-
公开(公告)号:JPH03294332A
公开(公告)日:1991-12-25
申请号:JP9656590
申请日:1990-04-13
Applicant: UBE INDUSTRIES
Inventor: ISHIKAWA SEIJI , JIBIKI HIROSHI , KADOMA KIMITOSHI
Abstract: PURPOSE:To obtain the subject thermoplastic compound having faint color and excellent heat-resistance and mechanical strength by heating and stirring a dihalogenodiphenylsulfone and a dihydric phenolic compound in a specific polar organic solvent in the presence of an alkali metal compound. CONSTITUTION:The objective compound can be produced by heating and stirring (A) a dihalogenodiphenylsulfone (e.g. 4,4'-dichlorodiphenylsulfone) and (B) a dihydric phenolic compound (e.g. hydroquinone) in a polar organic solvent consisting of a 2-imidazolidinone derivative of formula (R and R are methyl or ethyl) (preferably 1,3-dimethyl-2-imidazolidine) in the presence of an alkali metal compound (preferably sodium carbonate or potassium carbonate).
-
公开(公告)号:JPS54106621A
公开(公告)日:1979-08-21
申请号:JP28278
申请日:1978-01-06
Applicant: UBE INDUSTRIES
Inventor: KANEDA TAKAHO , ISHIKAWA SEIJI , DAIMON HIROSHI , KATSURA TOSHIO , HONDOU TADAHIRO , UEDA MASAHIRO
Abstract: PURPOSE:Copolyamide fibers that are composed of specific structures as recurring units and useful for industrial fibers as reinforcing materials for rubber products, ropes, filter cloths, a variety of covering cloths and others because of their high initial modulus, tensile strength, knot strength and heat resistance. CONSTITUTION:Said copolyamide fibers are substantially composed of rccurring units of structures shown by formula I, II and III wherein the units of formula I and II is substantialy equimolar with the unit of formula III and the molar ratio of the unit of formula I to that of formula II is 10/90-50/50. A copolyamide with an inherent viscosity of over 2.0, preferably over 3.0 dl/g measured with 0.5g/dl solution in 95-98% sulfuric acid at 30 deg.C is wet spun using conc, or fuming sulfuric acid as a solvent and water as a coagulant, forming fibers with initial modulus over 400g/d and tensile strength over 16g/d.
-
公开(公告)号:JPS5398416A
公开(公告)日:1978-08-28
申请号:JP1206677
申请日:1977-02-08
Applicant: UBE INDUSTRIES
Inventor: KANEDA TAKAHO , ISHIKAWA SEIJI , DAIMON HIROSHI , KATSURA TOSHIO , MAEDA TACHIAKI , HONDOU TADAHIRO
IPC: D01F6/80
Abstract: PURPOSE:Copolyamide fibers of specific structure unit with high initial modulus and tensile strength.
-
公开(公告)号:JPS5318696A
公开(公告)日:1978-02-21
申请号:JP9237676
申请日:1976-08-04
Applicant: UBE INDUSTRIES
Inventor: KANEDA AKIHO , ISHIKAWA SEIJI , DAIMON HIROSHI , KATSURA TOSHIO , MAEDA TACHIAKI , MOTOFUJI TADAHIRO
Abstract: PURPOSE:The title novel polyamide usable for coating compounds, adhesives, etc., readily soluble in organic soluble in organic solvents, sulfuric acid, etc., capable of being easily molded into films, fibers, etc., consisting of specific recurring structural units.
-
公开(公告)号:JPS5312988A
公开(公告)日:1978-02-06
申请号:JP8714076
申请日:1976-07-23
Applicant: UBE INDUSTRIES
Inventor: KANEDA AKIHO , ISHIKAWA SEIJI , DAIMON HIROSHI , MAEDA TACHIAKI , KATSURA TOSHIO , MOTOFUJI TADAHIRO
IPC: C08G69/00 , C07D307/91 , C08G69/32 , D01F6/80
Abstract: PURPOSE:A novel aromatic copolymaide having extremely high heat resistance and elasticity, consisting of specific structural units and three kinds of recurring units.
-
公开(公告)号:JPS5178812A
公开(公告)日:1976-07-09
申请号:JP14924574
申请日:1974-12-28
Applicant: UBE INDUSTRIES
Inventor: KANEDA AKIHO , ISHIKAWA SEIJI , KATSURA TOSHIO , MORIMOTO NOBUHIKO , MAEDA TACHIAKI , SEKYAMA TATSUO
-
公开(公告)号:JP2000154250A
公开(公告)日:2000-06-06
申请号:JP33168798
申请日:1998-11-20
Applicant: UBE INDUSTRIES
Inventor: ISHIKAWA SEIJI , YAMAMOTO SHIGERU
Abstract: PROBLEM TO BE SOLVED: To obtain a polyimide resin which is soluble in organic solvents and desirably applied to an underfill process where the circuit board on which semiconductor chips have been mounted is a polyimide substrate by selecting a polyimide resin containing a specified proportion of a polyimidosiloxane component. SOLUTION: The polyimide resin used comprises 40-80 mol% polyimidosiloxane component of formula I, 5-50 mol% polyimide component of formula II, and the balance of a polyimide component of formula III. In the formulae, R1 is a residue derived by removing the four carboxyl groups from an aromatic tetracarboxylic acid; R2 is a hydrocarbon group or phenylene; R3 is a 1-3C alkyl or phenyl; n1 is 3-50; r1 is hydroxyl or carboxyl; X is a direct bond, -O-, -S-, or a group of any one of formulae IV to IX; n2 is 1 or 2; n3 is 0-3; R4 and R5 are each H, methyl, or trifluoromethyl; and R6 is a residue derived by removing the amino groups from a diamine compound other than the diamine compounds forming the diamine components of formulae I and II.
