公开(公告)号：SK282254B6

公开(公告)日：2001-12-03

申请号：SK156096

申请日：1996-12-05

Applicant: BASF AG

Inventor： ELLER KARSTEN ,  KUMMER RUDOLF ,  STOPS PETER

IPC: B01J29/06 ,  C07B61/00 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C211/17 ,  C07C211/21 ,  C07C211/25 ,  C07C211/26 ,  C07C211/35 ,  C07C211/40 ,  C07C211/45

Abstract: Preparation of amines of formula (I) is claimed, which comprises reacting olefins of formula (II) with ammonia or a primary or secondary amine of formula HN(R )(R ) (III) at temperatures of 200-350 degrees C. and pressures of 100-300 bar in the presence of a heterogeneous catalyst comprising type SSZ-37 zeolite. R -R = H, 1-20C alkyl 2-20C alkenyl, 2-20C alkynyl, 3-20C cycloalkyl, 4-20C alkylcycloalkyl, 4-20C cycloalkylalkyl, aryl, 7-20C alkylaryl or 7-20C aralkyl. Or R and R together form a saturated or unsaturated 3-9C alkylene bridge; Or R or R = 21-200C alkyl, 21-200C alkenyl or together form a 2-12C alkylene bridge.

公开(公告)号：DE59606731D1

公开(公告)日：2001-05-10

申请号：DE59606731

申请日：1996-12-04

Applicant: BASF AG

Inventor： ELLER KARSTEN ,  KUMMER RUDOLF ,  STOPS PETER

IPC: C07D295/02 ,  B01J29/70 ,  C07B61/00 ,  C07C209/60 ,  C07C211/07 ,  C07D207/323

Abstract: PCT No. PCT/EP96/05406 Sec. 371 Date Jan. 29, 1998 Sec. 102(e) Date Jan. 29, 1998 PCT Filed Dec. 4, 1996 PCT Pub. No. WO97/21661 PCT Pub. Date Jun. 19, 1997A process for preparing amines of the general formula I (I) where R1, R2, R3, R4, R5 and R6 are each hydrogen, C1-C20-alkyl, C2-C20-alkenyl, C2-C20-alkynyl, C3-C20-cycloalkyl, C4-C20-alkylcycloalkyl, C4-C20-cycloalkylalkyl, aryl, C7-C20-alkylaryl or C7-C20-aralkyl, R1 and R2 are together a saturated or unsaturated C3-C9-alkylene dichain, and R3 or R5 are each C21-C200-alkyl or C21-C200-alkenyl or together a C2-C12-alkylene dichain by reacting olefins of the general formula II as defined above, with ammonia or primary or secondary amines of the general formula III , at temperatures from 200 DEG to 350 DEG C. and pressures from 100 to 300 bar in the presence of a heterogeneous catalyst, comprises using a heterogeneous catalyst comprising zeolites of the type SSZ-26, SSZ-33, CIT-1 or mixtures thereof.

