Composition useful for labelling biologically degradable polymers contains biologically degradable polymer and fluorescent dye

    公开(公告)号:DE19848873A1

    公开(公告)日:2000-04-27

    申请号:DE19848873

    申请日:1998-10-23

    Applicant: BASF AG

    Abstract: A composition containing: (X) a biologically degradable polymer and (Y) at least one fluorescent dye is new. Independent claims are also included for: (1) An acid component (A) from: (a1) 30-95 mole% of at least one aliphatic or cycloaliphatic dicarboxylic acid, an ester forming derivative, or a mixture of these, (a2) 5-70 mole% of at least one aromatic dicarboxylic acid or an ester forming derivative, or a mixture of these, (a3) 0-5 mole% of a compound containing sulfonate groups; (B) a diol component selected from: at least one 2-12C alkanediol and at least one 5-10C cycloalkanediol or their mixtures, and optionally one or more components selected from: (C) a component selected from: (c1) at least one ether-functional dihydroxy compound of formula (I): HO((CH2)n-O)m-H (I) HO-(C(O)-G-O-)pH (IIa) n = 2,3, or 4, and m = 2-250, (c2) at least one hydroxycarboxylic acid of formula (IIa) or (IIb): p =1-1500, r = 1-4, G = a residue selected from phenylene, -(CH2)q-, where q = 1-5, -C(R)H-, and -C(R)HCH2, where R = Me or Et, (c3) = at least one 2-12C amino-alkanol or at least one 5-10C-aminocycloalkanol or their mixtures, (c4) = at least one 1-8C diaminoalkane, (c5) = at least one 2,2-bisoxazoline of formula (III): where R = a single compound, a (CH2), with z-alkylene groups, with z = 2,3, or 4, or phenyl, (c6) = at least one aminocarboxylic acid, selected from a group consisting of natural aminoacids, polyamides of maximum molecular weight 18000 g/mol, obtainable by polycondensation of a 4-6C dicarboxylic acid and a 4-10C diamine, compounds of formula IVa and IVb: where s = 1-1500, and t = 1-4, and T = a residue selected from a group consisting of phenylene, -CH2)n-, where n = 1-12, -C(R )H-, and -C(R )HCH2, where R = Me, Et, polyoxazoline with the recurring unit V: where R = H, 1-6C alkyl, 5-8C cycloalkyl, unsubstituted or substituted with 1-4C alkyl up to 3-fold substituted phenyl, or equals tetrahydrofuryl, or mixture of (c1) to (c6); and (D), a component selected from: (d1) at least one compound with at least 3 groups able to form esters , (d2) at least one isocyanate, and (d3) at least one divinylether, or a mixture of (d1) to (d3); (2) a shaped body, film, or fibers obtained from the composition; (3) a process for labelling a biologically degradable polymer (X) involving mixing it with at least one fluorescent dye (Y) in an amount such that a fluorescence is produced which can be detected by a detector when the composition is subjected to electromagnetic radiation; (4) sorting of a compost mill, where the biologically degradable polymer contained in it is detected, loaded into the compost mill, and the unlabelled biologically undegradable polymer is removed from the compost mill. HO-(-C(O)-T-N(N)-)sH (IVa)

    46.
    发明专利
    未知

    公开(公告)号:DE19830389A1

    公开(公告)日:2000-01-13

    申请号:DE19830389

    申请日:1998-07-08

    Applicant: BASF AG

    Abstract: The invention relates to the utilization of shaped materials based on at least one biologically degradable polyactide or polyester or the mixtures thereof for producing foils for air-dried or smoked food products. The invention also relates to a method of production of said foils and biaxially oriented and thermofixed tubular films from a shaped material based on at least one biologically degradable polyactide or polyester or the mixtures thereof.

    47.
    发明专利
    未知

    公开(公告)号:DE19704275A1

    公开(公告)日:1998-08-06

    申请号:DE19704275

    申请日:1997-02-05

    Applicant: BASF AG

    Abstract: The invention relates to a transparent, stretchable film, especially for modified atmosphere food packaging, comprising at least three levels A,B,C and possibly D, wherein A is composed of a polymer P1 or a mixture of P1 and P2 and P1 is a rubber elastic block copolymer of styrene and a special softening phase of styrene and butadiene; the second layer B is made of a polymer P2 exhibiting a water vapour permeability Pw of less than 8; the third layer C is made of a polymer with an oxygen permeability Po of less than 1000; and optionally a fourth layer D made of a polymer without any limitation of permeability. The invention also relates to the use of the above-mentioned film as food packaging and to a method of packing food in particular, especially one using said film in a standard packing machine.

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