公开(公告)号：US11279853B2

公开(公告)日：2022-03-22

申请号：US15635237

申请日：2017-06-28

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Carsten Franke ,  Joseph C. Dingeldein ,  Jay A. Esch ,  Robert L. W. Smithson ,  Jayshree Seth ,  Olester Benson, Jr. ,  Karen J. Calverley ,  Alexander J. Huffman ,  Serkan Yurt ,  Setareh Niknezhad ,  Michael A. Kropp ,  John P. Baetzold

IPC: B33Y10/00 ,  B33Y30/00 ,  B33Y50/02 ,  B33Y70/00 ,  B29C35/08 ,  C09J5/00 ,  C09J9/00 ,  B05D3/06 ,  B05D5/10 ,  B29K105/00 ,  C09J4/00 ,  C09J133/00 ,  C09J7/20 ,  B29C64/112 ,  B33Y80/00 ,  C09J7/38 ,  C09J11/04 ,  C08F220/18 ,  B29K33/04

Abstract: A method of making an adhesive is provided, including obtaining an actinic radiation-polymerizable adhesive precursor composition disposed against a surface of an actinic radiation-transparent substrate and irradiating a first portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a first irradiation dosage. The method further includes irradiating a second portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a second irradiation dosage. The first portion and the second portion are adjacent to or overlapping with each other and the first irradiation dosage and the second irradiation dosage are not the same. The method forms an integral adhesive having a variable thickness in an axis normal to the surface of the actinic radiation-transparent substrate. Also, an adhesive article is provided, including a substrate having a major surface and an integral adhesive disposed on the major surface of the substrate. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.

公开(公告)号：US11274235B2

公开(公告)日：2022-03-15

申请号：US15552344

申请日：2016-04-21

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Joao R. Talamoni ,  Susana Shimizu ,  Jayshree Seth

IPC: C09J133/08 ,  C09J7/38 ,  C08F220/18

Abstract: An acrylic adhesive derived from the reaction product of (i) an acrylic acid ester of monohydric alcohol having an alkyl group of 5 to 10 carbon atoms; and (ii) a nonpolar acrylic monomer having a solubility of less than 9.2 as measured with the Fedors method using a homopolymer of the nonpolar acrylic monomer. The acrylic adhesive possesses performance characteristics that enable the adhesive to function in certain embodiments as a pressure-sensitive adhesive for applications involving articles that are sensitive to delamination or tearing upon removal of the adhesive from the article.

公开(公告)号：US20220033691A1

公开(公告)日：2022-02-03

申请号：US17278349

申请日：2018-10-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： John C. Clark ,  James R. Imbertson ,  Mark E. Mueller ,  Jayshree Seth ,  Joseph C. Spagnola ,  Dennis E. Vogel ,  Kim M. Vogel

IPC: C09J7/40 ,  C08J7/04 ,  C08J7/046 ,  C09J133/08 ,  C09D171/02 ,  C08G65/22 ,  C08G65/335

Abstract: An article comprising a flexible polymer substrate having two major surfaces, a surface layer comprising metal, metal oxide, silicon flexible polymer substrate; and a coating disposed on at least one surface layer, wherein the coating comprises a fluorinated polymer bonded to the surface layer; wherein the fluorinated polymer has the following general formula (I), where n=6 to 120; and where n=6 to 120; and where m=1 to 25 (R1); (R2); or where m=1 to 25 (R3).

公开(公告)号：US20210095166A1

公开(公告)日：2021-04-01

申请号：US17044564

申请日：2019-03-28

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jayshree Seth ,  Alexander J. Kugel ,  Guy M. Kallman ,  Sara H. Frisco ,  Owen M. Anderson

IPC: C09J7/40 ,  C09J7/26

Abstract: An adhesive transfer tape having an adhesive layer having at least one major surface that includes an irregular pattern of grooves, allowing for fluid egress.

公开(公告)号：US20200308321A1

公开(公告)日：2020-10-01

申请号：US15733259

申请日：2018-12-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Serkan Yurt ,  Stephen B. Roscoe ,  George W. Griesgraber ,  Babu N. Gaddam ,  Kevin M. Lewandowski ,  Bryan T. Whiting ,  Haeen Sykora ,  Aaron T. Hedegaard ,  Jayshree Seth ,  Janet A. Venne

IPC: C08F20/38 ,  C08F2/50 ,  C08K3/36 ,  C08K5/3492 ,  C08K5/5419 ,  C08F293/00 ,  C09J7/38

Abstract: Crosslinkable polymeric materials, crosslinked polymeric materials, articles containing the crosslinkable polymeric materials or crosslinked polymeric materials, and methods of making the articles and various compositions are provided. More particularly, the crosslinkable composition contains a) a first polymeric material, which has terminal dithiocarbamate or dithiocarbonate groups, b) a crosslinking composition containing a chlorinated triazine crosslinking agent and/or a crosslinking monomer having two or more ethylenically unsaturated groups, and c) a thixotropic agent containing metal oxide particles. The crosslinkable composition may be printable or dispensed. In some embodiments, the crosslinked composition is a pressure-sensitive adhesive.

