폐플라스틱으로부터 재생연료유를 생산하는 회분식 공정의 연속공정화 방법
    51.
    发明公开
    폐플라스틱으로부터 재생연료유를 생산하는 회분식 공정의 연속공정화 방법 有权
    从废弃塑料生产回收燃油的连续加工方法

    公开(公告)号:KR1020110075308A

    公开(公告)日:2011-07-06

    申请号:KR1020090131725

    申请日:2009-12-28

    CPC classification number: Y02W30/703

    Abstract: PURPOSE: A continuous processing method of a batch type process for producing recycled fuel oil from waste plastic is provided to convert a batch type thermal cracking process into a continuous thermal cracking process by adding some apparatuses to the batch type thermal cracking process and remodeling a conventional apparatus. CONSTITUTION: A continuous processing method of a batch type process for producing recycled fuel oil from waste plastic comprises the steps of: transferring residue sludge stacked in a thermal cracking step to a sludge reactor(9); leaving the powdery residue at the back end of the sludge reactor and transferring the residue to a residue transfer device(10) by thermally cracking the transferred sludge in the sludge reactor at a temperature of 410 - 460°C; and transferring the residue to a cooling device(12) through the residue transfer device and storing the cooled residue in a storage device(13).

    Abstract translation: 目的:提供一种用于从废塑料生产回收燃料油的间歇式方法的连续加工方法,通过向批式热裂解工艺添加一些装置并将常规 仪器。 构成:用于从废塑料生产回收燃料油的间歇式方法的连续加工方法包括以下步骤:将在热裂解步骤中堆叠的残渣污泥转移至污泥反应器(9); 在污泥反应器的后端留下粉末残留物,并通过在410-460℃的温度下对污泥反应器中转移的污泥进行热裂化将残余物转移到残余物转移装置(10); 并通过残余物转移装置将残余物转移到冷却装置(12),并将冷却的残余物储存在存储装置(13)中。

    고산도 원유 중의 산성분 제거를 위한 촉매 및 그 제법
    52.
    发明授权
    고산도 원유 중의 산성분 제거를 위한 촉매 및 그 제법 有权
    用于去除高TAN粗品中酸性化合物的催化剂及其制备方法

    公开(公告)号:KR101040966B1

    公开(公告)日:2011-06-16

    申请号:KR1020080110965

    申请日:2008-11-10

    CPC classification number: B01J21/10 B01J21/14 B01J37/031 C10G25/00

    Abstract: 본 발명은 고산도 원유(High TAN crude) 중의 산 성분을 반응을 통하여 제거하기 위한 촉매와 그 제법에 관한 것이다. 고산도 원유는 공정 부식을 일으키는 산성분이 많이 함유되어 있는데, 이러한 산성분을 탈탄산 반응을 통하여 제거한다. 기존의 탈탄산 반응을 위한 촉매로는 알칼리 토금속 산화물이나 수화물이 이용되었는데 이들 촉매들은 촉매 반응환경하에서 원유에 나프텐염의 형태로 녹아들어가 이차적인 문제를 유발한다. 본 발명은 알칼리토금속 양이온 혹은 전이금속 양이온이 실리케이트 혹은 알루미네이트 등의 음이온과 결합한 형태의 탈탄산 촉매를 제공하며 이 촉매는 산성분위기 하에서도 안정하면서 우수한 탈탄산 활성을 보인다.
    고산도 원유(High TAN crude), 나프텐산(Naphthenic acid), 탈탄산 반응(Decarboxylation), 염기성 촉매(Base catalyst), 내산성 촉매(acid resistance catalyst)

    오일 분산성 나노첨가제를 이용한 중질유의 가스화 방법
    53.
    发明公开
    오일 분산성 나노첨가제를 이용한 중질유의 가스화 방법 有权
    使用油分散的纳米添加剂的重油的气化方法

    公开(公告)号:KR1020110053583A

    公开(公告)日:2011-05-24

    申请号:KR1020090110166

    申请日:2009-11-16

    Abstract: PURPOSE: A gasification method of heavy crude oil using an oil dispersion nano additive is provided to improve the productivity of combustible hydrogen gas. CONSTITUTION: A gasification method of heavy crude oil using an oil dispersion nano additive comprises the following steps: uniformly dispersing a nano additive formed by metal oxides in the nanoparticle size selected from the group consisting of metal hydroxide, metal halide, metal nitrate, and metal sulfate, to heavy oil(S1); supplying steam and oxygen to the heavy oil(S2); spraying the heavy oil to the inside of a gasification reactor; and producing synthetic gas by gasifying(S3).

