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公开(公告)号:DE3736864A1
公开(公告)日:1989-03-30
申请号:DE3736864
申请日:1987-10-30
Applicant: HOECHST AG
Inventor: SOMMER ANDREAS DR , DIETZ ERWIN DR , URBAN MANFRED DIPL ING
Abstract: The invention relates to readily dispersible pigment preparations, which are stable to flocculation, for pigmenting natural and synthetic materials, preferably paints and printing inks, plastics and surface coatings, in particular stoving enamels. The pigment preparations are characterised by a content of compounds of the general formula (I) in which Q , Q and Q each denote -X-A, -OR , -SR , halogen, -NR R or a radical Q which is composed of up to 15 trivalent groups (Ia) in such a way that one group (Ia) is bonded via W to a free valence of the next group (Ia) or to the triazine ring of (I) and the other free valences are bonded to -X-A, -O-R , halogen or -NR R , at least one radical -X-A being present in (I), and A represents an aromatic system having 2 to 6 rings and at least 9 ring atoms or represents a group of 2 to 3 aromatic ring systems which are bonded via O, S, CO, SO2 or C1- C12-alkylene and each of which consists of 1 to 4 rings, A being optionally substituted by C1-C24-alkyl, OR', halogen, NR'R'', COOR', CONR'R'', NR'COR'', CN, CF3 or NO2, and R' and R'' denoting H or C1- C12-alkyl or, together with N, denoting a heterocyclic structure having 5 or 6 ring atoms, X represents NR , O or S, wherein R denotes H, C1-C6-alkyl, -hydroxyalkyl or -alkoxyalkyl or C5-C7-cycloalkyl, R , R and R each represent H, alkyl, alkenyl, cycloalkyl, aralkyl, heteroalkyl, phenyl, optionally substituted by C1-C12-alkyl, halogen, OR , NR R , COOR , CONR R , NR COR , CN, CF3, NO2 or -T(CH2)pNR R , in which R and R denote H or alkyl and R and R denote alkyl, p denotes 1-6 and T denotes a direct bond or O, S, CO, SO, SO2, NR , NR CO, NR SO2, SO2NR or CONR and R denotes H or C1-C12-alkyl, or represents C1-C12-hydroxyalkyl or -polyhydroxyalkyl or alkyl which is interrupted by one or more O atoms and/or NR groups, in which R denotes H or alkyl, and may be substituted by a 5-membered or 6- membered heterocyclic ring, or R has the above-mentioned meaning and R and R , together with N, represent a 5-membered or 6-membered ring of a heterocyclic system having 1 or 2 rings, W is Y -Y-Y , in which Y is alkylene, optionally interrupted by O, S, NH, N(Alkyl), CO, SO, SO2, C5-C7-cycloalkylene, C5-C10-arylene or heteroarylene having 5-7 ring atoms or a mononuclear to trinuclear carbocyclic or heterocyclic ring system having 5 to 14 ring atoms or two of the ring systems which are bonded via a direct bond or O, S, CO, SO or SO2, and Y denotes O, S or NR , in which R denotes alkyl, hydroxyalkyl, alkoxyalkyl or cycloalkyl or, together with N-Y-N, denotes a heterocyclic ring. The dispersants used can be prepared by reacting cyanuric halides with corresponding compounds H-X-A, HOR , HSR , HNR R and/or HWH.
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公开(公告)号:DE3623297A1
公开(公告)日:1988-01-21
申请号:DE3623297
申请日:1986-07-11
Applicant: HOECHST AG
Inventor: DIETZ ERWIN DR , SOMMER ANDREAS DR , KROH ADOLF , RIEPER WOLFGANG DR , HAFNER OTMAR
IPC: C08G59/32 , C08G59/50 , C09B67/46 , C09C3/08 , C09D17/00 , C09K23/00 , C09K23/52 , C08G59/14 , C08G59/06 , C08L63/04 , B01F17/52
Abstract: Addition compounds which are suitable as dispersants for solids in organic media are obtained from polyepoxides based on novolaks having 3 to 11 rings and a mixture of aliphatic, aromatic and/or heterocyclic amines.
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公开(公告)号:DE3064857D1
公开(公告)日:1983-10-27
申请号:DE3064857
申请日:1980-01-10
Applicant: HOECHST AG
Inventor: DIETZ ERWIN DR , GROSSMANN MAX DR , MAIKOWSKI MICHAEL DR
Abstract: Dispersions containing (a) a pigment, (b) an oxalkylated novolak, (c) urea and/or a compound containing at least 2 long-chain aliphatic groups and which are connected via a bridge member containing ester and/or amide groups, and (d) water and/or agents retarding drying up, and, optionally, usual adjuvants, are useful for pigmenting natural or synthetic materials, especially aqueous systems containing cellulose ethers.
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44.
