SOLIDOTHERMAL SYNTHESIS OF A BORON-CONTAINING ZEOLITE WITH AN MWW FRAMEWORK STRUCTURE
    51.
    发明申请
    SOLIDOTHERMAL SYNTHESIS OF A BORON-CONTAINING ZEOLITE WITH AN MWW FRAMEWORK STRUCTURE 审中-公开
    含MWW框架结构的含硼沸石的固体合成

    公开(公告)号:WO2018046481A1

    公开(公告)日:2018-03-15

    申请号:PCT/EP2017/072200

    申请日:2017-09-05

    Applicant: BASF SE

    Abstract: The present invention relates to a process for the production of a zeolitic material having an MWW framework structure comprising YO 2 and B 2 O 3 , wherein Y stands for a tetravalent ele- ment, said process comprising (i) preparing a mixture comprising one or more sources for YO 2 , one or more sources for B 2 O 3 , one or more organotemplates, and seed crystals, (ii) crystallizing the mixture obtained in (i) for obtaining a layered precursor of the MWW framework structure, (iii) calcining the layered precursor obtained in (ii) for obtaining the zeolitic material having an MWW framework structure, wherein the one or more organotemplates have the formula (I) R 1 R 2 R 3 N, wherein R 1 is (C 5 -C 8 )cycloalkyl, and wherein R 2 and R 3 are independently from each other H or alkyl, and wherein the mixture prepared in (i) and crystallized in (ii) contains 35 wt.-% or less of H 2 O based on 100 wt.-% of YO 2 contained in the mixture prepared in (i) and crystallized in (ii), as well as to a synthetic boron-containing zeolite which is obtainable and/or obtained according to the inventive process and to its use.

    Abstract translation: 本发明涉及生产具有包含YO 2和B 2 O 的MWW骨架结构的沸石材料的方法, 其中Y代表四价元素,所述方法包括(i)制备包含一种或多种YO 2来源的混合物,一种或多种来源于B (ii)使(i)中获得的混合物结晶以获得MWW骨架结构的分层前体,(iii) 煅烧(ii)中获得的层状前体以获得具有MWW骨架结构的沸石材料,其中所述一种或多种有机模板具有式(I)R 1 R 2 2, R 3 N,其中R 1是(C 5 -C 8)环烷基,并且其中R

    A PROCESS FOR PREPARING ETHENE OXIDE
    52.
    发明申请
    A PROCESS FOR PREPARING ETHENE OXIDE 审中-公开
    一种制备乙烯氧化物的方法

    公开(公告)号:WO2018011280A1

    公开(公告)日:2018-01-18

    申请号:PCT/EP2017/067576

    申请日:2017-07-12

    Applicant: BASF SE

    Abstract: A process for preparing ethene oxide comprising providing a liquid feed stream comprising ethene, hydrogen peroxide, and a solvent; passing the liquid feed stream into an epoxidation zone comprising a catalyst comprising a titanium zeolite comprising zinc and having framework type MWW, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation zone, obtaining a reaction mixture comprising ethene oxide, water, and the solvent; removing an effluent stream from the epoxidation zone, the effluent stream comprising ethene oxide, water and the solvent.

    Abstract translation: 一种制备氧化乙烯的方法,包括提供包含乙烯,过氧化氢和溶剂的液体进料物流; 使液体进料流进入包含催化剂的环氧化区,所述催化剂包含含锌沸石并具有骨架类型MWW,并使液体进料流在环氧化区中经受环氧化反应条件,获得包含氧化乙烯,水和 溶剂; 从环氧化区中除去流出物流,所述流出物流包含氧化乙烯,水和溶剂。

    VEHICLE COMPRISING AN INTERNAL COMBUSTION ENGINE, AT LEAST ONE STORAGE VESSEL AND A COOLING CHAMBER AND OPTIONALLY AN AIR CONDITION UNIT
    54.
    发明申请
    VEHICLE COMPRISING AN INTERNAL COMBUSTION ENGINE, AT LEAST ONE STORAGE VESSEL AND A COOLING CHAMBER AND OPTIONALLY AN AIR CONDITION UNIT 审中-公开
    包含内燃机的车辆,至少一个存储船和冷却室以及可选的空调机组

    公开(公告)号:WO2016180807A1

    公开(公告)日:2016-11-17

    申请号:PCT/EP2016/060389

    申请日:2016-05-10

    Applicant: BASF SE

    CPC classification number: F17C11/00 F17C11/005 F17C11/007

    Abstract: The invention is related to a vehicle (2) comprising an internal combustion engine (8), at least one storage vessel (1) and a cooling chamber (10) and optionally an air condition unit (12), wherein a sorption medium is disposed in the at least one storage vessel (1) and the at least one storage vessel (1) contains a fuel for the internal combustion engine (8), the combustion engine (8) and the at least one storage vessel (1) are connected by a pipe (14) for conducting the fuel, and the at least one storage vessel (1) is thermally coupled with the cooling chamber (10) and optionally the air condition unit (12). The invention is further related to a process for operation of said vehicle.

