made of titanium oxide compound is represented by the formula (1) CG/TixMyO2: wherein, CG is a conducting glass, which collects photoelectrical current generated from a semiconductor, such as indium tin oxide glass or SnO2 glass; M is ionic materials added to synthesize the titanium oxide semiconductor compound and is selected from the group consisting of P, As, Sb, Cr, V, Mo, Mn, Re, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Al, Ga, Sn, Pb, S, Y, Rb, Na, Mg and Ca; x represents atom % of Ti/(Ti+M) and is 92.00-99.99; and y represents atom % of M/(Ti+M) and is 0.01-8.00. The method for preparing the thin-film photoelectrode of titanium oxide compound comprises steps of: (i) gradually adding Ti(OCH(CH3)2)4 mixed with isopropyl alcohol to distilled water to make atom % of Ti/(Ti+M) be 92.00-99.99 under nitrogen atmosphere and intensely stirring the solution for 5-20 minutes; (ii) after adding HNO3 to the obtained solution of the step (i) until the pH value gets 1-2 to accurately deposit titania, adding ionic materials to the solution to make atom % of M/(Ti+M) be 0.01-8.00; (iii) intensely mixing the solution at a temperature of 60-100 deg.C for 5-10 hours and then evaporating water to obtain sol having viscosity; (iv) after dropping fixed amount of the obtained sol on ITO plate to coat the plate with the sol in order to have uniform thickness, sintering the ITO plate at a temperature of 200-550 deg.C for 30-60 minutes.
Abstract translation: 用途：提供一种用于将光能转化为电能的离子加入氧化钛化合物制成的薄膜光电极。 还提供了一种用于制备其的方法以及使用该方法产生光电流的方法。 构成：由氧化钛化合物制成的薄膜光电极由式（1）CG / TixMyO2表示：其中，CG是导电玻璃，其收集由半导体产生的光电流，例如氧化铟锡玻璃或SnO2玻璃 ; M是为了合成氧化钛半导体化合物而添加的离子材料，并且选自由P，As，Sb，Cr，V，Mo，Mn，Re，Fe，Ru，Co，Rh，Ir，Ni，Pd， Pt，Cu，Ag，Al，Ga，Sn，Pb，S，Y，Rb，Na，Mg和Ca; x表示Ti /（Ti + M）的原子％，为92.00-99.99; y表示M /（Ti + M）的原子％，为0.01〜8.00。 制备氧化钛化合物薄膜光电极的方法包括以下步骤：（i）将与异丙醇混合的Ti（OCH（CH3）2）4逐渐加入到蒸馏水中以使Ti /（Ti + M）原子％ 在氮气氛下为92.00-99.99并剧烈搅拌溶液5-20分钟; （ii）向得到的步骤（i）的溶液中加入HNO3直至pH值达到1-2，准确沉积二氧化钛后，向溶液中加入离子材料使M /（Ti + M）的原子百分比为0.01- 8.00; （iii）在60-100℃的温度下剧烈混合该溶液5-10小时，然后蒸发水以获得具有粘度的溶胶; （iv）将固定量的所得溶胶滴在ITO板上以将溶胶涂覆到板上以具有均匀的厚度后，在200-550℃的温度下将ITO板烧结30-60分钟。
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公开(公告)号：KR1020020044889A
公开(公告)日：2002-06-19
申请号：KR1020000074137
申请日：2000-12-07
Applicant: 한국화학연구원
IPC: C07C49/786
Abstract: PURPOSE: A method for preparing 2-hydroxy-4-octyloxybenzophenone of a benzophenone-based photostabilizer is provided, to improve the selectivity of the product(a yield of 95% without the generation of isomers). CONSTITUTION: The method comprises the step of mixing 2,4-dihydroxybenzophenone and octyl halide with a molar ratio of 2.0:1.8 to 2.0:3.0 (See the reaction scheme 1). In the reaction scheme 1, X is Cl, Br or I. Preferably the reaction temperature is 120-160 deg.C and the reaction time is 5-12 hours. Preferably an acid neutralizer(Na2CO3), a reaction catalyst(KI) and a reaction solvent(PEG400 : poly(ethylene glycol), a mean molecular weight 400) are employed. The molar ratio of Na2CO3 to 2,4-dihydroxybenzophenone is 2.0:0.5 to 1:1, and the molar ratio of KI is 0.05-0.10 mol% based on the weight of 2,4-dihydroxybenzophenone.
