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公开(公告)号:IN155261B
公开(公告)日:1985-01-12
申请号:IN909CA1980
申请日:1980-08-08
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED , ROTHBUHR LOTHAR , GREWATTA HEINZ
IPC: C08K3/00 , C04B20/10 , C08K5/00 , C08K5/5419 , C08K9/06 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08C7/00 , C08C9/10 , C08D7/00
Abstract: The invention relates to a silane/filler preparation, consisting essentially of from 5 to 70% by weight of at least one silane corresponding to the following formula Xp-CmH2m+1-pSiRn1(OR)3-n, I in which X=a halogen atom, preferably chlorine or bromine, p=1 or 2, m=1 to 5, R1=a C1-C5 alkyl group, C5-C8-cycloalkyl group or a phenyl group, R=a C1-C5-alkyl group, a C5-C8-cycloalkyl group, a phenyl group, a benzyl group or a C1-C5-alkoxy-C1-C5-alkyl group, and n=0, 1 or 2, and-respectively balanced to 100%-from 95 to 30% by weight of at lesat one inorganic filler, preferably carbon black and silicate fillers as, e.g., silica. There is also disclosed a process for the production of the silane/filler preparation and its use in optionally cross-linkable polymeric moulding compositions or vulcanizable or cross-linkable rubber moulding compositions such as sulphur-vulcanizable moulding compositions based on natural rubber and/or synthetic rubber.
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公开(公告)号:AU531546B2
公开(公告)日:1983-08-25
申请号:AU6118380
申请日:1980-08-08
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED , ROTHBUHR LOTHAR , GREWATTA HEINZ
IPC: C08K3/00 , C04B20/10 , C08K5/00 , C08K5/5419 , C08K9/06 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08J3/24 , C08L9/06 , C08L11/00 , C09C1/28 , C09C1/42 , C09C1/56 , C09C3/12
Abstract: The invention relates to a silane/filler preparation, consisting essentially of from 5 to 70% by weight of at least one silane corresponding to the following formula Xp-CmH2m+1-pSiRn1(OR)3-n, I in which X=a halogen atom, preferably chlorine or bromine, p=1 or 2, m=1 to 5, R1=a C1-C5 alkyl group, C5-C8-cycloalkyl group or a phenyl group, R=a C1-C5-alkyl group, a C5-C8-cycloalkyl group, a phenyl group, a benzyl group or a C1-C5-alkoxy-C1-C5-alkyl group, and n=0, 1 or 2, and-respectively balanced to 100%-from 95 to 30% by weight of at lesat one inorganic filler, preferably carbon black and silicate fillers as, e.g., silica. There is also disclosed a process for the production of the silane/filler preparation and its use in optionally cross-linkable polymeric moulding compositions or vulcanizable or cross-linkable rubber moulding compositions such as sulphur-vulcanizable moulding compositions based on natural rubber and/or synthetic rubber.
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公开(公告)号:LU82715A1
公开(公告)日:1982-05-10
申请号:LU82715
申请日:1980-08-14
Applicant: DEGUSSA
Inventor: GREWATTA HEINZ , WOLFF SIEGFRIED , ROTHBUEHR LOTHAR
IPC: C08K3/00 , C04B20/10 , C08K5/00 , C08K5/5419 , C08K9/06 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08K , C07F
Abstract: The invention relates to a silane/filler preparation, consisting essentially of from 5 to 70% by weight of at least one silane corresponding to the following formula Xp-CmH2m+1-pSiRn1(OR)3-n, I in which X=a halogen atom, preferably chlorine or bromine, p=1 or 2, m=1 to 5, R1=a C1-C5 alkyl group, C5-C8-cycloalkyl group or a phenyl group, R=a C1-C5-alkyl group, a C5-C8-cycloalkyl group, a phenyl group, a benzyl group or a C1-C5-alkoxy-C1-C5-alkyl group, and n=0, 1 or 2, and-respectively balanced to 100%-from 95 to 30% by weight of at lesat one inorganic filler, preferably carbon black and silicate fillers as, e.g., silica. There is also disclosed a process for the production of the silane/filler preparation and its use in optionally cross-linkable polymeric moulding compositions or vulcanizable or cross-linkable rubber moulding compositions such as sulphur-vulcanizable moulding compositions based on natural rubber and/or synthetic rubber.