    Abstract translation: 本发明涉及一种包括内燃机(8),至少一个存储容器(1)和冷却室(10)以及任选的空调单元(12)的车辆(2),其中设置吸附介质 在所述至少一个存储容器(1)和所述至少一个存储容器(1)中包含用于所述内燃机(8)的燃料,所述内燃机(8)和所述至少一个存储容器(1)被连接 通过用于传导燃料的管道(14),并且所述至少一个储存容器(1)与冷却室(10)和任选的空调单元(12)热耦合。 本发明还涉及所述车辆的操作过程。

    A PROCESS FOR PREPARING PROPYLENE OXIDE
    56.
    发明申请
    A PROCESS FOR PREPARING PROPYLENE OXIDE 审中-公开
    一种制备丙烯氧化物的方法

    公开(公告)号:WO2015010991A1

    公开(公告)日:2015-01-29

    申请号:PCT/EP2014/065244

    申请日:2014-07-16

    Abstract: A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, optionally propane, and at least one dissolved potassium salt of a phosphorus oxyacid wherein the molar ratio of potassium relative to phosphorus in the at least one potassium salt of a phosphorus oxyacid is in the range of from 0.6 to 1.4; (ii) passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MVVW comprising zinc, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane; (iii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane.

    Abstract translation: 一种用于制备环氧丙烷的连续方法,包括(i)提供包含丙烯,过氧化氢,乙腈,水,任选的丙烷和至少一种溶解的含磷酸钾的液体进料流,其中钾相对的摩尔比 在磷氧基酸的至少一种钾盐中的磷在0.6至1.4的范围内; (ii)将(i)中提供的液体进料流送入包含催化剂的环氧化反应器中,所述催化剂包含含锌的结构型MVVW的钛沸石,并使液体进料流在环氧化反应器中进行环氧化反应条件,得到反应混合物 包括环氧丙烷,乙腈,水,所述至少一种溶解的含磷酸的钾盐,任选的丙烯,以及任选的丙烷; (iii)从环氧化反应器中除去流出物流,所述流出物流包含环氧丙烷,乙腈,水,所述至少一种溶解的含磷酸的钾盐,任选的丙烯和任选的丙烷的至少一部分。

    ORGANOTEMPLATE-FREE SYNTHETIC PROCESS FOR THE PRODUCTION OF A ZEOLITIC MATERIAL OF THE CHA-TYPE STRUCTURE
    60.
    发明申请
    ORGANOTEMPLATE-FREE SYNTHETIC PROCESS FOR THE PRODUCTION OF A ZEOLITIC MATERIAL OF THE CHA-TYPE STRUCTURE 审中-公开
    用于生产CHA型结构的ZEOLITIC材料的无机合成方法

    公开(公告)号:WO2013068976A1

    公开(公告)日:2013-05-16

    申请号:PCT/IB2012/056292

    申请日:2012-11-09

    CPC classification number: B01J29/7015 B01J2229/186 C01B39/46

    Abstract: The present invention relates to an organotemplate-free synthetic process for the production of a zeoiitic material having a CHA-type framework structure comprising YO2, X 2 O 3 , and optionally comprising Z 2 O 5 , wherein said process comprises the steps of: (1 ) providing a mixture comprising one or more sources for YO 2 , one or more sources for X 2 O 3 , and seed crystals having a CHA framework structure, wherein the CHA framework structure of the seed crystals comprises YO 2 , X 2 O 3 , and optionally comprises Z2O5; and (2) crystallizing the mixture obtained in step (1 ); wherein Y is a tetravaient element, X is a trivalent element, and Z is a pentavalent element, wherein optionally one or more sources for Z 2 O 5 are further provided in step (1 ), and wherein if the CHA framework of the seed crystals does not contain Z 2 O 5 , the seed crystals then have a Y0 2 : X 2 O 3 molar ratio of 5 or greater than 5.

    Abstract translation: 本发明涉及一种用于生产具有包含YO 2,X 2 O 3和任选地包含Z 2 O 5的CHA型骨架结构的氧化锌材料的无有机模板的合成方法,其中所述方法包括以下步骤:(1)提供包含 YO2的一种或多种来源,X 2 O 3的一种或多种来源和具有CHA骨架结构的晶种,其中晶种的CHA骨架结构包含YO 2,X 2 O 3,并且任选包含Z 2 O 5; 和(2)使步骤(1)中获得的混合物结晶; 其中Y是四元素,X是三价元素,Z是五价元素,其中任选地在步骤(1)中还提供一种或多种Z2O5源,并且其中如果晶种的CHA骨架不包含 Z2O5,然后晶种的Y02:X2O3摩尔比为5或大于5。

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