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公开(公告)号:CA2345053C
公开(公告)日:2008-07-15
申请号:CA2345053
申请日:1999-09-21
Applicant: BASF AG
Inventor: THEIS GERHARD , VANSANT FRANS , HASSE HANS , ADRIAN TILL , BESSLING BERND
Abstract: The invention relates to a method for obtaining highly pure monoethylene glycol from the product of hydrolysis of ethylene oxide by distillation, by means of dehydration under pressure, preferably in a cascade, vacuum dehydration and subsequent pure distillation. During the vacuum dehydration, an aqueous stream containing monoethylene glycol in a concentration of less than 1 wt. %, preferably less than 0.1 wt. %, medium boilers and light boilers is drawn off and then sluiced out, optionally after reprocessing.
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公开(公告)号:RU2319684C2
公开(公告)日:2008-03-20
申请号:RU2005105045
申请日:2003-07-22
Applicant: BASF AG
Inventor: ADRIAN TILL , KHILL TOMAS , KINDLER KLAUS , KHAJDA BERND
IPC: C07C7/08 , B01D3/40 , C07C5/22 , C07C11/167
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公开(公告)号:ES2279821T3
公开(公告)日:2007-09-01
申请号:ES01945105
申请日:2001-05-09
Applicant: BASF AG
Inventor: MEYER GERALD , KAIBEL GERD , BOHNER GERD , KINDLER KLAUS , ADRIAN TILL , PICKENACKER KARIN
IPC: C07C7/08 , C07C11/167 , B01D3/14 , B01D3/40 , C07C5/09 , C07C7/00 , C07C7/163 , C10G7/08 , C10G70/00 , C10G70/02
Abstract: Un proceso para el trabajo de una fracción C4, que comprende las etapas de proceso - Destilación extractiva (I), - Hidrogenación selectiva de impurezas acetilénicas sobre un catalizador heterogéneo (II), una corriente de 1, 3-butadieno crudo que comprende un producto objetivo 1, 3-butadieno en una fracción de al menos 80% en peso que se obtiene siguiendo las etapas del proceso I y II y - La destilación de la corriente de 1, 3-butadieno crudo para aislar el 1, 3-butadieno (III) que comprende el producto objetivo 1, 3-butadieno en una fracción de al menos 99% en peso, en donde las etapas de proceso I y II se llevan a cabo en una columna única y el proceso de la etapa III se lleva a cabo en una segunda columna, el catalizador heterogéneo utilizado para la hidrogenación selectiva de impurezas acetilénicas está presente en la forma de internos reactivos.
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公开(公告)号:AT273265T
公开(公告)日:2004-08-15
申请号:AT01915134
申请日:2001-01-12
Applicant: BASF AG
Inventor: AUER HEINZ , BESSLING BERND , HAMMER HANS , HASSE HANS , SAUER FRIEDRICH , VICARI MAXIMILIAN , ADRIAN TILL
Abstract: The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid, in which firstly aqueous formic acid is produced by hydrolysis of methyl formate, with the methanol content in the methyl formate having been reduced in advance. The process according to the invention has the special feature that-before the hydrolysis of the methyl formate-the methanol content of the methanol-containing methyl formate is reduced in a distillation column, this distillation column simultaneously being employed for other separation functions during work-up of the formic acid.
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公开(公告)号:BR0110721A
公开(公告)日:2004-02-10
申请号:BR0110721
申请日:2001-05-09
Applicant: BASF AG
Inventor: MEYER GERALD , KAIBEL GERD , BOHNER GERD , KINDLER KLAUS , ADRIAN TILL , PICKENOCKER KARIN , PAHL MELANIE , HILL THOMAS
IPC: C07C7/08 , B01D3/14 , B01D3/40 , C07C5/09 , C07C7/00 , C07C11/167 , C10G7/08 , C10G70/00 , C10G70/02 , C07C7/163
Abstract: In a process for the work-up of a C4 fraction, comprising the process steps Extractive distillation (I), Selective hydrogenation over a heterogeneous catalyst (II), a crude 1,3-butadiene stream being obtained following process steps (I) and (II) and Distillation of the crude 1,3-butadiene stream for isolating pure 1,3-butadiene (III), the process steps I and II are carried out in a single column or in thermally coupled columns and the process step III is carried out in a second column.