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公开(公告)号:DD147945A5
公开(公告)日:1981-04-29
申请号:DD21746279
申请日:1979-12-07
Applicant: DEGUSSA
Inventor: SCHWARZ RUDOLF , KLEINSCHMIDT PETER , LIEDTKE CHRISTA , WOLFF SIEGFRIED
IPC: C08L7/00 , C07F7/08 , C07F7/12 , C07F7/18 , C08G75/02 , C08G75/14 , C08K5/5425 , C08K5/548 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L101/00
Abstract: Novel bis-(silylethyl)-oligosulphides are obtained by reacting a vinyl silane of the formula (CH2=CH)m-SiRn1R4-(m+n) in which R represents chlorine, bromine, iodine, C1-C3-alkoxy, 2-methoxyethoxy, 2-ethoxyethoxy or hydroxy, R1 represents C1-C3-alkyl, phenyl or C5-C7-cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m+n is 1, 2 or 3 with sulphur as well as in a given case hydrogen sulphide in molar ratios of vinyl silane to sulphur of from 1:2.5 to 1:10 and vinyl silane to hydrogen sulphide of from 1:0 to 1:5 at temperatures between about 100 DEG and 200 DEG C. under pressure of from 1 to 25 bars (total pressure at the reaction) temperature) and in the presence of sulphidation catalysts known per se, in a given case followed by hydrolysis or partial hydrolysis of the reaction products. The bis-(silylethyl)-oligosulphides are used as reinforcing additives (adhesive agents) in crosslinkable rubber mixtures containing silicate fillers and in a given case carbon black as well as in a given case sulphur and other customary constituents.
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公开(公告)号:CA1099855A
公开(公告)日:1981-04-28
申请号:CA295934
申请日:1978-01-30
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED , ROTHBUHR LOTHAR
IPC: C08L7/00 , C07F7/18 , C08J3/22 , C08K3/04 , C08K5/00 , C08K5/548 , C08L9/00 , C08L21/00 , C09K3/00
Abstract: The present invention provides a granular organosilane preparation composed of a) from 30 to 60% by weight of one or more organo-silanes corresponding to the formula in which R1 represents a monovalent alkyl radical containing from 1 to 3 carbon atoms, R2 represents a monovalent alkyl radical or alkoxy radical containing from 1 to 3 carbon atoms, R represents a divalent alkyl radical containing from 1 to 5 carbon atoms and x represents a value from 2.0 to 6.0, andb) from 70 to 40% by weight of one or more carbon blacks. The preparations have good storage stability, stability against hydrolysis and ease of working into rubber mixtures.
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公开(公告)号:FR2463790A1
公开(公告)日:1981-02-27
申请号:FR8017830
申请日:1980-08-13
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED , TAN EWE-HONG
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公开(公告)号:IT7951193D0
公开(公告)日:1979-12-24
申请号:IT5119379
申请日:1979-12-24
Applicant: DEGUSSA
Inventor: SCHWARZ RUDOLF , KLEINSCHMIT PETER , LIEDTKE CHISTA , WOLFF SIEGFRIED
IPC: C08L7/00 , C07F7/08 , C07F7/12 , C07F7/18 , C08G75/02 , C08G75/14 , C08K5/5425 , C08K5/548 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L101/00 , C07F
Abstract: Novel bis-(silylethyl)-oligosulphides are obtained by reacting a vinyl silane of the formula (CH2=CH)m-SiRn1R4-(m+n) in which R represents chlorine, bromine, iodine, C1-C3-alkoxy, 2-methoxyethoxy, 2-ethoxyethoxy or hydroxy, R1 represents C1-C3-alkyl, phenyl or C5-C7-cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m+n is 1, 2 or 3 with sulphur as well as in a given case hydrogen sulphide in molar ratios of vinyl silane to sulphur of from 1:2.5 to 1:10 and vinyl silane to hydrogen sulphide of from 1:0 to 1:5 at temperatures between about 100 DEG and 200 DEG C. under pressure of from 1 to 25 bars (total pressure at the reaction) temperature) and in the presence of sulphidation catalysts known per se, in a given case followed by hydrolysis or partial hydrolysis of the reaction products. The bis-(silylethyl)-oligosulphides are used as reinforcing additives (adhesive agents) in crosslinkable rubber mixtures containing silicate fillers and in a given case carbon black as well as in a given case sulphur and other customary constituents.
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公开(公告)号:CH612886A5
公开(公告)日:1979-08-31
申请号:CH1327674
申请日:1974-10-02
Applicant: DEGUSSA
Inventor: BURMESTER KURT , KLOETZER ERHARD DR , WOLFF SIEGFRIED , THURN FRIEDRICH DR
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公开(公告)号:CS187428B2
公开(公告)日:1979-01-31
申请号:CS693674
申请日:1974-10-10
Applicant: DEGUSSA , VULKANIZATED RUBBER COMPOSITIO
Inventor: BURMESTER KURT , WOLFF SIEGFRIED , KLOETZER ERHARD , THURN FRIEDRICH
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公开(公告)号:GB2259303B
公开(公告)日:1994-07-20
申请号:GB9217649
申请日:1992-08-19
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED , GORL UDO
IPC: C08J3/24 , C08K5/00 , C08K5/36 , C08K5/39 , C08K5/40 , C08K5/548 , C08K5/58 , C08L21/00 , C08K5/54
Abstract: In a process for the production of vulcanizable moulding compounds consisting of one or more natural or synthetic rubbers or polymers the quantity of accelerators from the class of thiurams and/or dithiocarbamates is reduced to half the quantity originally required through the use of 3-thiocyanatopropyl trialkoxy silanes.
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