HERBICIDE COMPOSITIONS CONTAINING AMIDES OF PYRAZOLO-3-CARBOXYLIC ACID AS ACTIVE COMPONENT AND PROCESS FOR PRODUCING THE ACTIVE COMPONENTS

    公开(公告)号:HUT55957A

    公开(公告)日:1991-07-29

    申请号:HU601290

    申请日:1990-09-21

    Applicant: BASF AG

    Abstract: Pyrazole-3-carboxamides of the general formula I in which the substituents have the following meanings: R represents hydrogen or optionally substituted C3-C8-cycloalkyl or C1-C4-alkyl, R represents hydroxyl; amino; C1-C4-alkylamino; di-C1-C4-alkylamino, aminocarbonyl-C1-C6-alkyl, optionally substituted C1-C4-alkoxy, C3-C6-alkenyl, C3-C6-alkynyl, phenyl or naphthyl, optionally substituted 5- to 6-membered heterocycle; one of the groups mentioned under R or R and R together form a 4- to 7-membered chain which can contain as ring member one of the following groups in addition to methylene groups: oxygen, sulphur, N-methyl or carbonyl; R represents optionally substituted 5- to 6-membered heterocycle, optionally substituted C3-C6-alkenyl, C3-C6-alkynyl, 5,6,7,8-tetrahydronaphthyl or phenyl, or one of the groups mentioned under R ; R represents nitro; cyano; carboxyl; halogen; optionally substituted C1-C4-alkoxy or C1-C4-alkylthio, or one of the groups mentioned under R ; R represents 4,5-dihydrooxazol-2-yl or a group COYR ; Y represents oxygen or sulphur; R represents hydrogen; C3-C8-cycloalkyl, optionally substituted C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, C5-C7-cycloalkenyl or phenyl, optionally substituted 5- to 6-membered heterocycle; phthalimido; tetrahydrophthalimido; succinimido; maleimido; benzotriazolyl or a group -N=CR R where R is hydrogen or C1-C6-alkyl and R is C3-C6-cycloalkyl, phenyl, furyl or a radical R , or R and R together form a 4- to 7-membered alkylene chain, and their agriculturally useful salts, where Y is not oxygen and R is not hydrogen when R is hydrogen and R is nitro, trifluoromethyl, halogen or C1-C4-alkoxy, and -YR is not ethoxy when R is hydrogen, R is methyl and R is phenyl or substituted phenyl.

    HERBICIDE PREPARATIONS CONTAINING PYRAZOLE-3-CARBONIC ACID-AMIDES AND PROCESS FOR THE PREPARATION OF THE ACTIVE AGENTS

    公开(公告)号:HU906012D0

    公开(公告)日:1991-03-28

    申请号:HU601290

    申请日:1990-09-21

    Applicant: BASF AG

    Abstract: Pyrazole-3-carboxamides of the general formula I in which the substituents have the following meanings: R represents hydrogen or optionally substituted C3-C8-cycloalkyl or C1-C4-alkyl, R represents hydroxyl; amino; C1-C4-alkylamino; di-C1-C4-alkylamino, aminocarbonyl-C1-C6-alkyl, optionally substituted C1-C4-alkoxy, C3-C6-alkenyl, C3-C6-alkynyl, phenyl or naphthyl, optionally substituted 5- to 6-membered heterocycle; one of the groups mentioned under R or R and R together form a 4- to 7-membered chain which can contain as ring member one of the following groups in addition to methylene groups: oxygen, sulphur, N-methyl or carbonyl; R represents optionally substituted 5- to 6-membered heterocycle, optionally substituted C3-C6-alkenyl, C3-C6-alkynyl, 5,6,7,8-tetrahydronaphthyl or phenyl, or one of the groups mentioned under R ; R represents nitro; cyano; carboxyl; halogen; optionally substituted C1-C4-alkoxy or C1-C4-alkylthio, or one of the groups mentioned under R ; R represents 4,5-dihydrooxazol-2-yl or a group COYR ; Y represents oxygen or sulphur; R represents hydrogen; C3-C8-cycloalkyl, optionally substituted C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, C5-C7-cycloalkenyl or phenyl, optionally substituted 5- to 6-membered heterocycle; phthalimido; tetrahydrophthalimido; succinimido; maleimido; benzotriazolyl or a group -N=CR R where R is hydrogen or C1-C6-alkyl and R is C3-C6-cycloalkyl, phenyl, furyl or a radical R , or R and R together form a 4- to 7-membered alkylene chain, and their agriculturally useful salts, where Y is not oxygen and R is not hydrogen when R is hydrogen and R is nitro, trifluoromethyl, halogen or C1-C4-alkoxy, and -YR is not ethoxy when R is hydrogen, R is methyl and R is phenyl or substituted phenyl.

