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公开(公告)号:AU2017216082B2
公开(公告)日:2020-12-03
申请号:AU2017216082
申请日:2017-01-25
Applicant: BASF SE
Inventor: KLAUBER ERIC GEORGE , RACK MICHAEL , SOERGEL SEBASTIAN , GOCKEL BIRGIT , GOETZ ROLAND
IPC: C07D231/14 , C07C251/72
Abstract: The present invention relates to a catalytic process for preparing pyrazoles comprising the step of cyclizing hydrazone substituted α,β-unsaturated carbonyl compounds by reacting them with hydrogen in a reaction mixture comprising as components (a) a hydrogenation catalyst, (b) an acid selected from Brønsted acids, ammonium salts of Brønsted acids, and Lewis acids, (c) a protic solvent, and optionally (d) an aprotic solvent.
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公开(公告)号:ES2795874T3
公开(公告)日:2020-11-25
申请号:ES17701485
申请日:2017-01-25
Applicant: BASF SE
Inventor: KLAUBER ERIC GEORGE , RACK MICHAEL , SOERGEL SEBASTIAN , GOCKEL BIRGIT , GOETZ ROLAND
IPC: C07D231/14 , C07C251/72
Abstract: Un proceso para preparar un compuesto de pirazol de formula V, o una sal, estereoisomero, tautomero o N-oxido del mismo **(Ver fórmula)** que comprende la etapa de ciclar un compuesto de carbonilo α,β-insaturado sustituido por hidrazona de formula IV **(Ver fórmula)** haciendolo reaccionar con hidrogeno, en donde el compuesto de formula IV se proporciona en una mezcla de reaccion que comprende como componentes: (a) un catalizador de hidrogenacion; (b) un acido seleccionado entre acidos de Bronsted, sales de amonio de acidos de Bronsted y acidos de Lewis; (c) un disolvente protico; y, opcionalmente (d) un disolvente aprotico; y en donde R1 es C(O)ORc, en donde Rc es alquilo C1-C4 o bencilo; R2 es CH3, o fluorometilo; R3 es H; R4 se selecciona entre alquilo C1-C4, grupo que no esta sustituido, o esta parcialmente halogenado, y R5 se selecciona entre alquilo C1-C4.
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公开(公告)号:PL3300602T3
公开(公告)日:2020-08-24
申请号:PL17193945
申请日:2013-06-12
Applicant: BASF SE
Inventor: SOERGEL SEBASTIAN , SAELINGER DANIEL , DEFIEBER CHRISTIAN , LANGEWALD JÜRGEN , GOCKEL BIRGIT , HADEN EGON , CULBERTSON DEBORAH , GUNJIMA KOSHI
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公开(公告)号:UA121395C2
公开(公告)日:2020-05-25
申请号:UAA201701767
申请日:2015-07-30
Applicant: BASF SE
Inventor: GOCKEL BIRGIT , SAELINGER DANIEL , SOERGEL SEBASTIAN , RACK MICHAEL
Abstract: Винахідстосуєтьсяспособуодержанняпіразольноїсполукиформули V, якийвключаєциклізаціюгідразонзаміщеноїα,β-ненасиченоїкарбонільноїсполукиформули IV задопомогоюїїреакціїз придатнимреагентом, наприклад, відновником, металоорганічнимреагентомабонуклеофільнимреагентом, причомусполукиформули V єуніверсальнимиреакційнимиінструментамидляодержанняречовинтонкогоорганічногосинтезу - піразольнихпохідних.
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公开(公告)号:AU2016218096B2
公开(公告)日:2020-02-20
申请号:AU2016218096
申请日:2016-02-03
Applicant: BASF SE
Inventor: WILHELM RONALD , MAZUIR FLORENT , SOERGEL SEBASTIAN
IPC: A01N43/58 , A01N37/46 , A01N43/713 , A01N43/80 , A01N43/82 , A01N43/90 , A01P3/00 , A01P5/00 , A01P7/00
Abstract: The present invention relates to the use of a pesticidal mixture PM comprising at least one compound of formula I as defined in the specification, an insecticide II and a fungicide III for protecting plants selected from wheat, maize, barley, oat, rye, rice, soybean, cotton, sugarbeet, rapeseed, and potato, the plant propagation material thereof, or soil or water, in which the plants are growing, against the attack or infestation by invertebrate pests and/or phytopathogenic harmful fungi. Furthermore, the present invention relates to a seed treatment composition comprising the pesticidal mixture PM and to seeds comprising the pesticidal mixture PM or the seed treatment composition thereof. Moreover, the present invention relates to a method for controlling invertebrate pests and/or phytopathogenic harmful fungi on plants selected from wheat, maize, barley, oat, rye, rice, soybean, cotton, sugarbeet, rapeseed, and potato comprising contacting the plant or the plant propagation material; the pest or its food supply, habitat or breeding ground; and/or the fungi or their habitat, with an effective amount of the pesticidal mixture PM or the seed treatment composition thereof. In a further aspect, the present invention relates to binary mixtures of a compound of formula I and tioxazafen, tetraniliprole, broflanilide, cyhalodiamide, fluazaindolizine, and fluxametamide, resp.
