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公开(公告)号:JP2003220327A
公开(公告)日:2003-08-05
申请号:JP2002353203
申请日:2002-12-05
Applicant: BASF AG
Inventor: KAIBEL GERD DR , MILLER CHRISTIAN , JANSEN HELMUT , KAIBEL BJOERN
Abstract: PROBLEM TO BE SOLVED: To provide a reactor in which a hot spot is difficult to occur in a catalyst packed inside the reactor, having little pressure drop when fluid reaction mixtures pass through the catalyst, and in which the heterogeneous catalyst is packed. SOLUTION: A fixed-bed reactor is described for carrying out reactions of fluid reaction mixtures in the presence of a particulate heterogeneous catalyst having a structured packing which forms interstices in the reactor interior, in which the quotient of the hydraulic diameter for the fluid flow through the structured packing and the equivalent diameter of the catalyst particles is in the range from 2 to 20, preferably in the range from 5 to 10, to such an extent that the catalyst particles are introduced into the interstices, loosely distributed and discharged under the action of gravity. COPYRIGHT: (C)2003,JPO
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公开(公告)号:JP2004034019A
公开(公告)日:2004-02-05
申请号:JP2002367784
申请日:2002-12-19
Applicant: Basf Ag , ビーエーエスエフ アクチェンゲゼルシャフト
Inventor: KAIBEL GERD DR , MILLER CHRISTIAN , KLAS KATRIN , KINDLER ALOIS , AQUILA WERNER , DOBLER WALTER , BREUER KLAUS , POMMER ACHIM , DIRNSTEINER THOMAS
CPC classification number: B01D3/141 , B01D3/14 , Y10S203/11 , Y10S203/20
Abstract: PROBLEM TO BE SOLVED: To provide a distillation column having high separation efficiency, in which the vapor amount is made constant all over the column including a feed section and a side steam take-off section.
SOLUTION: Partition walls DW are arranged substantially along the longitudinal direction of the distillation column so that the inside of the distillation column is divided into an upper zone 2 and a lower zone 4 of the feed section, an upper zone 3 and a lower zone 5 of the side stream take-off section, an upper common column section 1 and a lower common column section 6. A feeding mixture to be separated between the zones 2 and 4 of the feed section is in a wholly or partially vaporized state and/or the side stream to be taken off from the zones 3 and 5 of the side stream take-off section is in a wholly or partially vaporized state.
COPYRIGHT: (C)2004,JPO-
公开(公告)号:WO2005070858A3
公开(公告)日:2005-11-10
申请号:PCT/EP2005000531
申请日:2005-01-20
Applicant: BASF AG , RUDOLF PETER , MILLER CHRISTIAN
Inventor: RUDOLF PETER , MILLER CHRISTIAN
CPC classification number: C07C41/28 , C07C41/08 , C07C41/58 , Y02P20/582 , C07C43/303 , C07C43/15
Abstract: The invention relates to a method for the production of isopropenyl ethers of formula (A), wherein R represents an aliphatic, cycloaliphatic, aralyphatic, aromatic or heterocyclic radical which can include other substituents which do not react with acetylenes or allens, by reacting a gaseous flow (I), containing MAPD which is obtained from an olefin system and which is used to separate C3-sections, with at least one gaseous flow selected from a gaseous flow (II) containing an acetone ketal of formula (B), wherein R has the above-mentioned meaning, and a gaseous flow (III) containing a monohydroxyalcohol ROH, wherein R has the above-mentioned meaning, in the presence of a heterogeneous catalyst.
Abstract translation: 可以提议用于制备式(A)其中R为的异丙烯基醚的制备方法的脂族,脂环族,aralyphatischen指芳族或杂环基团,其不与乙炔或丙二烯,携带,通过使反应的其他取代基 - 一 含有从C3馏分分离用烯烃装置获得的MAPD的气态物流I,其包含至少一种选自如下的气态物流: - 含有式(B)的酮的缩酮的气态物流II,其中R如上定义 意思是 - 含有一元醇ROH的气体流III,其中R具有上述定义的含义 - 在非均相催化剂存在下。
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公开(公告)号:WO2005042443A3
公开(公告)日:2005-07-28
申请号:PCT/EP2004012097
申请日:2004-10-26
Applicant: BASF AG , MILLER CHRISTIAN , HEYDRICH GUNNAR , KLASS KATRIN , BECKER MICHAEL
Inventor: MILLER CHRISTIAN , HEYDRICH GUNNAR , KLASS KATRIN , BECKER MICHAEL
Abstract: The invention relates to a method for the production of orthoesters, wherein a first orthoester and a first alcohol are guided into a rectification column such that in at least one area of the column the first orthoester and the first alcohol react with a second orthoester and a second alcohol, and the second orthoester and the second alcohol are removed from the reaction area.