    PROCESS FOR THE PREPARATION OF HERBICIDE PREPARATIONS CONTAINING CARBONIC ACID AMIDES AND PROCESS FOR THE PREPARATION OF THE ACTIVE AGENTS

    公开(公告)号:HU906009D0

    公开(公告)日:1991-03-28

    申请号:HU600990

    申请日:1990-09-21

    Applicant: BASF AG

    Abstract: Carboxamides Ia, Ib, Ic and Id (X is O or S; R is H, halogen, optionally substituted alkyl, optionally substituted benzyl, alkoxy, alkylthio, haloalkoxy, haloalkylthio, optionally substituted phenyl, optionally substituted phenoxy or phenylthio, an optionally substituted 5- or 6-membered heterocycle having up to 2 hetero atoms, cycloalkylalkyl, optionally substituted alkenyl which can be epoxidised, optionally substituted alkynyl, optionally substituted cycloalkyl or cycloalkenyl; R is cycloalkylalkyl, optionally substituted alkenyl which can be epoxidised, optionally substituted cycloalkenyl; R is CHO, 4,5-dihydrooxazol-2-yl, COYR , CONR R ; Y is O or S; R is H, optionally substituted alkyl, cycloalkyl, optionally substituted alkenyl, optionally substituted cycloalkenyl, optionally substituted alkynyl, optionally substituted phenyl, a 5- or 6-membered heterocycle having up to 3 hetero atoms, benzotriazole, N-phthalimido, tetrahydrophthalimido, succinimido, maleimido, 2,2-di-methyl- 1,3-dioxolan-4-ylmethyl, 1,3-dioxolan-2-on-4-ylmethyl, in the case where Y = O: an equivalent of a cation from the group of the alkali metals or alkaline earth metals, Mn, Cu, Fe, ammonium and substituted ammonium, a radical -N = CR R or -W-Z; R and R are H, optionally substituted alkyl, optionally substituted haloalkyl, cycloalkyl, alkoxy, furanyl, optionally substituted phenyl; R + R are a 4- to 7-membered methylene chain; W is an alkylene chain, ethoxyethylene chain, butenylene or butynylene chain; Z is a moiety bonded to W in the omega -position which represents the same moiety which is linked to W in the alpha -position of W; R is H, alkyl, cycloalkyl; R is H; alkyl; -C(O-alkyl)=N-H or -C(O-alkyl)=N-alkyl; R + R are a 4- to 5-membered methylene chain; R is H, optionally substituted alkyl, optionally substituted cycloalkyl; R is H, OH, alkoxy, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted alkenyl, optionally substituted alkynyl, di-(C1-C4)-alkylamino, an optionally substituted 5- to 6-membered heterocycle having up to 2 hetero atoms, optionally substituted phenyl, optionally substituted naphthyl; R3 + R4 are a 4- to 7-membered methylene chain which can be interrupted by O, S or N-CH3, or are -(CH2)3-CO-> and their environmentally compatible salts are suitable as herbicides.

    PROCEDIMIENTO PARA LA OBTENCION DE BENZOFENONAS.

    公开(公告)号:ES2271675T3

    公开(公告)日:2007-04-16

    申请号:ES03785691

    申请日:2003-12-01

    Applicant: BASF AG

    Abstract: Procedimiento para la obtención de benzofenonas de la fórmula I (Ver fórmula) en la que X puede significar cloro, hidroxi, metoxi o alquilcarboniloxi con 1 a 6 átomos de carbono e Y puede significar cloro o bromo, mediante reacción de un cloruro de ácido de la fórmula II (Ver fórmula) en la que X e Y tienen el significado anteriormente indicado, con 3, 4, 5-trimetoxitolueno, caracterizado porque la reacción se lleva a cabo en presencia de a) un hidrocarburo aromático elegido del grupo formado por: el clorobenceno, el trifluoruro de benceno y el nitrobenceno como diluyente y b) desde un 0, 01 hasta un 0, 2% en moles, referido al cloruro de ácido, de un catalizador de hierro, c) a una temperatura que está comprendida entre 60ºC y el punto de ebullición del diluyente correspondiente.

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