公开(公告)号：DE102004027793A1

公开(公告)日：2006-01-05

申请号：DE102004027793

申请日：2004-06-08

Applicant: BASF AG

Inventor： FECHTENKOETTER ANDREAS ,  DUETTRA BERND ,  DORNIK KNUT

IPC: B01J20/28 ,  C08F8/00 ,  C08F210/02 ,  C08F220/00 ,  C09D11/02 ,  C09D123/08

Abstract: Ethylene copolymers (ECP) with at least one comonomer unit containing a photochemically-activatable group (PAG). Independent claims are also included for (1) a method (M1) for the production of ECP by polymerisation of (a) ethylene with (b) comonomer(s) containing PAG and (c) unsaturated carboxylic acid(s) or ester(s) at 170-300[deg]C and 500-4000 bar (2) a method (M2) for the production of ECP by polymerising (a) with (c) as above and then reacting the polymer with a compound of formula H-(X)n-(A)m-P* (IV) (3) materials (MECP) made from ECP for separating substances (4) a method (M3) for the production of MECP by exposing ECP to actinic radiation (5) a method (M4) for separating substances using MECP (6) a method (M4) for the production of lacquers, printing ink and toners by using ECP (7) micronised ECP with a number-average particle diameter of not more than 30 microns (8) lacquers, printing ink and toners containing or made from ECP (9) a method (M5) for printing substrates using such lacquers, ink and toners (10) printed substrates obtained by M5 .

公开(公告)号：BR9917230A

公开(公告)日：2002-01-08

申请号：BR9917230

申请日：1999-11-26

Applicant: BASF AG

Inventor： THIL LUCIEN ,  BREITSCHEIDEL BORIS ,  DISTELDORF WALTER ,  ZELLER EDGAR ,  WALTER MARC ,  MORSBACH BERND ,  DORNIK KNUT

IPC: C07B61/00 ,  C07C29/14 ,  C07C31/125 ,  C07C67/08 ,  C07C69/44 ,  C07C69/80 ,  C08K5/05 ,  C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  C08L27/06

Abstract: The mixture described is a mixture of isomeric nonanol diesters of a dicarboxylic acid, selected from the class consisting of a mixture of diesters of adipic acid in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.0 to 2.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.0 ppm with respect to TMS is from 1.20 to 5.00 and a mixture of diesters of phthalic acid, in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.1 to 3.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.1 ppm with respect to TMS is from 1.00 to 4.00.The diesters of adipic and phthalic acid are suitable as plasticizers for PVC-based molding compositions and have high compatibility, a low cold crack temperature, low torsional rigidity and/or high thermal stability.

公开(公告)号：CA2367358A1

公开(公告)日：2000-10-26

申请号：CA2367358

申请日：1999-11-26

Applicant: BASF AG

Inventor： DORNIK KNUT ,  MORSBACH BERND ,  THIL LUCIEN ,  BREITSCHEIDEL BORIS ,  WALTER MARC ,  ZELLER EDGAR ,  DISTELDORF WALTER

IPC: C07B61/00 ,  C07C29/14 ,  C07C31/125 ,  C07C67/08 ,  C07C69/44 ,  C07C69/80 ,  C08K5/05 ,  C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  C08L27/06

Abstract: The invention relates to a mixture of diesters of a dicarboxylic acid and isomeric nonanols. Said mixture is selected among a mixture of adipic acid diesters in whose 1H-NMR spectrum, obtained in CDCl3, the ratio of the surfa ce area below the resonance signals in case of chemical shifts of between 1.0 a nd 2.0 ppm towards TMS to the surface area below the resonance signals in case of chemical shifts of between 0.5 and 1.0 ppm towards TMS is between 1.20 and 5.00. Alternatively said mixture is selected among a mixture of phthalic aci d diesters in whose 1H-NMR spectrum, obtained in CDCl3, the ratio of the surfa ce area below the resonance signals in case of chemical shifts of between 1.1 a nd 3.0 ppm towards TMS to the surface area below the resonance signals in case of chemical shifts of between 0.5 and 1.1 ppm towards TMS is between 1.00 and 4.00. The above adipic and phthalic acid diesters are suitable for use as softeners for moulding materials on a PVC basis and characterized by high compatibility, low brittleness temperature, low stiffness in torsion and/or high thermal stability.

