SILANE/FILLER PREPARATIONS,A PROCESS FOR THEIR PRODUCTION

    公开(公告)号:IN155261B

    公开(公告)日:1985-01-12

    申请号:IN909CA1980

    申请日:1980-08-08

    Applicant: DEGUSSA

    Abstract: The invention relates to a silane/filler preparation, consisting essentially of from 5 to 70% by weight of at least one silane corresponding to the following formula Xp-CmH2m+1-pSiRn1(OR)3-n, I in which X=a halogen atom, preferably chlorine or bromine, p=1 or 2, m=1 to 5, R1=a C1-C5 alkyl group, C5-C8-cycloalkyl group or a phenyl group, R=a C1-C5-alkyl group, a C5-C8-cycloalkyl group, a phenyl group, a benzyl group or a C1-C5-alkoxy-C1-C5-alkyl group, and n=0, 1 or 2, and-respectively balanced to 100%-from 95 to 30% by weight of at lesat one inorganic filler, preferably carbon black and silicate fillers as, e.g., silica. There is also disclosed a process for the production of the silane/filler preparation and its use in optionally cross-linkable polymeric moulding compositions or vulcanizable or cross-linkable rubber moulding compositions such as sulphur-vulcanizable moulding compositions based on natural rubber and/or synthetic rubber.

    43.
    发明专利
    未知

    公开(公告)号:LU82715A1

    公开(公告)日:1982-05-10

    申请号:LU82715

    申请日:1980-08-14

    Applicant: DEGUSSA

    Abstract: The invention relates to a silane/filler preparation, consisting essentially of from 5 to 70% by weight of at least one silane corresponding to the following formula Xp-CmH2m+1-pSiRn1(OR)3-n, I in which X=a halogen atom, preferably chlorine or bromine, p=1 or 2, m=1 to 5, R1=a C1-C5 alkyl group, C5-C8-cycloalkyl group or a phenyl group, R=a C1-C5-alkyl group, a C5-C8-cycloalkyl group, a phenyl group, a benzyl group or a C1-C5-alkoxy-C1-C5-alkyl group, and n=0, 1 or 2, and-respectively balanced to 100%-from 95 to 30% by weight of at lesat one inorganic filler, preferably carbon black and silicate fillers as, e.g., silica. There is also disclosed a process for the production of the silane/filler preparation and its use in optionally cross-linkable polymeric moulding compositions or vulcanizable or cross-linkable rubber moulding compositions such as sulphur-vulcanizable moulding compositions based on natural rubber and/or synthetic rubber.

    44.
    发明专利
    未知

    公开(公告)号:DD147945A5

    公开(公告)日:1981-04-29

    申请号:DD21746279

    申请日:1979-12-07

    Applicant: DEGUSSA

    Abstract: Novel bis-(silylethyl)-oligosulphides are obtained by reacting a vinyl silane of the formula (CH2=CH)m-SiRn1R4-(m+n) in which R represents chlorine, bromine, iodine, C1-C3-alkoxy, 2-methoxyethoxy, 2-ethoxyethoxy or hydroxy, R1 represents C1-C3-alkyl, phenyl or C5-C7-cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m+n is 1, 2 or 3 with sulphur as well as in a given case hydrogen sulphide in molar ratios of vinyl silane to sulphur of from 1:2.5 to 1:10 and vinyl silane to hydrogen sulphide of from 1:0 to 1:5 at temperatures between about 100 DEG and 200 DEG C. under pressure of from 1 to 25 bars (total pressure at the reaction) temperature) and in the presence of sulphidation catalysts known per se, in a given case followed by hydrolysis or partial hydrolysis of the reaction products. The bis-(silylethyl)-oligosulphides are used as reinforcing additives (adhesive agents) in crosslinkable rubber mixtures containing silicate fillers and in a given case carbon black as well as in a given case sulphur and other customary constituents.

    GRANULAR-LIKE ORGANOSILANE PREPARATION

    公开(公告)号:CA1099855A

    公开(公告)日:1981-04-28

    申请号:CA295934

    申请日:1978-01-30

    Applicant: DEGUSSA

    Abstract: The present invention provides a granular organosilane preparation composed of a) from 30 to 60% by weight of one or more organo-silanes corresponding to the formula in which R1 represents a monovalent alkyl radical containing from 1 to 3 carbon atoms, R2 represents a monovalent alkyl radical or alkoxy radical containing from 1 to 3 carbon atoms, R represents a divalent alkyl radical containing from 1 to 5 carbon atoms and x represents a value from 2.0 to 6.0, andb) from 70 to 40% by weight of one or more carbon blacks. The preparations have good storage stability, stability against hydrolysis and ease of working into rubber mixtures.

    47.
    发明专利
    未知

    公开(公告)号:IT7951193D0

    公开(公告)日:1979-12-24

    申请号:IT5119379

    申请日:1979-12-24

    Applicant: DEGUSSA

    Abstract: Novel bis-(silylethyl)-oligosulphides are obtained by reacting a vinyl silane of the formula (CH2=CH)m-SiRn1R4-(m+n) in which R represents chlorine, bromine, iodine, C1-C3-alkoxy, 2-methoxyethoxy, 2-ethoxyethoxy or hydroxy, R1 represents C1-C3-alkyl, phenyl or C5-C7-cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m+n is 1, 2 or 3 with sulphur as well as in a given case hydrogen sulphide in molar ratios of vinyl silane to sulphur of from 1:2.5 to 1:10 and vinyl silane to hydrogen sulphide of from 1:0 to 1:5 at temperatures between about 100 DEG and 200 DEG C. under pressure of from 1 to 25 bars (total pressure at the reaction) temperature) and in the presence of sulphidation catalysts known per se, in a given case followed by hydrolysis or partial hydrolysis of the reaction products. The bis-(silylethyl)-oligosulphides are used as reinforcing additives (adhesive agents) in crosslinkable rubber mixtures containing silicate fillers and in a given case carbon black as well as in a given case sulphur and other customary constituents.

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