METHOD FOR PRODUCING N-PHOSPHONOMETHYLGLYCINE.

    公开(公告)号:MX234329B

    公开(公告)日:2006-02-13

    申请号:MXPA03011229

    申请日:2002-06-21

    Applicant: BASF AG

    Abstract: The present invention relates to a process for the recovery of N-phosphonomethylglycine from an aqueous mixture which contains N-phosphonomethylglycine, ammonium halides, and alkali metal or alkaline earth metal halides and optionally organic impurities in dissolved form, where (a) the pH of the mixture is adjusted to a value in the range from 2 to 8, (b) a separation of the mixture on a selective nanofiltration membrane is performed, a retentate which is richer in N-phosphonomethylglycine and poorer in halides and a permeate which is richer in halides and poorer in N-phosphonomethylglycine being obtained, and (c) the N-phosphonomethylglycine is recovered from the retentate. The process according to the invention makes possible the recovery of the N-phosphonomethylglycine with simultaneous separation of the halide salts.

    PROCEDIMIENTO PARA LA OBTENCION DE N-FOSFONOMETILGLICINA.

    公开(公告)号:ES2240779T3

    公开(公告)日:2005-10-16

    申请号:ES02754733

    申请日:2002-06-21

    Applicant: BASF AG

    Abstract: Procedimiento para la obtención de N- fosfonometilglicina, en el que: a) se hace reaccionar un derivado de hexahidrotriazina de la fórmula II en la que X significa CN, COOZ, CONR1R2 o CH2OY, Y significa H, un resto acilo alifático o aromático o un grupo alquilo con 1 hasta 6 átomos de carbono; Z significa H, un metal alcalino, un metal alcalinotérreo, alquilo con 1 hasta 18 átomos de carbono o arilo, que está substituido, en caso dado, por alquilo con 1 hasta 4 átomos de carbono, por NO2 o por O-alquilo con 1 hasta 4 átomos de carbono; R1 y R2, que pueden ser iguales o diferentes, significan H o alquilo con 1 hasta 4 átomos de carbono, con un fosfito de triacilo de la fórmula III P(OCOR3)3 (III) en la que los restos R3, que pueden ser iguales o diferentes, significan alquilo con 1 hasta 18 átomos de carbono o arilo, que está substituido, en caso dado, por alquilo con 1 hasta 4 átomos de carbono, por NO2 o por O-alquilo con 1 hasta 4 átomos de carbono, en un disolvente orgánico, b) la mezcla de la reacción obtenida se extrae con agua o con una solución acuosa de un ácido o con una solución acuosa de una base, c) se separan las fases y d) se hidroliza el producto contenido en la fase.

    57.
    发明专利
    未知

    公开(公告)号:BR0314399A

    公开(公告)日:2005-07-19

    申请号:BR0314399

    申请日:2003-04-25

    Applicant: BASF AG

    Abstract: Composition (A) contains at least one alkoxylated 6-18C alkanol (I). Composition (A) contains at least one alkoxylated 6-18C alkanol of formula RO-(A)n-(B)m-H (I). R = 6-18C linear or branched alkyl; A = propyleneoxy (PO); B = ethyleneoxy (EO) or a mixture of EO and PO; n = integer or fractional number of 0-5; and m = integer or fractional number of 0-20. When R is C5H11CH(C3H7)CH2-, n is less than 1, provided that R is a mixture where 70-99 %, by weight of C5H11 is linear and 1-30 %, by weight is EtCH(Me)CH2 and/or MeCH(Me)CH-2CH2. An Independent claim is also included for a method for preparing (I) by reacting ROH with propylene and ethylene oxides.

    58.
    发明专利
    未知

    公开(公告)号:AT293118T

    公开(公告)日:2005-04-15

    申请号:AT02754733

    申请日:2002-06-21

    Applicant: BASF AG

    Abstract: The invention relates to a process for preparing N-phosphono-methylglycine by reacting a hexahydrotriazine compound with a triacyl phosphite in an organic solvent, hydrolyzing the resulting phosphono compound after prior extraction into an aqueous phase and separation from the organic phase. The process avoids decomposition of the organic solvent during hydrolysis.

    Preparation of N-phosphonomethylglycine

    公开(公告)号:NZ530026A

    公开(公告)日:2004-07-30

    申请号:NZ53002602

    申请日:2002-06-21

    Applicant: BASF AG

    Abstract: A method is disclosed for producing N-phosphonomethylglycine by reacting a hexahydrotriazine compound with a triacyl phosphite in an organic solvent and the saponification of the phosphono compound that is obtained after previous extraction into an aqueous phase, and separation of the organic phase. This method prevents decomposition of the organic solvent during saponification.

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