公开(公告)号:CH638557A5
公开(公告)日:1983-09-30
申请号:CH1321378
申请日:1978-12-28
Applicant: HOECHST AG
Inventor: DIETZ ERWIN DR , GROSSMANN MAX DR , GUTBROD ROBERT , MAIKOWSKI MICHAEL DR
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公开(公告)号:CH630949A5
公开(公告)日:1982-07-15
申请号:CH1458577
申请日:1977-11-29
Applicant: HOECHST AG
Inventor: DIETZ ERWIN DR , MAIKOWSKI MICHAEL DR , GUTBROD ROBERT
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公开(公告)号:DK0492501T3
公开(公告)日:1997-04-07
申请号:DK91121937
申请日:1991-12-20
Applicant: HOECHST AG
Inventor: SCHWAB WOLFGANG DR , DIETZ ERWIN DR , AZ RAINER DR , SCHNAITMANN DIETER DR
IPC: C07D251/34 , C07D251/38 , C07D251/46 , C07D251/52 , C07D251/70 , C07D403/12 , C07D403/14 , C08G73/06 , C09K23/00 , C09K23/32 , C09K23/52 , B01F17/32
Abstract: Polymeric, water-soluble triazine compounds which contain both basic and acidic groups in the molecule have out-standing surfactant properties and are suitable for the preparation of dispersions of solids, preferably of dispersions of inorganic and/or organic pigments, in an aqueous or water-dilutable medium. Since these triazine compounds are colorless or only slightly colored, they do not influence the shade of the medium used.
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公开(公告)号:DE59108367D1
公开(公告)日:1997-01-02
申请号:DE59108367
申请日:1991-12-20
Applicant: HOECHST AG
Inventor: AZ RAINER DR , SCHWAB WOLFGANG DR , SCHNAITMANN DIETER DR , DIETZ ERWIN DR
IPC: C07D251/34 , C07D251/38 , C07D251/46 , C07D251/52 , C07D251/70 , C07D403/12 , C07D403/14 , C08G73/06 , C09K23/00 , C09K23/32 , C09K23/52 , B01F17/32
Abstract: Polymeric, water-soluble triazine compounds which contain both basic and acidic groups in the molecule have out-standing surfactant properties and are suitable for the preparation of dispersions of solids, preferably of dispersions of inorganic and/or organic pigments, in an aqueous or water-dilutable medium. Since these triazine compounds are colorless or only slightly colored, they do not influence the shade of the medium used.
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公开(公告)号:ES2093670T3
公开(公告)日:1997-01-01
申请号:ES91120839
申请日:1991-12-04
Applicant: HOECHST AG
Inventor: SCHWAB WOLFGANG DR , DIETZ ERWIN DR
Abstract: Pigment preparations whose pigment portion is composed essentially of organic pigments and of pigment additives of the formula I (I) in which P is a radical of an organic pigment and X in the methylene groups of the lactam ring is hydrogen, C1-C4-alkyl, phenyl, hydroxyl, NR1R2 or COOM, m is an integer from 3 to 20 and n can have a value from 0.1 to 4, are suitable for pigmenting high-molecular-weight organic materials in solvent-borne as well as aqueous systems. The pigment preparations have high flocculation stability and good rheological properties.
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公开(公告)号:DE59207080D1
公开(公告)日:1996-10-17
申请号:DE59207080
申请日:1992-03-20
Applicant: HOECHST AG
Inventor: DIETZ ERWIN DR , URBAN MANFRED
Abstract: In the conventional dry grinding of C.I. Pigment Violet 23, the environment is greatly polluted by the inevitably produced dusts, the generation of noise and heavy vibrations during the grinding process. According to the invention, it has now been found that this deficiency can be avoided if the base pigment is finely dispersed by aqueous-alcoholic bead grinding in the presence of selected pigment dispersing agents, derived from dioxazine compounds containing basic groups, together with a subsequent solvent finish. As a result of such a combination of the two aforementioned treatment processes, an increase in capacity is possible even without otherwise expensive investments for mechanical measures. The pigment preparations produced in this manner simultaneously result in an improvement of the application properties of the colorant in the coating and especially in nitrocellulose intaglio printing, in particular an improvement of the gloss and decrease in the abrasiveness compared with the trade names known in this field.
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公开(公告)号:DE58908176D1
公开(公告)日:1994-09-15
申请号:DE58908176
申请日:1989-09-28
Applicant: HOECHST AG
Inventor: DIETZ ERWIN DR , KROH ADOLF
Abstract: A process for the manufacture of 2,9-dimethylquinacridone pigments or mixed crystal pigments or mixtures of 2,9-dimethylquinacridone and quinacridones which can be substituted in the outer fused benzene nuclei by halogen, alkyl, alkoxy, H2N-CO-, alkyl-NH-CO- or (alkyl)2N-CO- groups, which are characterised by the shape of their crystalline particles with a mean ratio of length to width of in an amount of 1 to 20% by weight, where in formula (I) Q is a quinacridone radical which is unsubstituted or substituted by halogen, alkyl, alkoxy, H2N-CO-, alkyl-NH-CO- or (alkyl)2N-CO- groups, A is a direct bond or -O-, -S-, -NR -, -CO-, -SO2-, -CR R - or arylene, and Y is an -NR R group or the radical of a five-, six- or seven-membered heterocycle which contains 1 to 3 hetero atoms and which can be substituted by alkyl, alkoxy, hydroxyphenyl, halogen, -CN, carboxyl, CO-NNR', -SO2-NRR', hydroxyalkyl or alkylaminoalkyl, R and R' are hydrogen or alkyl, and R to R are, hydrogen and/or alkyl- or alkylene and n is 1 to 4, the pigments prepared in this way themselves and the use thereof for pigmenting natural or synthetic materials and coating systems.
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