公开(公告)号：JPH11148098A

公开(公告)日：1999-06-02

申请号：JP31364897

申请日：1997-11-14

Applicant: KAO CORP

Inventor： YAMAZAKI YOSHIHIRO ,  OKANO TETSUYA ,  MORIYAMA TADASHI ,  MATSUO NOBORU ,  HIOKI YUICHI

IPC: C11D10/02 ,  A01N25/12 ,  A01N25/30 ,  A01N43/64 ,  A01N59/08 ,  C11D17/00

Abstract: PROBLEM TO BE SOLVED: To obtain the subject detergent suitable for simply and surely sterilizing and cleaning a hard body such as a floor, capable of exhibiting stable and high sterilizing power and cleaning power, by making a chlorine-based sterilizer, a surfactant and a solid acid into a solid preparation. SOLUTION: This solid sterilizing detergent for a hard body has pH2-12 at 1 wt.% of an aqueous solution and comprises (A) 0.1-80 wt.% of a chlorine- based sterilizer such as dichloroisocyanuric acid, etc., (B) 0.1-80 wt.% of a solid acid such as fumaric acid, etc., (C) 0.01-80 wt.% of a surfactant, and, if necessary, (D) 0.1-80 wt.% of a foaming agent, (E) a pH adjuster, (F) 0.1-20 wt.% calculated as the amount of F1 of a mixture of (F1 ) 1 mol of a cationic sterilizer and (F2 )>=0.5 mol of a chelating agent and (G) 0.1-50 wt.% of an inorganic peroxide.

公开(公告)号：JPH11148097A

公开(公告)日：1999-06-02

申请号：JP31364797

申请日：1997-11-14

Applicant: KAO CORP

Inventor： YAMAZAKI YOSHIHIRO ,  OKANO TETSUYA ,  MORIYAMA TADASHI ,  ITOU SUMITOSHI ,  HIOKI YUICHI

IPC: C11D10/02 ,  A01N25/12 ,  A01N25/30 ,  A01N59/08 ,  C11D17/00

Abstract: PROBLEM TO BE SOLVED: To obtain the subject detergent suitable for use in cooking facilities on a large scale, capable of exhibiting excellent storage stability, handleability, safety, bactericidal properties and cleanability, by making a chlorine-based sterilizer, a surfactant and a solid acid into a solid preparation. SOLUTION: This solid sterilizing detergent for perishable foods has pH 2-12 at 1 wt.% aqueous solution and comprises (A) 0.1-80 wt.% of a chlorine- based sterilizer such as (higher) bleaching powder, sodium chlorite, etc., (B) 0.1-80 wt.% of a solid acid such as fumaric acid, succinic acid, etc., (C) 0.01-80 wt.% of a surfactant such as sodium oleate, a sorbitan fatty acid ester, etc., and, if required, (D) 0.1-80 wt.% of a foaming agent, (E) a pH adjuster and (F) 1-50 wt.% of an inorganic peroxide.

公开(公告)号：JPH10324624A

公开(公告)日：1998-12-08

申请号：JP13369597

申请日：1997-05-23

Applicant: KAO CORP

Inventor： MORIYAMA TADASHI ,  HIOKI YUICHI ,  SAWAI MINORU

IPC: A61K9/08 ,  A61K31/045 ,  A61K31/14

Abstract: PROBLEM TO BE SOLVED: To obtain the subject composition useful as a bactericidal disinfectant capable of suppressing skin drying (hand roughening) by mixing a lower alcohol using as a major component, a cationic bactericide, an amphipathic amide derivative and water. SOLUTION: This composition is prepared by mixing 30-95 wt.%, preferably 70-80 wt.%, of a lower alcohol (e.g. ethanol), 0.01-3.0 wt.%, preferably 0.05-0.3 wt.%, of a cationic bactericide (e.g. benzalkonium chloride bearing 8-18 C), 0.01-5.0 wt.%, preferably 0.1-1.0 wt.% of an amphipathic amide derivative a compound of the formula [R and R are each a 1-40 C (hydroxylated) hydrocarbon; R is an 1-6 C alkylene or single bond; R is H, an l-12 C alkoxy, etc., however, R is H when R is single bond]} and a water residual part.