    Abstract translation: 目的:提供使用油分散纳米添加剂的重质原油气化方法,以提高可燃氢气的生产率。 构成:使用油分散纳米添加剂的重质原油的气化方法包括以下步骤:将由金属氧化物形成的纳米添加剂均匀分散在选自金属氢氧化物,金属卤化物,金属硝酸盐和金属的纳米颗粒尺寸 硫酸盐,重油(S1); 向重油(S2)供应蒸气和氧气; 将重油喷射到气化反应器的内部; 并通过气化生产合成气(S3)。

    2가지 이상의 금속이 결합된 수산화물 계열 전구체의 표면 개질을 통한 유용성 입자 제조방법
    54.
    发明公开
    2가지 이상의 금속이 결합된 수산화물 계열 전구체의 표면 개질을 통한 유용성 입자 제조방법 有权
    通过由两种或多种金属成分组成的基于氢氧化物的前驱体进行表面改性制备油溶性颗粒的方法

    公开(公告)号:KR1020110051330A

    公开(公告)日:2011-05-18

    申请号:KR1020090107842

    申请日:2009-11-10

    Abstract: PURPOSE: A method for preparing oil-soluble particles is provided to obtain the oil-soluble particles based on various metal by inducing the reaction with organic acid after a hydroxide-based precursor is prepared. CONSTITUTION: Two or more metal compound aqueous solutions are mixed and stirred(S11). The pH of the mixed aqueous solution is controlled between 5.0 and 10.0 in order to cause coprecipitation. Precipitate is collected through the coprecipitation(S12). A hydroxide-based precursor combined with two or more metal is prepared. The surface of the hydroxide-based precursor is modified using organic acid through an esterification reaction. The organic acid is one selected from a group including aliphatic acid, alicyclic acid, aromatic acid, phosphorus-containing acid.

    Abstract translation: 目的:提供一种制备油溶性颗粒的方法,通过在制备基于氢氧化物的前体之后通过诱导与有机酸的反应,获得基于各种金属的油溶性颗粒。 构成:将两种以上的金属化合物水溶液混合搅拌(S11)。 将混合水溶液的pH控制在5.0和10.0之间以引起共沉淀。 通过共沉淀收集沉淀物(S12)。 制备与两种或更多种金属组合的基于氢氧化物的前体。 基于氢氧化物的前体的表面通过酯化反应用有机酸改性。 有机酸是选自脂肪酸,脂环族酸,芳香酸,含磷酸的组中的一种。

    미연탄소 및 질소산화물 저감용 철계 나노유체 연료첨가제및 그 제조방법
    55.
    发明公开
    미연탄소 및 질소산화물 저감용 철계 나노유체 연료첨가제및 그 제조방법 有权
    作为燃料添加剂的铁纳米微粒的制备和减少氮氧化物

    公开(公告)号:KR1020100013654A

    公开(公告)日:2010-02-10

    申请号:KR1020080075267

    申请日:2008-07-31

    CPC classification number: C10L10/02 B82B3/00 B82Y30/00 C10L1/1233 C10L2290/24

    Abstract: PURPOSE: A ferrous nanofluid fuel additive for reducing unburned carbon and nitrogen oxide and a manufacturing method thereof are provided to reduce the unburned carbon and the nitrogen oxide by dispersing nanoparticles on an organic solvent. CONSTITUTION: A manufacturing method of a ferrous nanofluid fuel additive for reducing unburned carbon and nitrogen oxide comprises the following steps: manufacturing nanoparticles of iron oxides or iron oxy-hydroxide by a chemical synthesis method; surface-reforming the nanoparticles with a surfactant with lipophilic property; and dispersing the nanoparticles in an organic solvent. The iron oxides or the iron oxy-hydroxide is ferrous hydroxide(Fe(OH)2), ferric hydroxide(Fe(OH)3), ferrous oxide(FeO), ferric oxide(Fe2O3) and triiron tetraoxide(Fe3O4).