公开(公告)号：US20200238670A1

公开(公告)日：2020-07-30

申请号：US16849316

申请日：2020-04-15

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Steven R. Austin ,  Jayshree Seth

IPC: B32B27/06 ,  C09J133/08 ,  C03C27/10 ,  C09J7/38 ,  C09J7/40 ,  C09J7/26 ,  B32B5/18 ,  C09J183/04 ,  C08K7/28

Abstract: Provided are adhesive articles and related methods that use a foam layer including an acrylic polymer or silicone polymer and having a pair of opposing major surfaces. An adhesive surface is disposed on each of the opposing major surfaces and a plurality of channels extend across at least one adhesive surface. The adhesive surface defining the channels contains a pressure-sensitive adhesive having a rheology enabling the plurality of channels to essentially disappear over time when the adhesive article is compressed. Advantageously, the provided articles and methods enable high immediate bond and handling strength, a high degree of wet out, weatherability, and superior aesthetics when used with transparent or translucent substrates.

公开(公告)号：US10414954B2

公开(公告)日：2019-09-17

申请号：US15533556

申请日：2015-12-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Lili Qie ,  Zhong Chen ,  Zhipeng Song ,  John R. Jacobsen ,  Peggy S. Willett ,  Robert D. Waid ,  Jayshree Seth

IPC: C09J133/08 ,  C08L33/08 ,  C08F220/06 ,  C08F216/14 ,  C08F220/18

Abstract: A pressure-sensitive adhesive is provided that is a dried product of a latex composition, which is formed from an emulsion composition. The latex composition and the emulsion composition are also provided. The emulsion composition has droplets that contain various monomers plus a (meth)acrylate polymer and a hydrogenated hydrocarbon tackifier dissolved in the monomers. Additionally, an article containing a layer of the pressure-sensitive adhesive and a method of forming the pressure-sensitive adhesive are provided. The pressure-sensitive adhesives often have both high peel adhesion and high shear strength (i.e., high cohesive strength or high shear holding power).

公开(公告)号：US10370564B2

公开(公告)日：2019-08-06

申请号：US15306200

申请日：2015-06-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Joon Chatterjee ,  Jitendra Rathore ,  Babu N. Gaddam ,  Jayshree Seth ,  Corinne E. Lipscomb

IPC: C09J4/06 ,  C09J11/04 ,  C08F220/10 ,  C08G77/442 ,  C09J133/06 ,  C09J183/10 ,  C08K5/101

Abstract: Pressure sensitive adhesive compositions are described comprising at least one low Tg ethylenically unsaturated monomer, and at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups. The low Tg ethylenically unsaturated monomer typically has a Tg no greater than 10° C. In some embodiments, the composition comprises at least 50, 55, 60, 65, or 70 wt-% of low Tg ethylenically unsaturated monomer. The low Tg ethylenically unsaturated monomer is typically an alkyl (meth)acrylate comprising 4 to 20 carbon atoms. In another embodiment, an adhesive composition is described comprising a syrup. The syrup comprising i) a free-radically polymerizable solvent monomer; ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl (meth)acrylate monomers, and iii) at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups. The free-radically polymerizable solvent monomer, polymerized units of the solute (meth)acrylic polymer, or a combination thereof comprise a low Tg ethylenically unsaturated monomer. Also described are pressure sensitive adhesive articles and method of preparing adhesive articles.

公开(公告)号：US20190218423A1

公开(公告)日：2019-07-18

申请号：US15768957

申请日：2016-12-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Joseph T. Bartusiak ,  Ning Zhou ,  Derek J. Dehn ,  Jeffrey O. Emslander ,  Corinne E. Lipscomb ,  Jayshree Seth ,  Jeffrey A. Carlson

IPC: C09J7/25 ,  C09J7/24 ,  C09J11/08 ,  C09J11/06 ,  C09J7/38 ,  C09J7/35 ,  C09J7/50 ,  C09J7/40

CPC classification number: C09J7/255 ,  C09J7/245 ,  C09J7/35 ,  C09J7/385 ,  C09J7/401 ,  C09J7/50 ,  C09J11/06 ,  C09J11/08 ,  C09J2203/31 ,  C09J2205/106 ,  C09J2205/114 ,  C09J2431/006 ,  C09J2433/00 ,  C09J2467/006 ,  C09J2483/005

Abstract: An article is described such as a tape or sheet, comprising a PLA-based film and a layer of (e.g. pressure sensitive) adhesive disposed on the film. The PLA-based film comprises a semicrystalline polylactic acid polymer; a second polymer such as polyvinyl acetate polymer having a glass transition temperature (Tg) of at least 25° C.; and plasticizer. The tape or sheet may further comprises a low adhesion backsize or a release liner. The article can be suitable for various end-uses. In one embodiment, the tape is a paint masking tape. In another embodiment, the tape is a floor marking tape.

公开(公告)号：US10005925B2

公开(公告)日：2018-06-26

申请号：US14352874

申请日：2012-10-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Patrick D. Hyde ,  Jeffrey M. Imsande ,  Jayshree Seth ,  Craig E. Hamer ,  Rebecca A. Shipman ,  Robert B. Secor ,  Michael C. Martin ,  Pentti K. Loukusa

IPC: B05C5/02 ,  C09J7/02 ,  C09D107/00 ,  C09D121/00 ,  C09D133/06 ,  C09J135/06 ,  C09D153/02 ,  C09J153/02 ,  C09J7/38

CPC classification number: C09J7/385 ,  B05C5/0254 ,  C09D107/00 ,  C09D121/00 ,  C09D133/06 ,  C09D153/02 ,  C09J7/383 ,  C09J7/387 ,  C09J135/06 ,  C09J153/02 ,  C09J2407/00 ,  C09J2433/00 ,  C09J2453/00 ,  Y10T428/24446 ,  Y10T428/273

Abstract: Articles with thin caliper melt coatings of high molecular weight, high viscosity materials and methods of making such coatings.