公开(公告)号：JPH07133494A

公开(公告)日：1995-05-23

申请号：JP27824393

申请日：1993-11-08

Applicant: KAO CORP

Inventor： IKEDA CHIKAKO ,  KOBAYASHI TAKATOSHI ,  HIOKI YUICHI ,  MORIYAMA TADASHI

IPC: A61K8/00 ,  A61K8/34 ,  A61K8/37 ,  A61K8/39 ,  A61K8/40 ,  A61K8/41 ,  A61K8/42 ,  A61K8/44 ,  A61Q5/02 ,  A61Q19/10 ,  C11D1/94 ,  A61K7/075 ,  A61K7/50

Abstract: PURPOSE:To obtain a detergent composition, containing a phosphoric acid ester- based surfactant, an ether type acetic acid-based surfactant, an amphoteric surfactant and a lower alcohol, excellent in detergency, low irritancy and touch in hard water, stable at low temperature and useful for the skin, hair, etc. CONSTITUTION:This detergent composition is obtained by blending (A) a phosphoric acid ester-based surfactant which is a compound expressed by the formula I (R is an 8-18C alkyl or alkenyl; X and X are each H or an alkali metal; (1) is 0-10) or a mixture thereof with a compound expressed by the formula II (R R are each the same kind as that of R ; X is the same kind as that of X ; (m) and (n) are each 0-10) at (100/0) to (70/30) content weight ratio of the components expressed by the formulas I/II with (B) an ether type acetic acid-based surfactant expressed by the formula III (R is an 8-18C alkyl or alkenyl; Z is O or CONH; X' is H, an alkali metal, etc.; (p) is 3-15), (C) an amphoteric surfactant expressed by the formula IV [A is R CO2 (R is single bond, a 1-3C alkylene, etc.), etc., B and B are each a 1-3C alkyl, etc.; R is O, CONH, etc.] or the formula V (A' is R CO2H; B is the same kind as that of B ) and (D) a

公开(公告)号：JPH0789828A

公开(公告)日：1995-04-04

申请号：JP23816093

申请日：1993-09-24

Applicant: KAO CORP

Inventor： MORIYAMA TADASHI ,  HIOKI YUICHI ,  IKEDA CHIKAKO ,  OKAMOTO SHIYURI

IPC: A61K8/00 ,  A61Q5/12 ,  C11D17/00 ,  A61K7/08

Abstract: PURPOSE:To obtain a rinsing agent composition free from the lowering of cationic surfactant activity even in the coexistence of a material having an anionic charge and capable of sufficiently exhibiting the characteristic function. CONSTITUTION:A rinsing agent composition contains (A) a cationic surfactant, optionally a quaternary ammonium salt of formula I or II [at least one of R to R and at least one of R and R are alkyl or alkenyl which may be replaced with alkoxyl, alkenyloxy, alkanoylamino, alkenoylamino, alkanoyloxy or alkenoyloxy having the total carbon number of 8-28 and the rests are benzyl, 1-5C alkyl, l-5C hydroxyalkyl or (R O)mH (R is 2-3C alkylene; (m)=1-20)] and (B) >=0.5 time mole (based on the component A), especially 1-2 times mole of chelate, e.g. ethylenediaminetetraacetic acid, citric acid or tripolyphosphoric acid. The compounding ratio of the component A is 0.5-20wt.%, preferably 1-10wt.%.

公开(公告)号：JPH0753995A

公开(公告)日：1995-02-28

申请号：JP20507693

申请日：1993-08-19

Applicant: KAO CORP

Inventor： MORIYAMA TADASHI ,  HIOKI YUICHI ,  TAMURA TATSUNORI ,  IKEDA CHIKAKO ,  OKAMOTO SHIYURI

IPC: C11D3/48 ,  C11D1/04 ,  C11D1/72 ,  C11D1/86 ,  C11D1/94 ,  C11D3/30

Abstract: PURPOSE:To obtain the composition not suffering from a decrease in the activity of the constituent cationic sterilizer even in the presence of a negatively charged substance and excelling in detergency by mixing a cationic sterilizer with a metal chelating agent and a nonionic surfactant and/or an amphoteric surfactant. CONSTITUTION:The composition comprises a cationic sterilizer (a), a metal chelating agent (b) in an amount 0.5 time by moles that of component (a) and a nonionic surfactant and/or an amphoteric surfactant (c). Component (a) is used in an amount of desirably 0.5-5wt.% based on the total composition, and component (c) is used in an amount of desirably 5-50wt.% based on the total composition. Desirable examples of component (b) used include ethylenediaminetetraacetic acid, hydroxyethyethylenediaminetriacetic acid and citric acid. Desirable examples of component (c) used include alkylpolyglycoside and alkyldimethylamino fatty acid betaine.

公开(公告)号：JPH06305920A

公开(公告)日：1994-11-01

申请号：JP10295793

申请日：1993-04-28

Applicant: KAO CORP

Inventor： MORIYAMA TADASHI ,  HIOKI YUICHI

IPC: A01N25/22 ,  A01N37/16 ,  A01N59/00 ,  A01N59/14

Abstract: PURPOSE:To provide a fungicide composition having high fungicidal effect, long durability and excellent storage stability and usable in a wide field from industrial use to domestic use. CONSTITUTION:The fungicide composition contains (A) 1 pt.wt. of an inorganic peroxide such as sodium percarbonate, sodium perborate and sodium peroxytripolyphosphate, (B) 0.01-10 pts.wt. of an organic acid incomplete ester of a polyhydric alcohol as an activation agent for the component A, e.g. 1-8C fatty acid incomplete ester of glycerols and/or sugars and (C) 0.01-90 pts.wt. of an alkaline earth metal salt necessary for the stabilization of the produced peracid. The amount of the component C is especially 0.1-20 pts.wt. based on the component B. The composition is produced in the form of a solid such as powder, granule and tablet by conventional method, diluted with water in use and applied preferably at an inorganic peroxide concentration of 25-1,000ppm.