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公开(公告)号:CA2493079A1
公开(公告)日:2004-02-05
申请号:CA2493079
申请日:2003-07-22
Applicant: BASF AG
Inventor: KINDLER KLAUS , HEIDA BERND , ADRIAN TILL , HILL THOMAS
Abstract: The invention relates to a continuous method for separating a C4 cut (C4) by means of extractive distillation using a selective solvent (LM) in an extractive distillation column (EDK). A separating wall (TW), forming a firs t partial region (A), a second partial region (B) and a lower common column region (C), is arranged in the longitudinal direction of the extractive distillation column (EDK). According to said method, a head flow (C4H10) comprising butane is separated from the first partial region (A), a head flo w (C4H8) comprising butene is separated from the second partial region (B), an d a flow (C4H6) comprising the hydrocarbons from the C4 cut is separated from the lower common column region (C), said hydrocarbons dissolving more easily in the selective solvent (LM) than the butane and the butene.
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公开(公告)号:NO20023513L
公开(公告)日:2002-08-26
申请号:NO20023513
申请日:2002-07-23
Applicant: BASF AG
Inventor: AUER HEINZ , BESSLING BERND , HAMMER HANS , HASSE HANS , SAUER FRIEDRICH , VICARI MAXIMILIAN , WAGNER GERHARD , ADRIAN TILL
Abstract: The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid in which, during the work-up, a compound of the general formula Iwhere the radicals R1 and R2 are alkyl, cycloalkyl, aryl or aralkyl groups, or R1 and R2 jointly, together with the N atom, form a heterocyclic 5- or 6-membered ring, and only one of the radicals is an aryl group, and where R3 is hydrogen or a C1-C4-alkyl group,is employed simultaneously as extractant for formic acid and as antifoam for a distillation process.
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公开(公告)号:NO20023480A
公开(公告)日:2002-08-22
申请号:NO20023480
申请日:2002-07-22
Applicant: BASF AG
Inventor: AUER HEINZ , BESSLING BERND , HAMMER HANS , HASSE HANS , SAUER FRIEDRICH , VICARI MAXIMILIAN , WAGNER GERHARD , ADRIAN TILL
CPC classification number: C07C51/445 , B01J14/00 , B01J2219/00006 , C07C51/09 , C07C51/44 , C07C51/48 , C07C53/02
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公开(公告)号:NO20023481A
公开(公告)日:2002-08-21
申请号:NO20023481
申请日:2002-07-22
Applicant: BASF AG
Inventor: AUER HEINZ , BESSLING BERND , HAMMER HANS , HASSE HANS , SAUER FRIEDRICH , VICARI MAXIMILIAN , ADRIAN TILL
CPC classification number: C07C51/445 , B01J14/00 , B01J2219/00006 , C07C51/09 , C07C51/44 , C07C51/48 , C07C53/02
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公开(公告)号:NO20023514D0
公开(公告)日:2002-07-23
申请号:NO20023514
申请日:2002-07-23
Applicant: BASF AG
Inventor: AUER HEINZ , BESSLING BERND , HAMMER HANS , HASSE HANS , SAUER FRIEDRICH , VICARI MAXIMILIAN , ADRIAN TILL
Abstract: The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid, in which firstly aqueous formic acid is produced by hydrolysis of methyl formate, with the methanol content in the methyl formate having been reduced in advance. The process according to the invention has the special feature that-before the hydrolysis of the methyl formate-the methanol content of the methanol-containing methyl formate is reduced in a distillation column, this distillation column simultaneously being employed for other separation functions during work-up of the formic acid.
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