公开(公告)号：MY129459A

公开(公告)日：2007-04-30

申请号：MYPI20000391

申请日：2000-02-03

Applicant: BASF AG

Inventor： THIL LUCIEN DR ,  BREITSCHEIDEL BORIS DR ,  DISTELDORF WALTER DR ,  ZELLER EDGAR DR ,  WALTER MARC DR ,  MORSBACH BERND ,  DORNIK KNUT

IPC: C07C69/76 ,  C07B61/00 ,  C07C29/14 ,  C07C31/125 ,  C07C67/08 ,  C07C69/44 ,  C07C69/80 ,  C08K5/05 ,  C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  C08L27/06

Abstract: THE MIXTURE DESCRIBED IS A MIXTURE OF ISOMERIC NONANOL DIESTERS OF A DICARBOXYLIC ACID, SELECTED FROM THE CLASS CONSISTING OF A MIXTURE OF DIESTERS OF ADIPIC ACID IN THE 1H NMR SPECTRUM OF WHICH, OBSERVED IN CDC13, THE RATIO OF THE AREA UNDER THE RESONANCE SIGNALS AT CHEMICAL SHIFTS IN THE RANGE FROM 1.0 TO 2.0 PPM WITH RESPECT TO TMS TO THE AREA UNDER THE RESONANCE SIGNALS AT CHEMICAL SHIFTS IN THE RANGE FROM 0.5 TO 1.0 PPM WITH RESPECT TO TMS IS FROM 1.20 TO 5.00 AND A MIXTURE OF DIESTERS OF PHTHALIC ACID, IN THE 1H NMR SPECTRUM OF WHICH, OBSERVED IN CDC13, THE RATIO OF THE AREA UNDER THE RESONANCE SIGNALS AT CHEMICAL SHIFTS IN THE RANGE FROM 1.1 TO 3.0 PPM WITH RESPECT TO TMS TO THE AREA UNDER THE RESONANCE SIGNALS AT CHEMICAL SHIFTS IN THE RANGE FROM 0.5 TO 1.1 PPM WITH RESPECT TO TMS IS FROM 1.00 TO 4.00.THE DIESTERS OF ADIPIC AND PHTHALIC ACID ARE SUITABLE AS PLASTICIZERS FOR PVC-BASED MOLDING COMPOSITIONS AND HAVE HIGH COMPATIBILITY, A LOW COLD CRACK TEMPERATURE, LOW TORSIONAL RIGIDITY AND/OR HIGH THERMAL STABILITY.

公开(公告)号：AU1387200A

公开(公告)日：2000-11-02

申请号：AU1387200

申请日：1999-11-26

Applicant: BASF AG

Inventor： THIL LUCIEN ,  BREITSCHEIDEL BORIS ,  DISTELDORF WALTER ,  ZELLER EDGAR ,  WALTER MARC ,  MORSBACH BERND ,  DORNIK KNUT

IPC: C07B61/00 ,  C07C29/14 ,  C07C31/125 ,  C07C67/08 ,  C07C69/44 ,  C07C69/80 ,  C08K5/05 ,  C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  C08L27/06

Abstract: The mixture described is a mixture of isomeric nonanol diesters of a dicarboxylic acid, selected from the class consisting of a mixture of diesters of adipic acid in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.0 to 2.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.0 ppm with respect to TMS is from 1.20 to 5.00 and a mixture of diesters of phthalic acid, in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.1 to 3.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.1 ppm with respect to TMS is from 1.00 to 4.00.The diesters of adipic and phthalic acid are suitable as plasticizers for PVC-based molding compositions and have high compatibility, a low cold crack temperature, low torsional rigidity and/or high thermal stability.

公开(公告)号：CA2367358C

公开(公告)日：2010-02-02

申请号：CA2367358

申请日：1999-11-26

Applicant: BASF AG

Inventor： WALTER MARC ,  MORSBACH BERND ,  ZELLER EDGAR ,  THIL LUCIEN ,  DORNIK KNUT ,  DISTELDORF WALTER ,  BREITSCHEIDEL BORIS

IPC: C07C69/44 ,  C07B61/00 ,  C07C29/14 ,  C07C31/125 ,  C07C67/08 ,  C07C69/80 ,  C08K5/05 ,  C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  C08L27/06

Abstract: The invention relates to a mixture of diesters of a dicarboxylic acid and isomeric nonanols. Said mixture is selected among a mixture of adipic acid diesters in whose 1H-NMR spectrum, obtained in CDCl3, the rat io of the surface area below the resonance signals in case of chemical shifts of between 1.0 and 2.0 ppm towards TMS to the surface are a below the resonance signals in case of chemical shifts of between 0.5 and 1.0 ppm towards TMS is between 1.20 and 5.00. Alternatively said mixture is selected among a mixture of phthalic acid diesters in whose 1H-NMR spectrum, obtained in CDCl3, the ratio of the surfa ce area below the resonance signals in case of chemical shifts of between 1.1 and 3.0 ppm towards TMS to the surface area below the resonan ce signals in case of chemical shifts of between 0.5 and 1.1 ppm towards TMS is between 1.00 and 4.00. The above adipic and phthalic acid diesters are suitable for use as softeners for moulding materials on a PVC basis and characterized by high compatibility, low brittleness temperature, low stiffness in torsion and/or high thermal stability.