公开(公告)号：DE59603989D1

公开(公告)日：2000-01-27

申请号：DE59603989

申请日：1996-08-19

Applicant: BASF AG

Inventor： DINGERDISSEN UWE ,  KUMMER RUDOLF ,  STOPS PETER ,  MUELLER ULRICH ,  HERRMANN JUERGEN ,  ELLER KARSTEN

IPC: B01J29/86 ,  C07B61/00 ,  C07C209/60 ,  C07C211/07 ,  C07C211/35

公开(公告)号：SK35298A3

公开(公告)日：1998-10-07

申请号：SK35298

申请日：1996-12-04

Applicant: BASF AG

Inventor： ELLER KARSTEN ,  KUMMER RUDOLF ,  STOPS PETER

IPC: B01J29/70 ,  C07B61/00 ,  C07C209/60 ,  C07D295/02 ,  C07C211/07 ,  C07D207/323

Abstract: A process is disclosed for producing amines of general formula (I) in which: R1, R2, R3, R4, R5, R6 stand for hydrogen, C1-C20-alkyl, C2-C20-alkenyl, C2-C20-alkinyl, C3-C20-cycloalkyl, C4-C20-alkyl-cycloalkyl, C4-C20-cycloalkyl-alkyl, aryl, C7-C20 alkylaryl or C7-C20-aralkyl; R1 and R2 together represent a saturated or unsaturated C3-C9 alkylene di-chain; and R3 or R5 stand for C21-C200-alkyl, C21-C200-alkenyl or together stand for a C2-C12 alkylene di-chain. The process involves reacting the olefins of general formula (II), in which R3, R4, R5, R6 have the above meanings, with ammonia or primary or secondary amines of general formula (III), in which R1 and R2 have the above meanings, at temperatures of 200 - 350 C and pressures of 100 - 300 bar in the presence of a heterogenous catalyst in the form of zeoliths of type SSZ-26, SSZ-33, CIT-1 or mixtures thereof.

公开(公告)号：SK48997A3

公开(公告)日：1998-05-06

申请号：SK48997

申请日：1997-04-18

Applicant: BASF AG

Inventor： KARSTEN ELLER ,  KUMMER RUDOLF ,  MULLER ULRICH

IPC: B01J21/12 ,  B01J23/10 ,  C07B61/00 ,  C07C209/02 ,  C07C209/60 ,  C07C211/03 ,  C07C211/16 ,  C07C211/21 ,  C07C211/25 ,  C07C211/26 ,  C07C211/34 ,  C07C211/45 ,  C07C211/54 ,  C07C211/57 ,  B01J21/00 ,  B01J23/94 ,  B01J23/92

Abstract: Method for preparation of amines of general formula (I) wherein R1, R2, R3, R4, R5, R6 are H, C2-20 alkyl, C1-20 alkenyl, C2-20 alkinyl, C3-20 cycloalkyl, C4-20 alkylcycloalkyl, C4-20 cycloalkylalkyl, aryl, C7-20alkylaryl or C7-20 aralkyl, R1 and R2 are together saturated or unsaturated C3-9 alkylene dichain and R3 and R5 C21-200 alkyl, C21-200 alkylene, or together C21-200 alkylene dichain, wherein reacts olefin of general formula (II), wherein R3, R4, R5 and R6 are of the said meaning, with ammonia or primary or secondary amine of general formula (III), wherein R1 and R2 are of the said meaning, under the temperatures 200 to 350 C and pressure 10.0 to 30.0 Mpa in the presence of mesoporous oxide with SiO2 as the main component with the BET surface in the shape of powder 400 to 600 m2g1, wherein the roentgenographic reflexes in the range of angles 2 to 6 2theta, used as a catalyst.

公开(公告)号：SK156096A3

公开(公告)日：1997-11-05

申请号：SK156096

申请日：1996-12-05

Applicant: BASF AG

Inventor： ELLER KARSTEN ,  KUMMER RUDOLF ,  STOPS PETER

IPC: B01J29/06 ,  C07B61/00 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C211/17 ,  C07C211/21 ,  C07C211/25 ,  C07C211/26 ,  C07C211/35 ,  C07C211/40 ,  C07C211/45

Abstract: Discloses is a process for preparation of amines of general formula (I) wherein R1, R2, R3, R4, R5, R6 are hydrogen, C1-20 alkyl, C2-8 alkenyl, C2H propargyl, C3-12 cycloalkyl, C5-10 alkyl-cycloalkyl, C4-12 cycloalkyl-alkyl, aryl, C7-12 alkylaryl or C7-12 aralkyl, R1 and R2 together are saturated or unsaturated C3-9 alkylene dichain and R3 or R5 are C21-200 alkenyl or together C2-12 alkylene dichain by the reaction of olefins of general formula (II) with ammonia or primary or secondary amines of general formula (III), under the temperature 200 to 350 C and the pressure 100 . 10exp(5) to 300 . 10exp(5) Pa in the presence of heterogeneous catalyst, using SSZ-37 zeolite as a heterogeneous catalyst.

