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公开(公告)号:PL362286A1
公开(公告)日:2004-10-18
申请号:PL36228601
申请日:2001-11-13
Applicant: BASF AG
Inventor: DISTELDORF WALTER , GOLFIER GUENTHER , MORSBACH BERND , SCHWIRTEN KURT
Abstract: A process is described for preparing esters of an acid component selected from among polybasic C 4 -C 10 carboxylic acids and an alcohol component selected from among C 3 -C 12 alkanols or from among C 3 -C 12 alkanediols, the alkyl chain of which may have interruption by from 1 to 3 oxygen atoms, by a) heating at boiling point, in a reaction zone and in the presence of an esterification catalyst, a mixture essentially consisting of the acid component or of an anhydride thereof and of the alcohol component, b) using rectification to separate the vapor comprising alcohol and water into an alcohol-rich fraction and a water-rich fraction, and c) returning the alcohol-rich fraction into the reaction zone and conducting the water-rich fraction out of the process. The process is simple to carry out and permits rapid achievement of essentially quantitative conversion.
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公开(公告)号:PL359527A1
公开(公告)日:2004-08-23
申请号:PL35952701
申请日:2001-07-04
Applicant: BASF AG
Inventor: BREITSCHEIDEL BORIS , SELBERDINGER RICHARD , ROSSATO KLAUS , STORZUM UWE , HOLZMANN JUERGEN , DISTELDORF WALTER , UEBLER CHRISTOPH , MORSBACH BERND , PETERS JARREN , GOLFIER GUENTER
IPC: C07B61/00 , C07C29/141 , C07C29/16 , C07C31/125 , C07C45/50 , C07C47/02 , C07C67/08 , C07C69/80 , C08K5/12 , C08L27/06
Abstract: A process is described for preparing mixtures of diesters of phthalic acid with decanols and tridecanols by reacting phthalic acid or a reactive derivative of phthalic acid with a mixture made from at least one decanol and at least one tridecanol. Mixtures obtainable in this way are also described, as is their use as plasticizers for molding compositions, and also mixtures of isomeric tridecanols suitable for preparing the mixtures of diesters.
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公开(公告)号:DE59510832D1
公开(公告)日:2003-12-24
申请号:DE59510832
申请日:1995-06-14
Applicant: DAIMLER CHRYSLER AG , BASF AG
Inventor: HARTWEG DR , HEINAU MARTINA , SEIBOLD ANDREA , WALZ DR , FETZER DR , MORSBACH BERND , BUECHELE DR
Abstract: A catalyst and a process for producing the catalyst are provided. For the catalytic reduction of NOx and for the oxidation of hydrocarbons, the catalyst contains a spinel containing the metals copper, zinc and aluminum.
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公开(公告)号:SI1233012T1
公开(公告)日:2003-10-31
申请号:SI200130020
申请日:2001-02-12
Applicant: BASF AG
Inventor: DISTELDORF WALTER DR , PETERS JARREN DR , MORSBACH BERND , KUMMER MATTHIAS DR , RUEHL THOMAS DR
IPC: B01D3/14 , C07C51/573 , C07C63/00 , C07C63/16
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公开(公告)号:BR0112172A
公开(公告)日:2003-05-06
申请号:BR0112172
申请日:2001-07-04
Applicant: BASF AG
Inventor: BREITSCHEIDEL BORIS , SELBERDINGER RICHARD , ROSSATO KLAUS , STORZUM UWE , HOLZMANN J RGEN , GOLFIER G NTHER , DISTELDORF WALTER , MORSBACH BERND , PETERS JARREN , BLER CHRISTOPH
IPC: C07B61/00 , C07C29/141 , C07C29/16 , C07C31/125 , C07C45/50 , C07C47/02 , C07C67/08 , C07C69/80 , C08K5/12 , C08L27/06
Abstract: A process is described for preparing mixtures of diesters of phthalic acid with decanols and tridecanols by reacting phthalic acid or a reactive derivative of phthalic acid with a mixture made from at least one decanol and at least one tridecanol. Mixtures obtainable in this way are also described, as is their use as plasticizers for molding compositions, and also mixtures of isomeric tridecanols suitable for preparing the mixtures of diesters.