公开(公告)号：DE59908919D1

公开(公告)日：2004-04-22

申请号：DE59908919

申请日：1999-11-26

Applicant: BASF AG

Inventor： THIL LUCIEN ,  BREITSCHEIDEL BORIS ,  DISTELDORF WALTER ,  ZELLER EDGAR ,  WALTER MARC ,  MORSBACH BERND ,  DORNIK KNUT

IPC: C07B61/00 ,  C07C29/14 ,  C07C31/125 ,  C07C67/08 ,  C07C69/44 ,  C07C69/80 ,  C08K5/05 ,  C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  C08L27/06

Abstract: The mixture described is a mixture of isomeric nonanol diesters of a dicarboxylic acid, selected from the class consisting of a mixture of diesters of adipic acid in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.0 to 2.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.0 ppm with respect to TMS is from 1.20 to 5.00 and a mixture of diesters of phthalic acid, in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.1 to 3.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.1 ppm with respect to TMS is from 1.00 to 4.00.The diesters of adipic and phthalic acid are suitable as plasticizers for PVC-based molding compositions and have high compatibility, a low cold crack temperature, low torsional rigidity and/or high thermal stability.

公开(公告)号：DE19924339A1

公开(公告)日：2000-11-30

申请号：DE19924339

申请日：1999-05-27

Applicant: BASF AG

Inventor： THIL LUCIEN ,  BREITSCHEIDEL BORIS ,  DISTELDORF WALTER ,  DORNIK KNUT ,  MORSBACH BERND

IPC: C07C67/08 ,  C07C69/44 ,  C07C69/80 ,  C08K5/11 ,  C07C29/141 ,  C07C45/50

Abstract: New mixtures (I) of dicarboxylic acid diesters with isomeric nonanols consist of adipate or phthalate diester mixtures having 1H-NMR spectra (obtained in CDCl3) with specific ratios of surface areas below the resonance signals for particular chemical shifts towards TMS. The ratio of the surface area for shifts of 1.0-2.0 ppm to that for shifts of 0.5-1.0 ppm is 1.20-5.00 for the adipate diesters; and the ratio of the surface area for shifts of 1.1-3.0 ppm to that for shifts of 0.5-1.1 ppm is 1.00-4.00 for the phthalate diesters; An Independent claim is included for mixtures (II) of isomeric nonanols which either: (i) form (I) as defined above on esterification with adipic or phthalic acid; or (ii) are obtained by hydroformylation of a mixture of isomeric octenes in presence of a cobalt catalyst and hydrogenation of the product, where the isomeric octene mixture is obtained by contacting a hydrocarbon mixture containing butenes with a heterogeneous catalyst containing a nickel oxide.

公开(公告)号：AU778207B2

公开(公告)日：2004-11-25

申请号：AU1387200

申请日：1999-11-26

Applicant: BASF AG

Inventor： THIL LUCIEN ,  BREITSCHEIDEL BORIS ,  DISTELDORF WALTER ,  ZELLER EDGAR ,  WALTER MARC ,  MORSBACH BERND ,  DORNIK KNUT

IPC: C07B61/00 ,  C07C29/14 ,  C07C31/125 ,  C07C67/08 ,  C07C69/44 ,  C07C69/80 ,  C08K5/05 ,  C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  C08L27/06

Abstract: The mixture described is a mixture of isomeric nonanol diesters of a dicarboxylic acid, selected from the class consisting of a mixture of diesters of adipic acid in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.0 to 2.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.0 ppm with respect to TMS is from 1.20 to 5.00 and a mixture of diesters of phthalic acid, in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.1 to 3.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.1 ppm with respect to TMS is from 1.00 to 4.00.The diesters of adipic and phthalic acid are suitable as plasticizers for PVC-based molding compositions and have high compatibility, a low cold crack temperature, low torsional rigidity and/or high thermal stability.

公开(公告)号：DK1171413T3

公开(公告)日：2004-07-19

申请号：DK99973824

申请日：1999-11-26

Applicant: BASF AG

Inventor： THIL LUCIEN ,  BREITSCHEIDEL BORIS ,  DISTELDORF WALTER ,  ZELLER EDGAR ,  WALTER MARC ,  MORSBACH BERND ,  DORNIK KNUT

IPC: C07B61/00 ,  C07C29/14 ,  C07C31/125 ,  C07C67/08 ,  C07C69/44 ,  C07C69/80 ,  C08K5/05 ,  C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  C08L27/06

Abstract: The mixture described is a mixture of isomeric nonanol diesters of a dicarboxylic acid, selected from the class consisting of a mixture of diesters of adipic acid in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.0 to 2.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.0 ppm with respect to TMS is from 1.20 to 5.00 and a mixture of diesters of phthalic acid, in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.1 to 3.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.1 ppm with respect to TMS is from 1.00 to 4.00.The diesters of adipic and phthalic acid are suitable as plasticizers for PVC-based molding compositions and have high compatibility, a low cold crack temperature, low torsional rigidity and/or high thermal stability.