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公开(公告)号:DE3238391A1
公开(公告)日:1984-04-19
申请号:DE3238391
申请日:1982-10-16
Applicant: BASF AG
Inventor: BRANDSTETTER FRANZ DR , KUCHNER KARL DR , MIETZNER FRANZ GEORG DR , REIMANN HORST DR , THEYSOHN RAINER DR , ZIEGLER WALTER DR
IPC: C08F4/28 , C08F210/02 , C08F6/26 , C08F220/12 , C08F220/18
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公开(公告)号:DE3237107A1
公开(公告)日:1984-04-12
申请号:DE3237107
申请日:1982-10-07
Applicant: BASF AG
Inventor: ZIEGLER WALTER DR , BRANDSTETTER FRANZ DR , BALL WOLFGANG DR , GLASER RUDOLF DR , GROPPER HANS DR , WEISS FRANK DR
IPC: C08F210/02 , C08F10/02
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公开(公告)号:DE3234492A1
公开(公告)日:1984-03-22
申请号:DE3234492
申请日:1982-09-17
Applicant: BASF AG
Inventor: ZIEGLER WALTER DR , BRANDSTETTER FRANZ DR , GROPPER HANS DR , HABERKORN HERBERT DR , ILLERS KARL HEINZ DR , RAMSTEINER FALKO DR , SADLOWSKI JUERGEN DR
IPC: C08F210/02 , C08F220/10
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公开(公告)号:DE3227747A1
公开(公告)日:1984-01-26
申请号:DE3227747
申请日:1982-07-24
Applicant: BASF AG
Inventor: ZENTGRAF ERNST , OEDER DIETER DR , BRANDSTETTER FRANZ DR
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公开(公告)号:DE3225171A1
公开(公告)日:1984-01-12
申请号:DE3225171
申请日:1982-07-06
Applicant: BASF AG
Inventor: WERNER MICHAEL DR , OEDER DIETER DR , BRANDSTETTER FRANZ DR , GROPPER HANS DR , WEISS FRANK DR
IPC: C08F2/34 , C08F4/28 , C08F210/02 , C08F220/18
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公开(公告)号:DE3217973A1
公开(公告)日:1983-11-17
申请号:DE3217973
申请日:1982-05-13
Applicant: BASF AG
Inventor: WERNER MICHAEL DR , BRANDSTETTER FRANZ DR , GROPPER HANS DR , GLASER RUDOLF DR , BALL WOLFGANG DR
IPC: C08F210/02 , C08F10/02 , C08F20/18
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公开(公告)号:DE4236058A1
公开(公告)日:1994-04-28
申请号:DE4236058
申请日:1992-10-26
Applicant: BASF AG
Inventor: BRANDSTETTER FRANZ DR , GAUSEPOHL HERMANN DR , THIELE REINER PROF DR
Abstract: Continuous radical bulk polymerisation of vinyl monomers opt. contg. small amts. of solvent and/or initiator is such that: (a) the starting mixt. is fed to a stirred or circulating reactor (2) where it is converted to a polymer content of 45-65 (esp. 50-60) wt.% before being passed to an adiabatically operated tubular reactor (5) in which an approx. plug flow dominates, the polymer content being increased to 65-90 (esp. 70-85) wt.% in this reactor (5), with the monomer fraction at outlet (6) being at least 10 wt.%; and (b) the polymer prodn. in stirred reactor (2) is at least 1.5 times that in tubular reactor (5) and the polymer soln. leaving reactor (5) is degassed without further reaction. ADVANTAGE - Monomers such as styrene can be polymerised to high conversions with a high space-time yield.
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公开(公告)号:DE4234601A1
公开(公告)日:1994-04-21
申请号:DE4234601
申请日:1992-10-14
Applicant: BASF AG
Inventor: BRANDSTETTER FRANZ DR , GAUSEPOHL HERMANN DR , THIELE REINER PROF DR
IPC: C08F297/04
Abstract: A process for the preparation of block copolymers of styrene or equivalents thereof on the one hand and of butadiene or equivalents thereof on the other hand by sequential anionic polymerisation, in which firstly one first monomer and the organometallic compound serving as initiator are combined to form a reaction mixture, and the reaction is continued until at least some of the first monomer has been consumed and at least one further monomer is then added and in each case reacted partly or fully, characterised in that the polymerisation is carried out continuously in a manner known per se in a tubular reactor, where the reaction of one monomer in each case is carried out in one reactor section (zone) in each case, and at least two reactor sections are separated by a mixing zone.
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公开(公告)号:DE3582151D1
公开(公告)日:1991-04-18
申请号:DE3582151
申请日:1985-11-23
Applicant: BASF AG
Inventor: BRANDSTETTER FRANZ DR , HAMBRECHT JUERGEN DR , REIMANN HORST DR , ZIEGLER WALTER DR
IPC: C08L23/08 , C08L101/00
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50.
公开(公告)号:DE3571628D1
公开(公告)日:1989-08-24
申请号:DE3571628
申请日:1985-09-14
Applicant: BASF AG
Inventor: PFIRRMANN GUENTHER DR , KAST HANS DR , SCHWIEGK LOTHAR DR , BRANDSTETTER FRANZ DR
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