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    METHOD FOR THE CONTINUOUS PRODUCTION OF ALDEHYDES
    2.
    发明申请
    METHOD FOR THE CONTINUOUS PRODUCTION OF ALDEHYDES 审中-公开
    连续生产醛的方法

    公开(公告)号：WO2005042458A3

    公开(公告)日：2005-06-09

    申请号：PCT/EP2004011530

    申请日：2004-10-14

    Applicant: BASF AG ,  VOLLAND MARTIN ,  MACKEWITZ THOMAS ,  AHLERS WOLFGANG ,  SCHAEFER ANSGAR ,  RICHTER WOLFGANG ,  PACIELLO ROCCO

    Inventor： VOLLAND MARTIN ,  MACKEWITZ THOMAS ,  AHLERS WOLFGANG ,  SCHAEFER ANSGAR ,  RICHTER WOLFGANG ,  PACIELLO ROCCO

    IPC: B01J31/18 ,  B01J31/24 ,  C07C45/50 ,  C07C47/02

    CPC classification number: B01J31/186 ,  B01J2231/321 ,  B01J2531/822 ,  C07C45/50 ,  C07C47/02

    Abstract: The invention relates to a method for the continuous production of aldehydes comprising between 5 and 21 carbon atoms, by the isomerising hydroformylation in a homogenous phase of olefin compositions comprising between 4 and 20 carbon atoms and containing alpha-olefins and olefins with internal double bonds, by means of a synthesis gas, in the presence of a homogeneous rhodium catalyst that is complexed with an organophosphorus ligand containing oxygen atoms and/or nitrogen atoms and a free ligand. Said production is carried out at high temperature and high pressure in a multi-stage reaction system consisting of at least two reaction zones. According to said method, the olefin composition is first reacted in a first reaction zone or a group of several first reaction zones at a total pressure of between 10 and 40 bar, using a synthesis gas with a CO/H2 molar ratio of between 4:1 and 1:2 until a 40 to 95 % conversion of the alpha-olefins is obtained. The hydroformylation product from the first reaction zone or group of several first reaction zones is then reacted in a subsequent reaction zone or group of several reaction zones at a total pressure of between 5 and 30 bar, using a synthesis gas with a CO/H2 molar ratio of between 1:4 and 1:1000. The total pressure in the subsequent reaction zone or zones is respectively 1 to (G1-Gf) bar lower than that of the preceding reaction zone, whereby G1 represents the total pressure in the respective preceding reaction zone and Gf represents the total pressure in the respective reaction zone that succeeds said first reaction zone or zones, with the proviso that the difference between G1 and Gf is greater than 1 bar and the partial CO pressure in the subsequent reaction zone or zones is respectively lower than that of the preceding reaction zone.

    Abstract translation: 用于连续制备含有内部双键具有4至20个碳原子的烯烃组合物由合成气的装置在含具有一个氧和/或氮原子的有机磷配体的存在下，通过在α-烯烃的均相异构化的加氢甲酰化的5至21个碳原子的醛和烯烃的配位过程 均相铑催化剂，并在升高的温度和在包括至少两个反应区的多阶段反应系统中升高的压力游离配位体，其中一个最初的烯烃的一组中的一个或多个第一反应区中在10至40巴的总压力与合成气 的CO / H2摩尔比为4：1至1：2的一组的一个或多个在反应至40的α-烯烃的转化率，以95％和加氢甲酰化混合物从该组下方的一个或多个第一反应区 反应1000，其中在一个或多个随后的反应区中的总压力通过1巴下，以（G1 GF）：在5〜30巴以1:1的CO / H 2摩尔比的总压力与合成气连接的反应区：4至1 比在各自的前一反应区中，其中G 1表示用于在一个或多个第一反应区的每个后续反应区中的总压各自的前一反应区和GF的总压力，条件是不同的是G1 GF大于1巴的条件， 并且其中所述一个或多个后续反应区中的CO分压在每种情况下低于在前面的反应区中的CO分压。

