公开(公告)号：DE102004004718A1

公开(公告)日：2005-08-18

申请号：DE102004004718

申请日：2004-01-29

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  POLKA HANS-MARTIN ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS

IPC: C07C253/34 ,  C07C255/04 ,  C07C255/07 ,  C07C253/10

Abstract: A process is described for removing hydrogen cyanide from mixtures comprising pentenenitrile, wherein the removal is effected by an azeotropic distillation of hydrogen cyanide with 1,3-butadiene.

公开(公告)号：DE102004004684A1

公开(公告)日：2005-08-18

申请号：DE102004004684

申请日：2004-01-29

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS

IPC: C07C253/10 ,  C07C255/07 ,  B01J35/10

Abstract: A process is described for preparing 3-pentenenitrile by hydrocyanating 1,3-butadiene with hydrogen cyanide over at least one catalyst, wherein the 1,3-butadiene and/or hydrogen cyanide is contacted with at least one microporous solid before the reaction.

公开(公告)号：DE102004004682A1

公开(公告)日：2005-08-18

申请号：DE102004004682

申请日：2004-01-29

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ANGEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG

IPC: C07C253/10 ,  C07C253/30 ,  C07C253/34 ,  C07C255/04 ,  C07C255/09

Abstract: A process is described for preparing adiponitrile by hydrocyanating 1,3-butadiene over a catalyst, by, in a first process step, hydrocyanating 1,3-butadiene to 3-pentenenitrile over at least one nickel(0) catalyst, and, in a second process step, hydrocyanating 3-pentenenitrile to adiponitrile over at least one nickel(0) catalyst with addition of at least one Lewis acid, wherein at least one of the at least one nickel(0) catalysts used in the particular process steps is transferred into the other process step.

公开(公告)号：CA2553041A1

公开(公告)日：2005-08-11

申请号：CA2553041

申请日：2005-01-27

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  HADERLEIN GERD ,  BARTSCH MICHAEL ,  JUNGKAMP TIM ,  MILLER CHRISTIAN ,  SCHEIDEL JENS ,  BASSLER PETER ,  BAUMANN ROBERT ,  SIEGEL WOLFGANG

IPC: C07C253/30 ,  C07C255/07

Abstract: The invention relates to a method for isomerization of pentene nitrile in an educt flow, wherein isomerization is performed on a homogeneously dissolved catalyst.

公开(公告)号：CA2543673A1

公开(公告)日：2005-05-12

申请号：CA2543673

申请日：2004-10-28

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  SCHEIDEL JENS ,  LUYKEN HERMANN ,  FLORES MIGUEL ANGEL ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  SIEGEL WOLFGANG

IPC: C07F9/50 ,  B01J31/18 ,  B01J31/24 ,  C07C253/10 ,  C07C253/30 ,  C07C255/07 ,  C07C255/09 ,  C07F9/12 ,  C07F9/48 ,  C07F9/6574

Abstract: The invention relates to phosphinite phosphites I of formula 1, 2, 3, 4, 5 or 6 and mixtures thereof, wherein R1, R2, R4 independently represent an alkyl or alkylene group with 1 to 8 carbon atoms, provided that at least one of the groups R1, R2, R4 is different from H; R5 to R22 independently represent H, an alkyl or alkylene group with 1 to 8 carbon atoms; R3 is H, methyl or ethyl; X is F, Cl or CF3, if n=1 or 2 and X is H, if n=0.

公开(公告)号：DE10314761A1

公开(公告)日：2004-10-14

申请号：DE10314761

申请日：2003-03-31

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  MOLNAR FERENC

IPC: B01J23/755 ,  B01J31/02 ,  B01J31/14 ,  B01J31/18 ,  C07C253/10 ,  C07C255/04 ,  B01J31/12 ,  B01J31/24 ,  C07B43/08

Abstract: A system which is suitable as a catalyst for the hydrocyanation of olefinically unsaturated compounds and comprises a) Ni(0) b) a compound which complexes Ni(0) as a ligand and contains trivalent phosphorus, c) a Lewis acid and d) a compound of the formula M Rn where M: Al or Ti R: identical or different monovalent alkoxy radicals, in which case a plurality of alkoxy radicals may be bonded together, and additionally, in the case that M=Al, R may be identical or different monovalent alkyl radicals, in which case a plurality of alkyl radicals may be bonded together or one or more alkyl radicals may be bonded to one or more of the abovementioned alkoxy radicals, n: valency of M, and processes for hydrocyanating an olefinically unsaturated compound in the presence of such a system.