    Abstract translation: 目的:提供一种用于还原未燃碳和氮氧化物的亚铁纳米流体燃料添加剂及其制造方法,以通过将纳米颗粒分散在有机溶剂上来还原未燃碳和氮氧化物。 构成:用于还原未燃碳和氮氧化物的亚铁纳米流体燃料添加剂的制造方法包括以下步骤:通过化学合成方法制造氧化铁或氢氧化铁的纳米颗粒; 用具有亲油性的表面活性剂对纳米颗粒进行表面重整; 并将纳米颗粒分散在有机溶剂中。 氧化铁或氧化氢铁是氢氧化亚铁(Fe(OH)2),氢氧化铁(Fe(OH)3),氧化亚铁(FeO),氧化铁(Fe2O3)和四氧化三铁(Fe 3 O 4)。

    고효율 염소제거장치를 구비한 연료유정제장치
    56.
    发明授权
    고효율 염소제거장치를 구비한 연료유정제장치 有权
    用于精炼燃料油的装置,包括用于除氯的高效率装置

    公开(公告)号:KR100922366B1

    公开(公告)日:2009-10-19

    申请号:KR1020070122429

    申请日:2007-11-29

    Abstract: 본 발명은 염소 성분을 제거하기 위한 연료유 정제장치에 관한 것으로, 더 상세하게는 폐플라스틱을 열분해하여 수득한 연료유 중 대부분을 차지하는 저급연료유를 경제성이 있는 고품질로 정제하기 위한 연료유정제장치를 제공하되, 특히 염소성분을 효과적으로 제거하기 위하여 화학정제장치 및 물-오일분리기와 물-오일혼합기의 분리 및 혼합효율을 더욱 향상시키기 위한 고효율 염소제거장치를 구비한 연료유정제장치에 관한 것이다.
    염소제거장치, 저급 열분해유, 정제장치, 폐플라스틱, 열분해, 효율향상

    염소제거장치를 구비한 연료유정제장치
    57.
    发明授权
    염소제거장치를 구비한 연료유정제장치 有权
    用于精炼燃油的装置,包括用于去除氯液的装置

    公开(公告)号:KR100824965B1

    公开(公告)日:2008-04-28

    申请号:KR1020070043953

    申请日:2007-05-07

    Abstract: A fuel oil-refining apparatus is provided to remove chloride components contained in fuel oil, which is obtained by treating waste plastic or waste oil, thereby producing high-quality fuel oil without chloride components. A chemical refinement unit(60) mixes low-quality fuel oil and basic aqueous solution, wherein the low-quality fuel oil is prepared by pyrolyzing and distilling one component selected from waste plastic, waste synthetic resin, waste rubber, or waste oil. A water-oil separator(70) separates fuel oil from the mixture of the fuel oil and the basic aqueous solution. A horizontal partition wall(730) is disposed in the middle of the water-oil separator to divide an inside space of the water-oil separator into a first space(710) and a second space(720). Upper portions of the first space and the second space communicate with each other. Further, a fuel oil-refining apparatus(200) additionally contains a water-oil mixer(80) at an upper part of the chemical refinement unit.

    Abstract translation: 提供燃料油精炼装置以除去通过处理废塑料或废油获得的燃料油中所含的氯化物成分,由此生产没有氯化物组分的高质量燃料油。 化学精制单元(60)将低质量燃料油和碱性水溶液混合,其中低质量燃料油通过热解和蒸馏选自废塑料,废合成树脂,废橡胶或废油中的一种组分来制备。 油 - 油分离器(70)将燃料油与燃料油和碱性水溶液的混合物分离。 水分隔壁(730)设置在水 - 油分离器的中间以将油水分离器的内部空间分成第一空间(710)和第二空间(720)。 第一空间和第二空间的上部彼此连通。 此外,燃料精炼装置(200)另外在化学精制装置的上部还含有水 - 油混合器(80)。

    촉매내장형 다단 저온플라즈마 반응기
    58.
    发明授权
    촉매내장형 다단 저온플라즈마 반응기 有权
    촉매내장형다단저온플라즈마반응기

