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公开(公告)号:PL383682A1
公开(公告)日:2008-04-14
申请号:PL38368204
申请日:2004-02-24
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , HADERLEIN GERD , FLORES MIGUEL , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JENS , SIEGEL WOLFGANG , BASSLER PETER
IPC: C07C253/10 , C07C253/34 , C07C255/04
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公开(公告)号:AT368676T
公开(公告)日:2007-08-15
申请号:AT05701205
申请日:2005-01-27
Applicant: BASF AG
Inventor: SCHEIDEL JENS , JUNGKAMP TIM , BARTSCH MICHAEL , HADERLEIN GERD , BAUMANN ROBERT , LUYKEN HERMANN , DECKERT PETRA , PFAB PETER , SIEGEL WOLFGANG , AECHTNER TOBIAS
IPC: C07F9/00 , C07C253/34 , C07C255/04 , C07F9/02
Abstract: A process for extractively removing nickel(0) complexes having phosphorus ligands and/or free phosphorus ligands from a reaction effluent of a hydrocyanation of unsaturated mononitriles to dinitriles by extraction by means of a hydrocarbon, a phase separation of the hydrocarbon and of the reaction effluent into two phases being effected at a temperature T (in ° C.), wherein the content of nickel(0) complexes having phosphorus ligands and/or free phosphorus ligands in the reaction effluent of the hydrocyanation, depending on the temperature T, is at least y % by weight and, irrespective of the temperature T, is a maximum of 60% by weight, where the numerical value of the minimum content y is given by the equation y=0.5.T+20 and T is to be used in the equation as a dimensionless numerical value.
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公开(公告)号:PL1610893T3
公开(公告)日:2007-07-31
申请号:PL04722843
申请日:2004-03-24
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , HADERLEIN GERD , FLORES MIGUEL ANGEL , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JENS , SIEGEL WOLFGANG , MOLNAR FERENC
IPC: B01J27/14 , B01J23/755 , B01J31/02 , B01J31/14 , B01J31/18 , C07C253/10 , C07C255/04
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公开(公告)号:BRPI0507258A
公开(公告)日:2007-06-26
申请号:BRPI0507258
申请日:2005-01-27
Applicant: BASF AG
Inventor: SCHEIDEL JENS , JUNGKAMP TIM , BARTSCH MICHAEL , HADERLEIN GERD , BAUMANN ROBERT , LUYKEN HERMANN , DECKERT PETRA , PFAB PETER , SIEGEL WOLFGANG , AECHTNER TOBIAS
IPC: C07F9/00 , C07C253/34 , C07C255/04 , C07F9/02
Abstract: A process for extractively removing nickel(0) complexes having phosphorus ligands and/or free phosphorus ligands from a reaction effluent of a hydrocyanation of unsaturated mononitriles to dinitriles by extraction by means of a hydrocarbon, a phase separation of the hydrocarbon and of the reaction effluent into two phases being effected at a temperature T (in ° C.), wherein the content of nickel(0) complexes having phosphorus ligands and/or free phosphorus ligands in the reaction effluent of the hydrocyanation, depending on the temperature T, is at least y % by weight and, irrespective of the temperature T, is a maximum of 60% by weight, where the numerical value of the minimum content y is given by the equation y=0.5.T+20 and T is to be used in the equation as a dimensionless numerical value.
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公开(公告)号:BRPI0507196A
公开(公告)日:2007-06-26
申请号:BRPI0507196
申请日:2005-01-26
Applicant: BASF AG
Inventor: JUNGKAMP TIM , BAUMANN ROBERT , BARTSCH MICHAEL , HADERLEIN GERD , LUYKEN HERMANN , SCHEIDEL JENS
IPC: C07C253/34 , C07C255/07
Abstract: A process is described for separating mixtures of isomeric pentenenitriles, in which at least one isomer is removed from the mixture, wherein the separation of the substance mixtures of isomeric pentenenitriles is effected distillatively under reduced pressure.