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公开(公告)号:DE10056179A1
公开(公告)日:2002-05-29
申请号:DE10056179
申请日:2000-11-13
Applicant: BASF AG
Inventor: DISTELDORF WALTER , GOLFIER GUENTHER , MORSBACH BERND , SCHWIRTEN KURT
Abstract: The invention relates to a method for producing esters of an acid component chosen from the multibasic C4-C10-carboxylic acids and an alcohol component chosen from C3-C12-alkanols or -alkanediols whose alkyl chain can be interrupted by 1 to 3 oxygen atoms. Sad method comprises the following steps: a) a mixture consisting essentially of the acid component or an anhydride thereof and the alcohol component is heated to boiling in a reaction zone in the presence of an esterification catalyst; b) the vapours containing alcohol and water are separated into a fragment that is rich in alcohol and a fragment that is rich in water by rectification; and c) the alcohol-rich fraction is fed back into the reaction zone, while the water-rich fraction is extracted from the process. The inventive method is simple to carry out and allows the rapid adjustment of an essentially quantitative conversion.
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公开(公告)号:AU1829802A
公开(公告)日:2002-05-21
申请号:AU1829802
申请日:2001-11-13
Applicant: BASF AG
Inventor: DISTELDORF WALTER , GOLFIER GUNTHER , MORSBACH BERND , SCHWIRTEN KURT
Abstract: A process is described for preparing esters of an acid component selected from among polybasic C 4 -C 10 carboxylic acids and an alcohol component selected from among C 3 -C 12 alkanols or from among C 3 -C 12 alkanediols, the alkyl chain of which may have interruption by from 1 to 3 oxygen atoms, by a) heating at boiling point, in a reaction zone and in the presence of an esterification catalyst, a mixture essentially consisting of the acid component or of an anhydride thereof and of the alcohol component, b) using rectification to separate the vapor comprising alcohol and water into an alcohol-rich fraction and a water-rich fraction, and c) returning the alcohol-rich fraction into the reaction zone and conducting the water-rich fraction out of the process. The process is simple to carry out and permits rapid achievement of essentially quantitative conversion.
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公开(公告)号:ES2164480T3
公开(公告)日:2002-02-16
申请号:ES99125759
申请日:1999-12-23
Applicant: BASF AG
Inventor: HOLZMANN JURGEN , BREITSCHEIDEL BORIS DR , DISTELDORF WALTER DR , HALLER CHRISTIANE , MORSBACH BERND
Abstract: Polyester is produced by reaction of an aliphatic dicarboxylic acid, neopentyl glycol, at least one other diol, and a nonanol mixture comprising mainly 1-nonanol, monomethyloctanols, dimethylheptanols and monoethylheptanols. An Independent claim is also included for the nonanol mixture.
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公开(公告)号:BR9917230A
公开(公告)日:2002-01-08
申请号:BR9917230
申请日:1999-11-26
Applicant: BASF AG
Inventor: THIL LUCIEN , BREITSCHEIDEL BORIS , DISTELDORF WALTER , ZELLER EDGAR , WALTER MARC , MORSBACH BERND , DORNIK KNUT
IPC: C07B61/00 , C07C29/14 , C07C31/125 , C07C67/08 , C07C69/44 , C07C69/80 , C08K5/05 , C08K5/10 , C08K5/11 , C08K5/12 , C08L27/06
Abstract: The mixture described is a mixture of isomeric nonanol diesters of a dicarboxylic acid, selected from the class consisting of a mixture of diesters of adipic acid in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.0 to 2.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.0 ppm with respect to TMS is from 1.20 to 5.00 and a mixture of diesters of phthalic acid, in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.1 to 3.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.1 ppm with respect to TMS is from 1.00 to 4.00.The diesters of adipic and phthalic acid are suitable as plasticizers for PVC-based molding compositions and have high compatibility, a low cold crack temperature, low torsional rigidity and/or high thermal stability.
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60.
公开(公告)号:AU5787701A
公开(公告)日:2001-07-09
申请号:AU5787701
申请日:2000-12-12
Applicant: BASF AG
Inventor: HOLZMANN JURGEN , BREITSCHEIDEL BORIS , DISTELDORF WALTER , HALLER CHRISTIANE , MORSBACH BERND
Abstract: Polyester is produced by reaction of an aliphatic dicarboxylic acid, neopentyl glycol, at least one other diol, and a nonanol mixture comprising mainly 1-nonanol, monomethyloctanols, dimethylheptanols and monoethylheptanols. An Independent claim is also included for the nonanol mixture.
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