Abstract translation: 本发明公开了用于制备原酸酯,其中一个引入第一原酸酯和在精馏塔中这样的条件下,即在列中,第一原酸酯与第一醇到第二原酸酯和第二醇的至少一个区域的反应下的第一醇的方法,和 第二原酸酯与从反应区中连续地去除第二醇。
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公开(公告)号:ES2290349T3
公开(公告)日:2008-02-16
申请号:ES02791781
申请日:2002-12-05
Applicant: BASF AG
Inventor: KAIBEL GERD , MILLER CHRISTIAN , DOBLER WALTER , DIRNSTEINER THOMAS , SIGL MARCUS , JANSEN HELMUT
IPC: B01D3/26 , B01D3/00 , B01J19/32 , B01J8/00 , B01J8/02 , B01J8/04 , B01J8/12 , B01J19/24 , B01J21/04 , B01J23/10 , B01J35/02 , C07B61/00 , C07C45/28 , C07C45/72 , C07C45/74 , C07C49/203
Abstract: Columna para la puesta en práctica de destilaciones reactivas en presencia de un catalizador heterogéneo en forma de partículas, con una empaquetadura formada por chapas de empaquetadura que forman cavidades en el espacio interior de la columna, caracterizada porque la columna presenta primera y segunda zona parcial, que están dispuestas alternantemente, y se diferencian en la superficie específica de las chapas de empaquetadura, de tal manera que en las primeras zonas parciales el cociente de diámetro hidráulico para la corriente gaseosa a través de la empaquetadura y el diámetro equivalente de partículas de catalizador se sitúa en el intervalo de 2 a 20, preferentemente en el intervalo de 5 a 10, de modo que las partículas de catalizador se pueden introducir en las cavidades, distribuir y descargar sueltas bajo acción de la fuerza de gravedad, y porque en las segundas zonas parciales el cociente de diámetro hidráulico para la corriente gaseosa a través de la empaquetadura y el diámetro equivalente de partículas de catalizador es menor que 1, y porque en las segundas zonas parciales no se introducen partículas de catalizador.
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公开(公告)号:DE102004033183A1
公开(公告)日:2006-02-02
申请号:DE102004033183
申请日:2004-07-09
Applicant: BASF AG
Inventor: KASHANI-SHIRAZI NAWID , MILLER CHRISTIAN , HEISLER HEINRICH-DIETER , MUELLER JOACHIM
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公开(公告)号:CA2548262A1
公开(公告)日:2005-06-23
申请号:CA2548262
申请日:2004-12-10
Applicant: BASF AG
Inventor: DOBLER WALTER , MILLER CHRISTIAN , KINDLER ALOIS , BAHR NICOLAUS , SALDEN AXEL
IPC: C07C49/04 , C07C45/62 , C07C45/74 , C07D231/12 , C07D231/14 , C07D231/16 , C07D231/18 , C07D231/38 , C07D231/56 , C07D233/54 , C07D235/06 , C07D249/12 , C07D257/04 , C07D311/72 , C07D401/12 , C07D403/12 , C07D409/04 , C07D473/34
Abstract: The invention relates to a method for the production of tetrahydrogeranylacetone (tetrahydropseudoionone) by means of aldolcondensation of citral with acetone and subsequent hydrogenation. The invention also relates to the utilization of the tetrahydrogeranylacetone th us obtained for the production of phytol, isophytol, tocopherol and/or tocopher ol derivatives. The invention further relates to methods for the production of tocopherols and/or tocopherol derivatives.
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公开(公告)号:DE10233231A1
公开(公告)日:2004-02-05
申请号:DE10233231
申请日:2002-07-22
Applicant: BASF AG
Inventor: MILLER CHRISTIAN , RUDOLF PETER , TELES JOAQUIM HENRIQUE
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公开(公告)号:CA2492269A1
公开(公告)日:2004-01-22
申请号:CA2492269
申请日:2003-07-14
Applicant: BASF AG
Inventor: MILLER CHRISTIAN , GOEBBEL HANS-GEORG , KAIBEL GERD , AQUILA WERNER , DOBLER WALTER , DIRNSTEINER THOMAS , HAHN THILO , BREUER KLAUS
Abstract: A method for the production of tetrahydrogeranylacetone is disclosed, whereb y pseudoionone, geranylacetone and/or dihydrogeranylacetone in the liquid phas e, in which particles of a catalyst, for the preferential hydrogenation of carb on- carbon double bonds before carbon-oxygen double bonds, are suspended, is fed through a device along in the presence of a gas comprising hydrogen, said device preventing the transport of the catalyst particles.
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公开(公告)号:DE10159816A1
公开(公告)日:2003-06-18
申请号:DE10159816
申请日:2001-12-06
Applicant: BASF AG
Inventor: KAIBEL GERD , MILLER CHRISTIAN , JANSEN HELMUT , KAIBEL BJOERN
Abstract: Fixed bed reactor comprises a structured packing (1) forming intermediate chambers (3) inside the reactor. The quotient of the hydraulic diameter for the fluid stream through the packing and the equivalent diameter of catalyst particles (4) is in the region of 2-20, preferably 5-10. The catalyst particles are introduced into the intermediate chambers under the action of gravity, loosely distributed and removed. Preferred Features: The structured packing has a cross-channel structure, and comprises packing sheets for insertion along the longitudinal axis of the reactor. The packing has a reduced flow resistance on its surface.
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