    PROCEDIMIENTO PARA EL HIDROFORMIDADO DE OLEFINAS CON 2 A 6 ATOMOS DE CARBONO.
    4.
    发明专利
    PROCEDIMIENTO PARA EL HIDROFORMIDADO DE OLEFINAS CON 2 A 6 ATOMOS DE CARBONO. 未知

    公开(公告)号：ES2282631T3

    公开(公告)日：2007-10-16

    申请号：ES03729477

    申请日：2003-01-16

    Applicant: BASF AG

    Inventor： RICHTER WOLFGANG ,  MULLER ROLF ,  KROKOSZINSKI ROLAND

    IPC: C07C45/50 ,  C07B61/00 ,  C07C29/16 ,  C07C31/02 ,  C07C45/00 ,  C07C47/02

    Abstract: Procedimiento para el hidroformilado, en el que se hace reaccionar continuamente al menos una olefina con 2 a 6 átomos de carbono con monóxido de carbono e hidrógeno en presencia de un catalizador de hidroformilado en una zona de reacción, que contiene una fase líquida, y de la fase líquida se extrae una corriente S), de esta corriente se extrae calor, y a continuación se devuelve un componente material a la zona de reacción, continuando la reacción en la corriente S) al menos hasta la extracción de calor, y alimentándose a esta corriente monóxido de carbono y/o hidrógeno, antes de que la misma se empobrezca en éstos en tal medida que los componentes remanentes entren en reacciones secundarias indeseables, y/o el hidroformilado se detenga esencialmente.

    PROCEDIMIENTO PARA LA OBTENCION DE PRTODUCTOS DE HODROFORMILACION DE OLEFINAS CON 2 HASTA 8 ATOMOS DE CARBONO.
    5.
    发明专利
    PROCEDIMIENTO PARA LA OBTENCION DE PRTODUCTOS DE HODROFORMILACION DE OLEFINAS CON 2 HASTA 8 ATOMOS DE CARBONO. 未知

    公开(公告)号：ES2254478T3

    公开(公告)日：2006-06-16

    申请号：ES01967099

    申请日：2001-06-27

    Applicant: BASF AG

    Inventor： RICHTER WOLFGANG ,  KROKOSZINSKI ROLAND ,  MULLER ROLF ,  GEISSLER BERNHARD

    IPC: C07B61/00 ,  C07C45/50 ,  C07C47/02

    Abstract: Procedimiento para la obtención de productos de hidroformilación de olefinas con 2 hasta 8 átomos de carbono, en el que a) se alimenta una materia prima hidrocarbonada en una zona de craqueo/deshidrogenación y se somete a un craqueo térmico y/o catalítico y/o a una deshidrogenación obteniéndose un gas de disociación que contiene olefinas, b) se somete al gas de disociación, o fracciones del mismo, a una separación en, al menos, una corriente hidrocarbonada enriquecida en olefina con i átomos de carbono y, al menos, una corriente hidrocarbonada empobrecida en olefina con i átomos de carbono, c) se alimenta la corriente hidrocarbonada, enriquecida en olefina con i átomos de carbono, con monóxido de carbono e hidrógeno en una zona de hidroformilación y se hace reaccionar en presencia de un catalizador para la hidroformilación, d) se separa, a partir de la descarga procedente de la zona de hidroformilación, una corriente constituida esencialmente por olefina con i átomos de carbono no convertida y por hidrocarburo con i átomos de carbono saturado, e) se recila la corriente constituida esencialmente por olefina con i átomos de carbono no convertida y por el hidrocarburo con i átomos de carbono saturado, al menos en parte hasta la etapa b), significando i un número entero desde 2 hasta 8.