Abstract translation: 目的：提供二苯甲酮类光稳定剂的2-羟基-4-辛氧基二苯甲酮的制备方法，提高产物的选择性（产率95％，不产生异构体）。 方案：该方法包括以摩尔比2.0：1.8至2.0：3.0混合2,4-二羟基二苯甲酮和辛基卤化物的步骤（参见反应方案1）。 在反应方案1中，X为Cl，Br或I.优选反应温度为120-160℃，反应时间为5-12小时。 优选使用酸中和剂（Na 2 CO 3），反应催化剂（KI）和反应溶剂（PEG400：聚（乙二醇），平均分子量400）。 Na 2 CO 3与2,4-二羟基二苯甲酮的摩尔比为2.0:0.5:1:1，基于2,4-二羟基二苯甲酮的重量，KI的摩尔比为0.05-0.10mol％。
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公开(公告)号：KR100301281B1
公开(公告)日：2001-09-13
申请号：KR1019990022953
申请日：1999-06-18
IPC: B01J27/04
CPC classification number: B01J27/138 , B01J35/002 , B01J35/004 , Y02E60/364
Abstract: 본발명은물을광반응으로분해하는데에사용되는 CdS계광촉매(광촉매시스템)의제조방법및 이에의한수소의제조방법에관한것으로, 본발명의광촉매의제조방법은하기의화학식 6를가지는광촉매를제조함에있어서, M의값이 0.001∼20.00이되도록 Cd 및 M 함유화합물을물에용해한후, 여기에반응물로 HS 또는 NaS 중선택된 1종을가하고저어서 Cd[M]S 침전물을얻고, 이침전물을물로세척한후 질소(기류)분위기와 105∼150℃의온조에서 1.5∼3.0시간동안질소기류하에서진공건조시킨다음, 이건조된 Cd[M]S 침전물에액상의제 1항기재의 m함유물을 m의함유량이전체광촉매에대하여 0.10∼5.00 중량% 되도록가하여도핑처리하는것을특징으로하며, (상기화학식에서 m은전자받게로서도핑된금속을나타내며, Ni, Pd, Pt, Fe, Ru, Co 또는이들의산화물중 선택된 1종이상이며, a는 m의중량백분율을나타내며 0.10∼5.00의값을갖는다. M은 V, Cr, Al, P, As, Sb, Pb 중선택된금속이고, b는 M/(M+Cd)의몰%를나타낸것으로 0.001∼20.00의값을갖는다.) 본발명의수소제조방법은환원제로 NaSO를 0.05∼1.00몰, 전자공여체로 NaS를 0.05∼1.00몰을가한물과접촉, 현탁시키고교반하면서광필터(LightFlter)로조정된가시광선영역의광 또는태양광을조사하여반응시키는것을특징으로한다.
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Patent Agency Ranking
公开(公告)号：KR1020000019205A
公开(公告)日：2000-04-06
申请号：KR1019980037180
申请日：1998-09-09
IPC: B01J27/04
CPC classification number: C01B3/042 , B01J23/06 , B01J27/043 , B01J27/045 , B01J35/002 , B01J35/004 , B01J37/03 , Y02E60/364
Abstract: PURPOSE: A photocatalyst for generating hydrogen is provided to activate the photo catalyst in a sunbeam area as well as in a visible ray area, to increase generating amount of hydrogen and to make the life span of the catalyst semi-permanent. CONSTITUTION: A photo catalyst is indicated as a chemical formula, m(A)/Cd(M(B))S. A method for producing the photo catalyst is composed of the steps of: dissolving a compound containing Cd and M to make mole % of M 0.05 to 20.00; stirring the dissolved compound after giving the compound H2S or Na2S as a reactor to gain a Cd£M|S deposit; cleansing the deposit with water until pH keeps 7; drying the cleansed deposit in a vacuum under a nitrogen atmosphere, and doping the deposit by giving the deposit liquid compound containing m to be 0/10 to 2.50wt% of m content. The m stands for doped metal.
