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    41.
    发明专利
    未知

    公开(公告)号：NO862524D0

    公开(公告)日：1986-06-23

    申请号：NO862524

    申请日：1986-06-23

    Applicant: STANDARD OIL CO OHIO

    Inventor： HARRIS JONATHAN H ,  TENHOVER MICHAEL A ,  GRASSELLI ROBERT K

    IPC: C25B11/10 ,  C22C45/00 ,  C25B11/04 ,  C25B11/08 ,  C25B11/00

    Abstract: Novel rhodium based amorphous metal alloys having the formula RhrAa where: A is B, P, As and mixtures thereof; r is from about 50 to 96 percent; and a is from about 4 to 50 percent. Novel rhodium based amorphous metal alloys are also based on the formula RhrBbDd where: D is Ir, Pd, Ru, Ti, Zr, Nb, Ta, Y, Hf and mixtures thereof; r is from about 50 to 96 percent; b is from about 4 to 50 percent; and d is from about 0 to 60 percent; and r + b + d = 100. Novel process for the generation of halogens from halide-containing solutions can be performed by employing the rhodium based metal alloys of the present invention.

    IMPROVED AMORPHOUS METAL ALLOY MATERIALS FOR REVERSIBLE HYDROGEN STORAGE
    42.
    发明专利
    IMPROVED AMORPHOUS METAL ALLOY MATERIALS FOR REVERSIBLE HYDROGEN STORAGE 未知

    公开(公告)号：PT82287A

    公开(公告)日：1986-04-01

    申请号：PT8228786

    申请日：1986-03-26

    Applicant: STANDARD OIL CO OHIO

    Inventor： GRASSELLI ROBERT K ,  TENHOVER MICHAEL A ,  HARRIS JONATHAN H

    IPC: B22F9/00 ,  C22C38/00 ,  C01B3/00 ,  C22C5/00 ,  C22C14/00 ,  C22C19/00 ,  C22C45/02 ,  C22C45/10 ,  C22C1/00

    Abstract: @ Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formula A a M b M' c wherein A is at least one metal selected from the group consisting of Ag, Au, Hg, Pd, and Pt;M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co, Fe, Zn, Cd, Ga and Mn; andM' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; andwherein a ranges from greater than zero to about 0.80;b ranges from zero to about 0.70; andc ranges from about 0.08 to about 0.95; characterized in that 1) a substantial portion of A is disposed on the surface of said material and/or 2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with. a bulk storage material comprising a reversible hydrogen storage material.

    CATALYST FOR PREPARATION OF MALEIC ANHYDRIDE FROM FOUR-CARBON HYDROCARBONS
    49.
    发明专利
    CATALYST FOR PREPARATION OF MALEIC ANHYDRIDE FROM FOUR-CARBON HYDROCARBONS 未知

    公开(公告)号：CA1122958A

    公开(公告)日：1982-05-04

    申请号：CA352925

    申请日：1980-05-28

    Applicant: STANDARD OIL CO OHIO

    Inventor： SURESH DEV D ,  BREMER NOEL J ,  GRASSELLI ROBERT K

    IPC: B01J21/00 ,  B01J23/00

    Abstract: (4856) PREPARATION OF MALEIC ANHYDRIDE FROM FOUR CARBON HYDROCARBONS Catalyst comprising the combined oxides of vanadium and at least one element selected from the group consisting of boron, niobium, tantalum, antimony, tungsten and chromium have been found to be especially effective in the oxidation of n-butane, n-butenes and butadiene, or a mixture thereof with molecular oxygen in the vapor phase to yield maleic anhydride. The catalysts of the present invention may be further promoted with additional elements to enhance activity, stability and selectivity. The reaction with n-butane gives an especially pure product in good yield and selectivity.

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