公开(公告)号：SK93496A3

公开(公告)日：1997-03-05

申请号：SK93496

申请日：1996-07-17

Applicant: BASF AG

Inventor： ELLER KARSTEN ,  MUELLER ULRICH ,  KUMMER RUDOLF ,  STOPS PETER

IPC: B01J29/70 ,  B01J29/74 ,  B01J29/76 ,  B01J29/78 ,  C07B61/00 ,  C07C209/60 ,  C07C211/03 ,  C07C211/17 ,  C07C211/21 ,  C07C211/23 ,  C07C211/27 ,  C07C211/35 ,  C07C211/45

Abstract: Disclosed is a process for preparation of amines of general formula (I) wherein R1, R2, R3, R4, R5, R6 are hydrogen, C1-20 alkyl, C2-12 alkenyl, C2-8 alkinyl, C3-12 cycloalkyl, C4-12 alkyl-cycloalkyl, C4-12 cycloalkyl-alkyl, aryl, C7-16 alkylaryl or C7-16 aralkyl, R1 and R02 together are saturated or unsaturated C3-9 alkylene di-chain and R3 or R5 are together C2-12 alkylene dichain, by the reaction of olefins of general formula (II), wherein R3, R4, R5 and R6 are of the said meanings with ammonia or primary or secondary amines of general formula (III) wherein R1 and R2 are of the said meaning, under the temperatures from 200 to 350 C and pressures 100 . 10exp(5) Pa, in the presence of heterogeneous catalysts wherein the PSH-3-, MCM-22, SSZ-25 zeolites or mixtures thereof are used as heterogeneous catalyst.

公开(公告)号：ZA956574B

公开(公告)日：1997-02-07

申请号：ZA956574

申请日：1995-08-07

Applicant: BASF AG

Inventor： STOPS PETER ,  REIF WOLFGANG ,  FRANZ LOTHAR ,  MENGER VOLKMAR ,  BECKER RAINER ,  KUMMER RUDOLF ,  WINDERL SIEGFRIED

IPC: B01J21/06 ,  B01J23/885 ,  B01J37/03 ,  B01J23/88 ,  C07C209/08 ,  C07C209/16 ,  C07C209/18 ,  C07C211/03 ,  C07C ,  C07F ,  B01J

Abstract: Prodn. of amines (I) comprises reacting a primary or secondary alcohol (II) with ammonia or a primary or secondary amine (III) at 80-250 deg.C under 1-400 bar hydrogen pressure in the presence of a catalyst comprising: a) 20-85wt.% O2-contg. Zr cpds. calculated as ZrO2; b) 1-30 wt.% O2-contg. Cu cpds. calculated as CuO; c) 30-70 wt.% O2 contg. Ni cpds. calculated as NiO; d) 0-15 wt.% O2 contg. Mo cpds. calculated as MoO3; and opt. e) up to 10 wt.% O2-contg. Al and/or Mn cpds. calculated as Al2O3 or MnO2.

公开(公告)号：AT69800T

公开(公告)日：1991-12-15

申请号：AT87114503

申请日：1987-10-05

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG ,  TAGLIEBER VOLKER ,  POHL HANS HENNING ,  KUMMER RUDOLF ,  BAUR KARL GERHARD

IPC: B01J29/86 ,  B01J29/00 ,  B01J29/04 ,  B01J29/46 ,  B01J29/88 ,  C07B61/00 ,  C07C67/00 ,  C07C209/00 ,  C07C209/60 ,  C07C211/02 ,  C07C211/07

公开(公告)号：CA1237443A

公开(公告)日：1988-05-31

申请号：CA458662

申请日：1984-07-11

Applicant: BASF AG

Inventor： SCHNEIDER HEINZ-WALTER ,  RICHTER WOLFGANG ,  DISTELDORF WALTER ,  KUMMER RUDOLF

IPC: B01J31/00 ,  B01J31/20 ,  B01J31/24 ,  C07B61/00 ,  C07C67/313 ,  C07C67/38 ,  C07C67/39 ,  C07C69/44 ,  C07C69/67

Abstract: - 7 - O.Z. 0050/36619 Pure monoesters of adipic acid are prepared by a process in which a) a pentenoate is reacted with carbon monoxide and hydrogen at from 90 to 140.degree.C and under from 5 to 300 bar in the presence of a carbonyl complex of cobalt or of rhodium, and a 5-formylvalerate is separated off, and b) the 5-formylvalerate thus obtained is oxidized with molecular oxygen, or with a gas containing this, at from 20 to 100.degree.C under from 1 to 10 bar.