54.
    发明专利
    未知

    公开(公告)号:DE3741159A1

    公开(公告)日:1989-06-15

    申请号:DE3741159

    申请日:1987-12-04

    Applicant: BASF AG

    Abstract: Cyanopyridines of the formula are prepared by reacting acrolein and an alkanal or its acetal or ketone of the formula where R1, R2 and R3 may be identical or different and are each hydrogen, alkyl of 1 to 6 carbon atoms or aryl and R4 is alkyl and n is 0-11, with ammonia in the presence of a zeolite as a catalyst. The reaction is preferably carried out in the gas phase.

    55.
    发明专利
    未知

    公开(公告)号:DE3740270A1

    公开(公告)日:1989-06-01

    申请号:DE3740270

    申请日:1987-11-27

    Applicant: BASF AG

    Abstract: Phenylacetaldehydes of the general formula I (I) where R1 to R5 are each independently of the others hydrogen, alkyl, alkoxy, halogen, haloalkyl, haloalkoxy or haloalkylthio, by catalytic rearrangement in the presence of a zeolite, are prepared by reacting an epoxy of the formula II or a phenylglycol of the formula III (II) (III) where Y and Z can be identical to or different from each other and are each hydroxyl, alkoxy, aryloxy or acyloxy, in the gas phase over a borosilicate zeolite catalyst at from 70 DEG to 200 DEG C. under reduced pressure.

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