    6.
    发明专利
    未知

    公开(公告)号：DE50101627D1

    公开(公告)日：2004-04-08

    申请号：DE50101627

    申请日：2001-06-27

    Applicant: BASF AG

    Inventor： RICHTER WOLFGANG ,  KROKOSZINSKI ROLAND ,  MUELLER ROLF ,  MCATEE MICHAEL

    IPC: C07B61/00 ,  C07C45/50 ,  C07C47/02

    Abstract: Disclosed is a method for the hydroformylation of olefins comprising 2 to 8 atoms, whereby a) an inflow containing olefins and a gas mixture containing hydrogen and carbon monoxide are fed into a reaction zone and reacted in the presence of a hydroformylation catalyst, b) the reaction product which is released from the raw hydroformylation product is redirected into the reaction zone during the extraction of a gaseous recovery flow. The inventive method is characterised in that c) the recovery flow is brought into intimate contact with a wash liquid in order to eliminate the unreacted olefins contained therein, the wash liquid being a vented hydroformylation product, and the olefin-charged wash liquid and the raw hydroformylation product are redirected for regeneration. Said inventive method enables unreacted olefins to be reclaimed to a large extent from the recovery flow.

    7.
    发明专利
    未知

    公开(公告)号：AT260882T

    公开(公告)日：2004-03-15

    申请号：AT01962789

    申请日：2001-06-27

    Applicant: BASF AG

    Inventor： RICHTER WOLFGANG ,  KROKOSZINSKI ROLAND ,  MUELLER ROLF ,  MCATEE MICHAEL

    IPC: C07B61/00 ,  C07C45/50 ,  C07C47/02

    Abstract: Disclosed is a method for the hydroformylation of olefins comprising 2 to 8 atoms, whereby a) an inflow containing olefins and a gas mixture containing hydrogen and carbon monoxide are fed into a reaction zone and reacted in the presence of a hydroformylation catalyst, b) the reaction product which is released from the raw hydroformylation product is redirected into the reaction zone during the extraction of a gaseous recovery flow. The inventive method is characterised in that c) the recovery flow is brought into intimate contact with a wash liquid in order to eliminate the unreacted olefins contained therein, the wash liquid being a vented hydroformylation product, and the olefin-charged wash liquid and the raw hydroformylation product are redirected for regeneration. Said inventive method enables unreacted olefins to be reclaimed to a large extent from the recovery flow.

    10.
    发明专利
    未知

    公开(公告)号：DE3775080D1

    公开(公告)日：1992-01-23

    申请号：DE3775080

    申请日：1987-01-23

    Applicant: BASF AG

    Inventor： HUTMACHER HANS-MARTIN ,  MERGER FRANZ ,  BROECKER FRANZ JOSEF ,  FISCHER ROLF ,  VAGT UWE ,  HARDER WOLFGANG ,  PRIESTER CLAUS-ULRICH ,  SCHNEIDER HEINZ-WALTER ,  RICHTER WOLFGANG

    IPC: B01J23/74 ,  B01J23/78 ,  B01J25/00 ,  C07B61/00 ,  C07D201/08

    Abstract: (i) 5-formyl-valeric acid ester is reacted with excess NH3 and H2, using alkanols as solvents, in the presence of hydrogenation catalysts, at 40-130 deg.C. (ii) NH3 and H2 are removed from the reaction mixt. obtd. (iii) The reaction mixt. is heated to 150-250 deg.C and caprolactam is recovered. (A) Catalysts are used which are prepd. by calcining cpds. having formula (I): ((MgaNi(II)bCo(II)c)Al2)CO3(OH)16 x 4 H2O (I) a = integer or decimal no. 0-4; b,c = integers or decimal nos. 0-6; provided that 2 x (a + b + c) = 2. at 200-600 deg.C and subsequent redn. with H2 at higher temp. (B) Ni catalysts can also be used contg. 30-60 wt.% finely-divided Ni pptd. on Mg silicate. (C) Raney-Ni or Raney-Co catalysts can be used in a suspension process. (D) The Raney-Ni or Raney-Co catalyst can be fixed magnetically or electro-magnetically in the reaction-zone.

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