公开(公告)号：AU731668B2

公开(公告)日：2001-04-05

申请号：AU2369597

申请日：1997-05-29

Applicant: HOECHST AG

Inventor： FRITZE CORNELIA ,  KUBER FRANK ,  BOHNEN HANS

IPC: B01J31/22 ,  C07F3/00 ,  C07F5/02 ,  C07F7/02 ,  C07F7/08 ,  C07F7/22 ,  C07F7/30 ,  C07F9/28 ,  C07F9/50 ,  C07F17/00 ,  C08F4/00 ,  C08F4/42 ,  C08F4/602 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/64 ,  C08F4/643 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C07F9/6596 ,  C08F4/12

Abstract: The present invention relates to a catalyst system containing (a) at least one compound of the formula (II):where R are each a halogen or a C1-40 group; X are each a C1-40 haloalkylene, C6-40 arylene, C6-40 haloarylene, C7-40 arylalkylene, C7-40 haloarylalkylene, C2-40 alkynylene, a haloalkynylene group containing up to 40 carbon atoms, C2-40 alkenylene, or C2-40 haloalkenylene group; M are each an element of group IIa, IIIa, IVa, or Va of the Periodic Table of the elements; A is a cation of group Ia, IIa, IIIa of the Periodic Table of the Elements; a, b, or c is an interger from 0 to 10 and if a=0 then b=0; if a>=1 then a=b.c; d, f, or g is 0 or 1 and when d=0, g is 0; j is an integer from 1 to 5 and (b) at least one metallocene.

公开(公告)号：AU718870B2

公开(公告)日：2000-04-20

申请号：AU5080796

申请日：1996-04-22

Applicant: HOECHST AG

Inventor： AULBACH MICHAEL ,  BREKNER MICHAEL-JOACHIM ,  KUBER FRANK ,  ZENK ROLAND

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/64 ,  C08F4/642 ,  C08F4/68 ,  C08F4/69 ,  C08F10/00 ,  C08F4/76 ,  C08F4/78 ,  C08F4/643

Abstract: Metallocene cpds. of formula (I) with at least two different metallocene fragments L-MX2-L are new: (I) B = bridging unit; m = 2-100,000; M = Gp. IVb, Vb or VIb metal; X = H, 1-40C hydrocarbon-contg. gp., OH, halogen or pseudohalogen L = a pi-ligand or other electron donor. Also claimed is (i) a catalyst component contg. cpd(s). (I) and cocatalyst(s); (ii) a process for the prodn. of olefin polymers by polymerisation of olefin(s) in presence of a catalyst as in (i); (iii) polyolefins obtd. by this process.

公开(公告)号：NO965106D0

公开(公告)日：1996-11-29

申请号：NO965106

申请日：1996-11-29

Applicant: HOECHST AG

Inventor： WINTER ANDREAS ,  KUBER FRANK ,  BACHMANN BERND

IPC: A23L3/00 ,  C08F4/60 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/62 ,  C08F4/622 ,  C08F4/642 ,  C08F4/645 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/06 ,  C08F210/00 ,  C08F210/06 ,  C08F210/16 ,  C08F216/00 ,  C08F216/06 ,  C08J5/18 ,  C08F

Abstract: Copolymer comprises propylene units and a comonomer of ethylene or at least 4C olefin. Copolymer comprises 30-99.5 wt.% propylene units and 0.5-70 wt.% comonomer of ethylene or at least 4C olefin of formula (I): RaCH=CHRb (I) Ra and Rb = H or 1-15C alkyl or form a 4-12C ring with the C atom. An Independent claim is included for a polymer mixture containing at least one such copolymer.

公开(公告)号：NO955306L

公开(公告)日：1996-07-01

申请号：NO955306

申请日：1995-12-27

Applicant: HOECHST AG

Inventor： AULBACH MICHAEL ,  FRITZE CORNELIA ,  HERRMANN HANS-FRIEDRICH ,  KUBER FRANK ,  SPALECK WALTER ,  ZENK ROLAND

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/62 ,  C08F4/622 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C07F7/00

Abstract: Polynuclear metallocene cpds. of formula L X2-L )-ÄB(L -M X2-L )Ük-B-L X2-L ) (I) are new: M = tetravalent metal; L -L = -ligands; B = divalent bridging unit; X = H, halogen, 1-10 C fluorocarbyl or 1-40 C hydrocarbyl; and k = 0-10. Also claimed are (i) catalyst components contg. (a) cpd(s) of formula (I) and (b) cocatalysts(s), and (ii) a process for the prodn. of olefin polymers by polymerisation of olefin(s) in presence of the above catalyst combination.

公开(公告)号：NO962760D0

公开(公告)日：1996-06-28

申请号：NO962760

申请日：1996-06-28

Applicant: HOECHST AG

Inventor： KUBER FRANK ,  RIEDEL MICHAEL

IPC: C07B61/00 ,  B01J31/26 ,  C07C2/86 ,  C07C13/28 ,  C07C13/32 ,  C07C13/465 ,  C07F17/00 ,  C07C

Abstract: Prodn. of carbon-bridged biscyclopentadiene cpd. comprises reacting one or two cyclopentadiene cpds. (LH), at least one being a substd. cyclopentadiene, with a carbonyl cpd. in the presence of a base and a phase transfer catalyst. Also claimed is the prodn. of a phase transfer catalyst. Also claimed is the prodn. of a carbon-bridged biscyclopentadienyl-metallocene.