-
公开(公告)号:JPH11310754A
公开(公告)日:1999-11-09
申请号:JP11827998
申请日:1998-04-28
Applicant: UBE INDUSTRIES
Inventor: ISHIKAWA SEIJI , YAMAMOTO SHIGERU , WATANABE YOSHIAKI
IPC: C09D179/08 , C09D183/10 , H01B3/30 , H01B3/46 , H01L23/29 , H01L23/31
Abstract: PROBLEM TO BE SOLVED: To obtain a coating material which has a good storage stability and gives a cured film excellent in plating resistance, heat resistance, softness, etc., by incorporating a polyimidesiloxane, an epoxy resin, a fine-particle inorg. filler, and a high-b.p. solvent each in a specified amt. into the same and imparting a specified viscosity to the same. SOLUTION: This coating material contains 100 pts.wt. org.-solvent-soluble polyimidesiloxane represented by formulas I-III, 2-30 pts.wt. epoxy resin, 20-150 pts.wt. fine-particle inorg. filler, and 60-140 pts.wt. high-b.p. solvent and has a viscosity of 400-1,000 P. In the formulas, R1 is a tetravalent residue formed by removing four carboxyl groups from a tetracarboxylic acid; R2 is a residue formed by removing the NH2 group from a compd. of formula IV; R3 is a residue formed by removing the NH2 group from a compd. of formula V; R4 is R2 or R3 ; n1 is 3-50; R5 is a divalent hydrocarbon group or phenyl; R6 is an alkyl or the like; X is a direct bond or the like; r1 is OH or COOH; n2 is 1 or 2; n3 is 0-3; and m1, m2, and m3 are each the mole fraction of the respective component and are 60-92.5 mol.%, 7.5-40 mol.%, and the rest, respectively, the sum being 100 mol.%.
-
公开(公告)号:JPH10733A
公开(公告)日:1998-01-06
申请号:JP15652896
申请日:1996-06-18
Applicant: UBE INDUSTRIES
Inventor: ISHIKAWA SEIJI , YASUNO HIROSHI
IPC: C08J5/12 , B32B15/08 , B32B15/088 , C08G59/40 , C08G73/10 , C08L63/00 , C09J163/00 , C09J179/08 , H05K3/38
Abstract: PROBLEM TO BE SOLVED: To eliminate the fixation of a metal layer to a substrate under pressure at high temperature by a method wherein a composition, which is prepared by dissolving a polymer component consisting of non-crystalline polyimide siloxane and aromatic epoxy compound in organic solvent, is applied onto the substrate so as to paste the metal layer to the board at the lamination of the metal layer to the substrate through adhesive. SOLUTION: At the manufacturing of a laminated substrate such as one represented by the flexible substrate of a tape of TAB, a composition, which is prepared by dissolving a polymer component consisting of non-crystalline polyimide siloxane having a functional group reacting with an epoxy group in a benzene ring and an aromatic epoxy compound in organic solvent, is applied onto a laminated substrate and, after the solvent is removed through evaporation, the metal layer is pasted to the bonding surface of the substrate under heat and pressure. At this case as the functional group reactive with the epoxy group of the non-crystalline polyimide siloxane, an OH group or a COOH group is employed. Further, the adhesive is prepared from the reactive mixture of 100 pts.wt. of the non-crystalline polyimide siloxane and 1-50 pts.wt. of epoxy resin.
-
公开(公告)号:JPH09100350A
公开(公告)日:1997-04-15
申请号:JP14905096
申请日:1996-06-11
Applicant: UBE INDUSTRIES
Inventor: ISHIKAWA SEIJI , YASUNO HIROSHI , SAKURAI HIROYUKI
IPC: C08G73/10 , C08G77/455 , C08L79/08 , C09D183/10 , G03F7/038 , G03F7/075 , H01B3/30
Abstract: PROBLEM TO BE SOLVED: To obtain a photosensitive polyimidosiloxane which is solvent-soluble and used for forming an insulating film by polymerizing an aromatic tetracarboxylic acid dianhydride with a photosensitive-group-containing aromatic diamine and a specified diaminopolysiloxane and imidating the obtained polyamic acid. SOLUTION: Equipment amounts of an aromatic tetracarboxylic acid dianhydride component of formula I (wherein R1 and R2 are each an acid anhydride-group- containing mononuclear aromatic group; and X is CO, O or a direct bond) and a diamine component comprising 15-80mol% photosensitive-group-containing aromatic diamine of formula II (wherein R3 is a photosensitive-group-containing aromatic group having a hydrocarbon unsaturation) and 85-20mol% diaminopolysiloxane of formula III (wherein R4 is a hydrocarbon group; R5 is a 1-3C alkyl or a phenyl; and (l) is 3-30) are polymerized, and the formed polyamic acid is imidated to obtain a photosensitive polyimidosiloxane soluble in organic solvents. The new aromatic polyimidosiloxane is excellent in heat resistance and electrical properties and flexible and is excellent as an overcoating material for flexible printed wiring boards, an interlayer insulation material or an insulation film forming material for solid-state elements.
-
-
-
-
-
-
-
-
-