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公开(公告)号:AU2015295287B2
公开(公告)日:2019-07-04
申请号:AU2015295287
申请日:2015-07-30
Applicant: BASF SE
Inventor: GOCKEL BIRGIT , SAELINGER DANIEL , SOERGEL SEBASTIAN , RACK MICHAEL
IPC: C07D231/14 , C07D405/06
Abstract: The present invention relates to a process for preparing a pyrazole compound of formula V, which comprises cyclizing a hydrazone substituted α,β-unsaturated carbonyl compound of formula IV by reacting it with a suitable reagent, e.g. a reducing agent, an organometallic reagent or a nucleophilic reagent. The compounds of formula V are versatile reaction tools for the preparation of pyrazole derived fine chemicals. The present invention also relates to pyrazole compounds of formulae Va, Vb, Vc, and VI.
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公开(公告)号:CO2018008428A2
公开(公告)日:2018-08-21
申请号:CO2018008428
申请日:2018-08-10
Applicant: BASF SE
Inventor: KLAUBER ERIC GEORGE , RACK MICHAEL , SOERGEL SEBASTIAN , GOCKEL BIRGIT , GOETZ ROLAND
IPC: C07D231/14 , C07C251/72
Abstract: RESUMEN La presente invención se refiere a un proceso catalítico para preparar pirazoles que comprende la etapa de ciclar compuestos de carbonilo α,β-insaturados sustituidos por hidrazona mediante su reacción con hidrógeno en una mezcla de reacción que comprende como componentes (a) un catalizador de hidrogenación, (b) un ácido seleccionado de ácidos de Brønsted, sales de amonio de ácidos de Brønsted y ácidos de Lewis, (c) un solvente prótico y opcionalmente (d) un solvente aprótico.
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公开(公告)号:AU2017216082A1
公开(公告)日:2018-07-26
申请号:AU2017216082
申请日:2017-01-25
Applicant: BASF SE
Inventor: KLAUBER ERIC GEORGE , RACK MICHAEL , SOERGEL SEBASTIAN , GOCKEL BIRGIT , GOETZ ROLAND
IPC: C07D231/14 , C07C251/72
Abstract: The present invention relates to a catalytic process for preparing pyrazoles comprising the step of cyclizing hydrazone substituted α,β-unsaturated carbonyl compounds by reacting them with hydrogen in a reaction mixture comprising as components (a) a hydrogenation catalyst, (b) an acid selected from Brønsted acids, ammonium salts of Brønsted acids, and Lewis acids, (c) a protic solvent, and optionally (d) an aprotic solvent.
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公开(公告)号:CA2736538C
公开(公告)日:2018-02-20
申请号:CA2736538
申请日:2009-09-23
Applicant: BASF SE
Inventor: GROSS STEFFEN , KOERBER KARSTEN , VON DEYN WOLFGANG , KAISER FLORIAN , DESHMUKH PRASHANT , DICKHAUT JOACHIM , LE VEZOUET RONAN , SOERGEL SEBASTIAN , POHLMAN MATTHIAS , ANSPAUGH DOUGLAS D , CULBERTSON DEBORAH L , OLOUMI SADEGHI HASSAN
IPC: C07D403/12 , A01N43/56
Abstract: The present invention relates to pyrazole compounds of formulae I or I1 and the salts and N-oxides thereof, formulae (I), (II), wherein A is a pyrazole radical of formulae A1, A2 or A3, wherein formulae (A1), (A2), (A3), # denotes the binding site; R41, R42, R43, R51 are H, halogen, CN, NO2, C1-C10-alkyl and the like; R52 , R53 are H, halogen, CN, NO2, C1-C10-alkyl, and the like; R61, R62, R63 are H, CN, NO2, C1-C10-alkyl, and the like; T is C(R t) or N; U is C(R u) or N; V is C(R v) or N; W is C(R w) or N; with the proviso that at least one of the groups T, U, V and W is N; R t, R u, R v, R w are H, halogen, C1-C4-alkyl and the like; X1 is S, O or NR1a, wherein R1a is selected H, C1-C10-alkyl and the like; X2 is OR2a, NR2b R2c, S(O)m R2d, wherein m is 0, 1 or 2, R2a is C1-C4-alkyl, C1-C4-haloalkyl and the like, R2b, R2c are H, C1-C4-alkyl, C1-C4-haloalkyl and the like, or R2b and R2c together with the nitrogen atom to which they are bound form a heterocycle, and R2d is C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl and the like; and R1 is H, CN, C1-C10-alkyl and the like. The present invention further relates to a method for controlling invertebrate pests, to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material, comprising at least one compound according to the present invention, to a method for treating or protecting an animal from infestation or infection by parasites and to an agricultural composition containing at least one compound according to the present invention.
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公开(公告)号:AU2015295287A1
公开(公告)日:2017-02-16
申请号:AU2015295287
申请日:2015-07-30
Applicant: BASF SE
Inventor: GOCKEL BIRGIT , SAELINGER DANIEL , SOERGEL SEBASTIAN , RACK MICHAEL
IPC: C07D231/14 , C07D405/06
Abstract: The present invention relates to a process for preparing a pyrazole compound of formula V, which comprises cyclizing a hydrazone substituted α,β-unsaturated carbonyl compound of formula IV by reacting it with a suitable reagent, e.g. a reducing agent, an organometallic reagent or a nucleophilic reagent. The compounds of formula V are versatile reaction tools for the preparation of pyrazole derived fine chemicals. The present invention also relates to pyrazole compounds of formulae Va, Vb, Vc, and VI.
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