公开(公告)号：NO955306D0

公开(公告)日：1995-12-27

申请号：NO955306

申请日：1995-12-27

Applicant: HOECHST AG

Inventor： AULBACH MICHAEL ,  FRITZE CORNELIA ,  HERRMANN HANS-FRIEDRICH ,  KUBER FRANK ,  SPALECK WALTER ,  ZENK ROLAND

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/62 ,  C08F4/622 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C07F

Abstract: Polynuclear metallocene cpds. of formula L X2-L )-ÄB(L -M X2-L )Ük-B-L X2-L ) (I) are new: M = tetravalent metal; L -L = -ligands; B = divalent bridging unit; X = H, halogen, 1-10 C fluorocarbyl or 1-40 C hydrocarbyl; and k = 0-10. Also claimed are (i) catalyst components contg. (a) cpd(s) of formula (I) and (b) cocatalysts(s), and (ii) a process for the prodn. of olefin polymers by polymerisation of olefin(s) in presence of the above catalyst combination.

公开(公告)号：AU661587B2

公开(公告)日：1995-07-27

申请号：AU4149193

申请日：1993-06-25

Applicant: HOECHST AG

Inventor： KUBER FRANK ,  BACHMANN BERND ,  SPALECK WALTER ,  WINTER ANDREAS ,  ROHRMANN JURGEN

IPC: C07F7/00 ,  B01J31/22 ,  B01J31/26 ,  B01J31/38 ,  C07C13/465 ,  C07C17/14 ,  C07C45/46 ,  C07C49/563 ,  C07C49/67 ,  C07F17/00 ,  C08F4/16 ,  C08F4/42 ,  C08F4/44 ,  C08F4/60 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/642 ,  C08F4/6592 ,  C08F4/76 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  C08F297/08 ,  C08F4/69 ,  C08F4/68 ,  C08F4/646

Abstract: Catalysts consisting of a metallocene of formula (I) and a cocatalyst are claimed, M = a Group IVb, Vb or VIb metal; R , R = H, 1-10C alkyl or alkoxy, 6-10C aryl or aryloxy, 2-10C alkenyl, 7-40C aralkyl or alkaryl, 8-40C aralkenyl, OH or halogen; R = H, halogen, optionally halogenated 1-10C alkyl, 6-10C aryl, N(R )2, SR , OSi(R )3, Si(R )3 or P(R )2 (with R = halogen, 1-10C alkyl or 6-10C aryl); R -R = as for R , or adjacent groups may form part of one or more aromatic or aliphatic rings, or the groups R and R or R may form such rings with the attached atoms; R = -X-, -X-X-, -Y-Y-, -O-X-O- -Y-, -O-X-, -Y-X-, -Y-Y-Y-, =BR , =AlR , -O-, -S-, =SO, =SO2, =NR , =CO, =PR or =P(O)R ; X = -M R R -; Y = -CR R ; R , R = H, halogen, 1-10C alkyl, fluoroalkyl or alkoxy, 6-10C aryl, fluoroaryl or aryloxy, 2-10C alkenyl, 7-40C aralkyl or alkaryl, or 8-40C aralkenyl, or R + R + the attached atoms may form ring(s); M = silicon, germanium or tin. Also claimed are: (i) polyolefins obtained by (co)polymerisation of olefins of formula Ra-CH=CH-Rb (with Ra, Rb = H or 1-14C hydrocarbyl, or Ra + Rb may form part of one or more rings) at -60 to 200 degrees C and 0.5-100 bar in solution, suspension or gas phase, in presence of these catalysts; (ii) a process for the production of metallocenes (I); and (iii) intermediate indanones, indenes and bridged ligand systems formed in this process.

公开(公告)号：NO952307D0

公开(公告)日：1995-06-12

申请号：NO952307

申请日：1995-06-12

Applicant: HOECHST AG

Inventor： ERKER GERHARD ,  TEMME BODO ,  AULBACH MICHAEL ,  BACHMANN BERND ,  KUBER FRANK

IPC: C07F17/00 ,  C07F7/08 ,  C08F4/44 ,  C08F4/60 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/62 ,  C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  C07F

Abstract: The present invention relates to zwitterionic neutral transition metal compounds. The compounds are suitable as catalyst components for the polymerization of olefins.

公开(公告)号：AU657616B2

公开(公告)日：1995-03-16

申请号：AU3820693

申请日：1993-04-27

Applicant: HOECHST AG

Inventor： WEISSE LAURENT ,  ROHRMANN JURGEN ,  KUBER FRANK ,  STRUTZ HEINZ

IPC: C07F7/08 ,  C07C45/45 ,  C07C45/46 ,  C07C49/617 ,  C07C49/665 ,  C07C49/67 ,  C07C49/675 ,  C07C49/753 ,  C07C49/755 ,  C07J1/00 ,  C07J11/00 ,  C07C45/68