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公开(公告)号:AT358134T
公开(公告)日:2007-04-15
申请号:AT03704443
申请日:2003-01-21
Applicant: BASF AG
Inventor: VOLLAND MARTIN , SEITZ VERENA , MAASE MATTHIAS , FLORES MIGUEL ANGEL , PAPP RAINER , MASSONNE KLEMENS , STEGMANN VEIT , HALBRITTER KLAUS , NOE RALF , BARTSCH MICHAEL , SIEGEL WOLFGANG , BECKER MICHAEL , HUTTENLOCH OLIVER
IPC: C07D233/58 , B01J31/24 , C07B61/00 , C07B63/00 , C07B63/02 , C07C1/30 , C07C7/10 , C07C13/23 , C07C45/50 , C07C67/14 , C07C67/58 , C07C69/14 , C07C69/78 , C07C403/12 , C07D233/60 , C07D403/12 , C07F7/18 , C07F9/02 , C07F9/12 , C07F9/142 , C07F9/145 , C07F9/22 , C07F9/46 , C07F9/48 , C07F9/50 , C07F9/52 , C07F9/572 , C07F9/6503 , C07F9/6574 , C07F9/6584
Abstract: Process for preparing aminodihalophosphines, diaminohalophosphines, triaminophosphines, phosphorous ester diamides, aminophosphines, diaminophosphines, phosphorous ester amide halides and aminophosphine halides with elimination of an acid in the presence of an auxiliary base, wherein the auxiliary base b) and the acid form a salt which is liquid at temperatures at which the desired product is not significantly decomposed during the process of separating off the liquid salt and c) the salt of the auxiliary base forms two immiscible liquid phases with the desired product or the solution of the desired product in a suitable solvent.
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公开(公告)号:BRPI0415975A
公开(公告)日:2007-01-23
申请号:BRPI0415975
申请日:2004-10-28
Applicant: BASF AG
Inventor: HADERLEIN GERD , BAUMANN ROBERT , BARTSCH MICHAEL , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JENS , SIEGEL WOLFGANG
IPC: B01J31/18 , B01J31/24 , C07C253/10 , C07C255/04 , C07F15/04 , B01J37/16 , B01J31/30
Abstract: The present invention provides a process for preparing nickel(0)-phosphorus ligand complexes starting from nickel(II)-ether adducts.
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公开(公告)号:BRPI0409316A
公开(公告)日:2006-04-25
申请号:BRPI0409316
申请日:2004-04-15
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , HADERLEIN GERD , FLORES MIGUEL ANGEL , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JENS , SIEGEL WOLFGANG , KUNSMANN-KEITEL DAGMAR PASCALE , BASSLER PETER
IPC: C01C3/02 , C01C3/04 , C07C253/00
Abstract: A process for dewatering hydrocyanic acid by distillation, which includes distilling crude hydrocyanic acid containing from 50 to 99.9% by weight of HCN, from 0.1 to 40% by weight of water, from 0 to 15% by weight of carbon oxides and optionally from 0.01 to 1% by weight of an involatile stabilizer, at a pressure of from 1 bar to 2.5 bar, a bottom temperature of from 100° C. to 130° C. and a top temperature of from 25° C. to 54° C., in the absence of a volatile stabilizer, in a distillation column to obtain a top draw stream containing purified, anhydrous hydrocyanic acid and carbon oxides and a bottom draw stream including water and, optionally, the involatile stabilizer.
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公开(公告)号:AR047477A1
公开(公告)日:2006-01-18
申请号:ARP050100310
申请日:2005-01-28
Applicant: BASF AG
Inventor: JUNG DIETER , POLKA H , BAUMANN ROBERT , BARTSCH MICHAEL , HADERLEIN GERD , LUYKEN HERMANN , SCHEIDEL JENS
IPC: C07C253/34 , C07C255/04 , C07C255/07
Abstract: Reivindicacion 1: Procedimiento para reducir el contenido de ácido cianhídrico en mezclas que contienen pentenonitrilos y ácido cianhídrico, caracterizado porque la reduccion del contenido de ácido cianhídrico se realiza mediante separacion de ácido cianhídrico por medio de una destilacion azeotropica con 1,3-butadieno. Reivindicacion 2: Procedimiento segun la reivindicacion 1, que está caracterizado por las siguientes etapas de procedimiento: a) hidrocianuracion de 1-3-butadieno por transformacion de éste con ácido cianhídrico en presencia de por lo menos un catalizador de hidrocianuracion, obteniéndose una corriente de hidrocianuracion, que contiene 3-pentenonitrilo, 2-metil-3-butenonitrilo, ácido cianhídrico, 1,3-butadiendo y el por lo menos un catalizador de hidrocianuracion, b) separacion de una mezcla de ácido cianhídrico y 1,3-butadieno, que forma un azeotropo, a partir de la corriente de hidrocianuracion por destilacion.
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公开(公告)号:DE102004004672A1
公开(公告)日:2005-08-18
申请号:DE102004004672
申请日:2004-01-29
Applicant: BASF AG
Inventor: JUNGKAMP TIM , BAUMANN ROBERT , SCHROEDER THORSTEN , BARTSCH MICHAEL , HADERLEIN GERD , LUYKEN HERMANN , SCHEIDEL JENS
IPC: C07C253/10 , C07C255/07
Abstract: A process is described for preparing 3-pentenenitrile by hydrocyanating 1,3-butadiene in the presence of at least one catalyst, wherein unhydrocyanated 1,3-butadiene is removed from the effluent of the hydrocyanation and recycled into the process, and the recycled 1,3-butadiene is monitored for the content of hydrogen cyanide.
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