公开(公告)号：JPH05284984A

公开(公告)日：1993-11-02

申请号：JP9072392

申请日：1992-04-10

Applicant: KAO CORP

Inventor： MASANAKA MASAFUMI ,  HIOKI YUICHI ,  MORIYAMA TADASHI

IPC: C12P13/04 ,  C12P13/08 ,  C12R1/01 ,  C12R1/06 ,  C12R1/07 ,  C12R1/125 ,  C12R1/13 ,  C12R1/15

Abstract: PURPOSE:To efficiently produce a large amount of an L-amino acid such as L-glutamic acid, L-lysine or L-glutamine by culturing a bacterium capable of producing an L-amino acid in a medium containing a specific polyglycerol and collecting the L-amino acid from the culture mixture. CONSTITUTION:Glycerol is condensed through dehydration in the presence of an alkali preferably at 200-300 deg.C to prepare a polyglycerol, an alkylene oxide is added to the polyglycerol in the presence of an alkali catalyst under pressure by heating to give an adduct of the polyglycerol with a polyoxyalkylene of the formula (n is 2-50; R to R are H or 2-31C acyl; X is 2-4C alkylene; m1, m2 and m3 are 0-200). Then this compound is added to a medium containing a carbon source, a nitrogen source, a salt, etc., a bacterium (e.g. Corynebacterium glutamicum) capable of producing an L-amino acid is inoculated into the medium, cultured at 30 deg.C for 18 hours and a product is collected from the culture solution by ion exchange resin treatment to efficiently produce a large amount of the L-amino acid.

公开(公告)号：JPH04316504A

公开(公告)日：1992-11-06

申请号：JP8528191

申请日：1991-04-17

Applicant: KAO CORP

Inventor： IWASAKI TETSUHARU ,  MORIYAMA TADASHI ,  HIOKI YUICHI

IPC: A01N33/12 ,  A01N37/02 ,  A01N41/04

Abstract: PURPOSE:To provide an agricultural or horticultural biocide potency-increasing agent containing as an essential ingredient a specific compound in which a specified substituent is introduced into a quaternary ammonium salt group exhibiting the biocide potency-increasing effect, reduced in the chemical damages of useful plants and crops without deteriorating the above-mentioned effect, and permitting to produce preparations containing the ingredient in high concentrations. CONSTITUTION:An agricultural or horticultural biocide potency-increasing agent contains as an essential ingredient a compound of formula I [R1 is 20-40C straight chain or branched chain alkyl, alkenyl, alkylarylpolyalkylene, alkylpolyoxyethylene, alkylpolyoxypropylene, acylaminoalkyl, acyloxyalkyl; R2, R3 are group of formula II of III, 1-4C alkyl, 2-4C hydroxyalkyl; R4 is the respective 12-30C groups of R1; X is a counter ion such as halide ion, or phosphate ester, sulfate ester or carboxylate ion which has a

公开(公告)号：JP2001072997A

公开(公告)日：2001-03-21

申请号：JP2000197986

申请日：2000-06-30

Applicant: KAO CORP

Inventor： OKAUCHI YUJI ,  MORIYAMA TADASHI ,  HIRAMATSU HIROYOSHI ,  HIOKI YUICHI

IPC: A61L2/18 ,  A01N25/30 ,  A01N37/18 ,  A01N59/00 ,  A01N63/00 ,  C11D3/48 ,  C11D7/10 ,  C11D7/18 ,  C11D7/32 ,  C11D7/42 ,  C11D7/60

Abstract: PROBLEM TO BE SOLVED: To obtain a bactericidal detergent composition which provides sure bactericidal effects by a simple treatment and is excellent in safeness and workability by incorporating an inorganic peroxide, tetraacetylethylenediamine, and protease into the same. SOLUTION: An inorganic peroxide (A), tetraacetylethylenediamine (B), and protease (C) are compounded in a wt. ratio of A/B of (10/1)-(1/2). Ingredient C is compounded preferably in such an amount that the activity in use is 20 APU/L to 10 mAPU/L. Preferably, the composition further contains at least one surfactant (D) selected from among nonionic, anionic, cationic, and ampholytic surfactants and an alkali (alkaline earth metal) salt of an inorganic acid (E). Preferably, ingredients D and E are compounded in such amounts that the wt. ratio of B/D is (20/1)-(2/1) and that of A/E is (1/1)-(4/1).