公开(公告)号：DE10311119A1

公开(公告)日：2004-09-23

申请号：DE10311119

申请日：2003-03-12

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  KUNSMANN-KEITEL DAGMAR PASCALE

IPC: C07C255/07 ,  C07C253/30

Abstract: Isomerization of 2-methyl-3-butenonitrile (I) to linear pentenonitrile (II) in the presence of zero-valent nickel, a tridentate phosphorus ligand and a Lewis acid comprises removing a mixture of (I) and (II) from the reaction mixture during isomerization.

公开(公告)号：AU2003246375A1

公开(公告)日：2004-02-02

申请号：AU2003246375

申请日：2003-07-04

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  SCHEIDEL JENS

IPC: B01J31/18 ,  B01J27/32 ,  B01J31/40 ,  B01J38/00 ,  C07B61/00 ,  C07C253/10 ,  C07C255/04 ,  C07C255/07

Abstract: A process for the recovery of a Lewis acid from a reaction mixture (I) which has been obtained in the hydrocyanation of an olefinically unsaturated compound to a nitrile which has a miscibility gap with water under certain pressure and temperature conditions, in the presence of a catalyst system comprising a Lewis acid and a complex compound. The method comprises a) removing the complex compound from mixture (I) to give a mixture (II), b) adding water to mixture (II) and placing mixture (II) under pressure and temperature conditions to provide a phase (III) and a phase (IV), c) adding a liquid diluent (V) which c1) does not form an azeotrope with water and whose boiling point under certain pressure conditions is higher than that of water, or c2) forms an azeotrope or heteroazeotrope with water under certain pressure conditions, to phase (III), d) subjecting the mixture of phase (III) and liquid diluent (V) to distillation under the pressure conditions mentioned in step c1) or c2), and e) subjecting mixture (VII) to hydrocyanation of an olefinically unsaturated compound to give the nitrile.

公开(公告)号：CA2464710A1

公开(公告)日：2003-04-24

申请号：CA2464710

申请日：2002-10-04

Applicant: BASF AG

Inventor： MOLNAR FERENC ,  HADERLEIN GERD ,  ALTMAYER MARCO ,  JUNGKAMP TIM ,  SIEGEL WOLFGANG ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BARTSCH MICHAEL ,  BAUMANN ROBERT

IPC: B01J31/22 ,  B01J31/18 ,  C07B61/00 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  C07C255/07 ,  C07F9/48

Abstract: The invention relates to phosphinites I of formulae (1) or (2), in which R1, R2, R5, R6, R7, R8, R9 independently represent hydrogen, an alkyl or alkylen e group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms; R3 is H or methyl; R4 is i-propyl or t-butyl; X is F, Cl or CF3 and n is 1 or 2.

公开(公告)号：BR0015200A

公开(公告)日：2002-06-18

申请号：BR0015200

申请日：2000-10-25

Applicant: BASF AG

Inventor： BAUMANN ROBERT ,  FISCHER JAKOB ,  JUNGKAMP TIM ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  SIEGEL WOLFGANG

IPC: B01J31/22 ,  B01J31/02 ,  B01J31/18 ,  C07B61/00 ,  C07C253/10 ,  C07C253/30 ,  C07C255/03 ,  C07C255/07 ,  C07C255/19 ,  C07F9/145 ,  C07F15/04

Abstract: New phosphites (I), with alkylaryl, arylaryl and/or condensed aryl groups, have 1, 2 or 3 o-substituted and optionally 1 or 2 m- and/or p-substituted aryl groups. New phosphites of formula (I), with alkylaryl, arylaryl and/or condensed aryl groups, have 1, 2 or 3 o-substituted and optionally 1 or 2 m- and/or p-substituted aryl groups; P(O-R 1>)(O-R 2>) y(O-R 3>) z(O-R 4>) p (I) R 1>an aromatic group with a 1-18 carbon (C) alkyl, an aromatic substituent or a condensed aromatic system in the o-position to the oxygen (O) atom linking the phosphorus (P) atoms to the aromatic system; R 2>a similar aromatic group substituted in the m-position; R 3>a similar aromatic group substituted in the p-position; R 4>an aromatic group with a different substituent in the o-, m- or p-position and a hydrogen (H) atom in the o-position; x : 1 or 2; y, z, p : 0, 1 or 2; (x+y+z+p) : 3 Independent claims are also included for: (a) new transition metal complexes (II) with (I) as ligand; (b) the preparation of (I); (c) the preparation of (II); (d) the addition of hydrogen cyanide to an olefinic double bond in the presence of (II) as catalyst; and (e) the isomerization of organic nitriles in the presence of (II) as catalyst.