Abstract translation: 目的：提供用于产生氢的光催化剂，以在阳光区域和可见光区域激活光催化剂，以增加氢的产生量并使催化剂的寿命半永久。 构成：光催化剂以化学式m（A）/ Cd（M（B））S表示。 制备光催化剂的方法包括以下步骤：将含有Cd和M的化合物溶解，使摩尔％的M为0.05〜20.00; 在给出化合物H2S或Na2S作为反应器之后，搅拌溶解的化合物以获得Cd£M | S沉积物; 用水清洗沉淀物直到pH保持7; 在氮气气氛下在真空中干燥净化的沉积物，并通过给出含有m的沉积液体化合物为0/10至2.50重量％的m含量来掺杂沉积物。 m代表掺杂金属。
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公开(公告)号：KR1020000019204A
公开(公告)日：2000-04-06
申请号：KR1019980037179
申请日：1998-09-09
IPC: B01J27/04
CPC classification number: C01B3/042 , B01J27/045 , B01J27/049 , B01J35/002 , B01J35/004 , Y02E60/364
Abstract: PURPOSE: A photo catalyst having a semi-eternal life span is provided to activate a catalyst in a visible ray area regulated with a photo filter and to improve the amount of generating hydrogen. CONSTITUTION: In an equation of Pt(x)Zn/£M(y)|S, x shows a weight percentage of Pt and has a 0.05 to 2.50 value, and M is an element metal selected among V, Cr, Mo, Mn, Re, Fe, Ru, Os, Rh, Ir, Ni, Cu, Al, Ga and P. In addition, y shows a mole % of M/(M+Zn) and has a 0.01 to 20.00 value. Herein, a compound containing Zn and M is dissolved in water so M as to be 0.01 to 20, and H2S or Na2S is given in the compound to obtain a Zn(M)S deposit. Then, the deposit is washed with water until pH becomes 7, and the washed deposit is dried. The Pt compound of a liquid phase is given in the dried Zn(M)S deposit so the Pt content as to be 0.05 to 2.50 wt%, and an ultra violet photo is injected to dope Pt on Zn£M|S in a nitrogen atmosphere. Then, it is washed and dried again until pH becomes 7, oxidation-calcined at 280 to 420°C for 1 to 3 hours and reduction-calcined at 280 to 420°C for 1 to 3 hours.
Abstract translation: 目的：提供具有半永久寿命的光催化剂，以激活用光过滤器调节的可见光区域中的催化剂，并改善产生氢气的量。 构成：在Pt（x）Zn /£M（y）| S的方程中，x表示Pt的重量百分比，并具有0.05至2.50的值，M是选自V，Cr，Mo，Mn中的元素金属 ，Re，Fe，Ru，Os，Rh，Ir，Ni，Cu，Al，Ga和P.另外，y表示M /（M + Zn）的摩尔％，为0.01〜20.00。 这里，将含有Zn和M的化合物溶解在水中，使M为0.01〜20，在化合物中给出H 2 S或Na 2 S，得到Zn（M）S沉积物。 然后，用水洗涤沉淀物直到pH变为7，并将洗涤的沉积物干燥。 在干燥的Zn（M）S沉积物中给出液相的Pt化合物，使Pt含量为0.05〜2.50重量％，并注入紫外照片以在氮气中掺杂Pt 大气层。 然后再次洗涤和干燥直至pH变为7，在280至420℃下氧化煅烧1至3小时，并在280至420℃下还原煅烧1至3小时。
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48.发明授权
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50.发明公开신규 가시광선 흡수 그레핀 박막 광촉매, 이를 이용한 산화환원효소 보조인자의 재생방법 및 이를 이용한 효소반응으로 이산화탄소로부터 포름산을 제조하는 방법 有权用于从二氧化碳甲酸作为新可见光吸收方法，其光催化列宾薄膜，这种氧化 - 还原酶辅助因子的再现方法和通过使用相同的酶反应。
公开(公告)号：KR1020170072531A
公开(公告)日：2017-06-27
申请号：KR1020150180787
申请日：2015-12-17
Applicant: 한국화학연구원
IPC: C01B31/04 , C07D221/18 , B01J35/00 , C12N9/02
CPC classification number: Y02P20/582
Abstract: 본발명은신규가시광선흡수그레핀박막광촉매, 이를이용한산화환원효소보조인자의재생방법및 이를이용한효소반응으로이산화탄소로부터포름산을제조하는방법에관한것이다. 본발명에따른그레핀복합체를포함하는광촉매는기존의전기적전환용전극대신태양광중의가시광선을흡수하는것이가능함으로써, 태양광에너지를사용하여추가적인에너지비용의낭비없이산화환원효소의보조인자를재생할수 있어경제적이고환경친화적일뿐만아니라, 박막형태로도제조가능하므로, 대량생산및 자동화가가능하며, 더욱이온난화가스인이산화탄소를고정하여다양한화합물을선택적으로제조하는인공광합성을응용한신규제조산업에유용하게사용될수 있다.
Abstract translation: 本发明涉及一种生产由二氧化碳甲酸作为新可见光吸收该光催化列宾薄膜，这种方法再现氧化还原酶助理的，并使用使用相同的酶反应。 含有根据本发明的列宾复合光催化剂，通过它可以通过使用所述太阳能吸收太阳能光地方的电极的可见光用于现有电开关，发挥氧化还原酶的字符辅因子没有额外的能量成本的损失 它不仅可以成本有效和环境友好的，薄膜这样的形式也可以制备，并且大规模生产和自动化是可能的，并且在hansingyu通过将人工光合作用选择性生产各种化合物行业的固定二氧化碳的制造变暖气体而且有用 可以使用。
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