    公开(公告)号:KR100464167B1

    公开(公告)日:2005-01-03

    申请号:KR1020020010366

    申请日:2002-02-27

    Abstract: PURPOSE: A catalyst embedded multistep low temperature plasma reactor is provided which is capable of controlling desired reaction according to types of catalyst used by minimizing a time required for radicals generated in the plasma region to reach the catalyst region. CONSTITUTION: In treating air pollutants such as nitrogen oxides, sulfur oxides and volatile organic compounds, the catalyst embedded multistep low temperature plasma reactor is characterized in that an upper duct(1) on which inlet is formed is connected to a reactor main body(3) formed in multistep through an upper flange(2), a lower duct(5) on which outlet is formed is connected to reactor main body(3') through a lower flange(6), upper supports(9,9') are connected to lower supports(8,8') on which bar type electrodes(7,7') are formed in the respective reactor main bodies(3,3'), catalyst (C) is charged into the supports(8,8',9,9'), and catalyst grounding electrode and catalyst discharging electrode at which meshes(10,10') and wires(11,11') are installed are inserted into upper and lower parts of the supports(8,8',9,9'), wherein the reactor main bodies(3,3') are fabricated of Teflon, alumina or ceramics, and the catalyst electrodes are fabricated of stainless steel, Teflon, alumina or ceramics, wherein honeycomb shaped particulate catalyst (C) such as Cu/ZSM-5 based catalyst, photocatalyst, mixed photocatalyst, SCR catalyst and oxidation catalyst is charged into cylinder of the catalyst electrodes, and wherein the catalyst grounding electrode and catalyst discharging electrode are connected in series to easily control capacity of the reactor.

    Abstract translation: 目的:提供一种催化剂嵌入的多步低温等离子体反应器,其能够根据所使用的催化剂类型来控制期望的反应,其通过最小化在等离子体区域中产生的自由基到达催化剂区域所需的时间。 本发明公开了一种催化剂埋入式多级低温等离子体反应器,在处理空气污染物如氮氧化物,硫氧化物和挥发性有机化合物时,其特征在于:形成入口的上导管(1)与反应器主体(3) )通过上部凸缘(2)形成为多级,形成有出口的下部管道(5)通过下部凸缘(6)与反应器主体(3')连接,上部支撑体(9,9')为 (3,3')上形成有棒状电极(7,7')的下部支承体(8,8')上,将催化剂(C)填充到支承体(8,8' ,9,9')以及在其上安装网眼(10,10')和导线(11,11')的催化剂接地电极和催化剂放电电极被插入到支撑件(8,8',8,9')的上部和下部中, 9,3'),其中反应器主体(3,3')由聚四氟乙烯,氧化铝或陶瓷制成,并且催化剂电极由不锈钢,聚四氟乙烯,氧化铝或c 在催化剂电极的圆筒内填充Cu / ZSM-5系催化剂,光催化剂,混合光催化剂,SCR催化剂,氧化催化剂等蜂窝状颗粒状催化剂(C),催化剂接地电极和催化剂放电电极为 串联连接以容易地控制反应器的容量。

    폐타이어/폐유의 복합열분해에 의한 오일화 장치와 그 방법
    59.
    发明授权
    폐타이어/폐유의 복합열분해에 의한 오일화 장치와 그 방법 失效
    用于通过组合热分解制备油的装置和方法使用的废物/油

    公开(公告)号:KR100148205B1

    公开(公告)日:1998-08-01

    申请号:KR1019950014824

    申请日:1995-06-05

    Abstract: 본 발명은 가열된 폐유내에서 폐타이어를 열분해 반응시켜 오일화하기 위한 열분해 반응조건과 장치 및 그 방법에 관한 것으로 열분해 반응시 온도를 380℃로 낮추고 폐타이어와 폐유의 공급비를 2:1하여 분해시킴으로서 폐유에 대한 폐타이어의 처리량을 높이고 열효율을 증대시켰으며 반응기내 첨가제 수산화 칼슘[Ca(OH)
    2 ]을 첨가하여 열분해 생성오일중의 유황분과 염소등의 유해물질의 함유량을 최소화하였고, 열분해 장치의 기계적 결함을 해소하기 위해 폐유가열장치, 폐타이어의 연속공급장치, 열분해 반응기 및 잔유물 건조기의 장치상의 문제점을 개선한 폐타이어/폐유의 복합열분해에 의한 오일화 장치.

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