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公开(公告)号:PT91648A
公开(公告)日:1990-03-30
申请号:PT9164889
申请日:1989-09-07
Applicant: CIBA GEIGY AG
Inventor: HUBELE ADOLF , ZONDLER HELMUT
IPC: A01N43/54 , C07D239/30 , C07D239/34 , C07D239/38 , C07D239/42 , C07D401/00 , C07D401/12 , C07D403/00 , C07D403/12 , C07D405/00 , C07D405/12 , C07D409/00 , C07D409/12 , C07D239/00
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公开(公告)号:ZA891767B
公开(公告)日:1989-11-29
申请号:ZA891767
申请日:1989-03-08
Applicant: CIBA GEIGY AG
Inventor: ZONDLER HELMUT , HELMUT ZONDLER , MEYER ALFRED , ALFRED MEYER , ECKHARDT WOLFGANG , WOLFGANG ECKHARDT , KUNZ WALTER , WALTER KUNZ
IPC: A01N43/40 , A01N43/50 , A01N43/54 , A01N43/58 , A01N43/60 , A01N43/653 , C07D213/81 , C07D401/06 , C07D401/12 , C07D401/14 , C07D413/14 , C07D , A01N
Abstract: Novel substituted isonicotinic acid amides of the general formula in which X in ortho/ortho'-position are equal and represent fluorine, chlorine, bromine or iodine; Q1 is unsubstituted pyridimin-4-yl, or pyrimidin-4-yl substituted by R1, R2 and R3; Q2 is unsubstituted pyrimidin-2-yl, or pyrimidin-2-yl substituted by R1, R2 and R3; Q3 is unsubstituted pyrimidin-5-yl, or pyrimidin-5-yl substituted by R1, R2 and R3; Q4 is pyridin-2-yl, pyridin-3-yl or pyridin-4-yl each of which is unsubstituted or substituted by R1, R2 and R3; Q5 is pyridazin-3-yl or pyridazin-4-yl each of which is unsubstituted or substituted by R1, R2 and R3; Q6 is unsubstituted pyrazin-2-yl, or pyrazin-2-yl substituted by R1, R2 and R3; R1, R2, R3 are hydrogen, halogen, C1-C6alkyl, C1-C6haloalkyl having from 1 to 3 halogen atoms, C1-C6alkoxy, C2-C6alkoxyalkyl, C1-C6thioalkyl, C1-C6haloalkoxy having from 1 to 5 halogen atoms, C3-C6alkenyloxy, C3-C6alkynyloxy, C3-C6thioalkenyl, C3-C6cycloalkyl, C3-C6cycloalkyl substituted by methyl, or nitro, cyano, the radical CH(OR4)2 or COOR4 in which R4 is C1-C4alkyl; also phenyl, phenoxy, thiophenyl, benzyl, benzyloxy or thiobenzyl; or phenyl, phenoxy, thiophenyl, benzyl, benzyloxy or thiobenzyl each substituted at least once by C1-C3alkyl, C1-C3-alkoxy, C1-C3haloalkyl having from 1 to 3 halogen atoms, halogen, nitro or by cyano; and also N(R5)R6 in which R5 and R6, independently of one another, are each C1-C6alkyl; and furthermore piperidinyl, pyrrolidinyl, morpholinyl, imidazolyl or triazolyl, or piperidinyl, pyrrolidinyl, morpholinyl, imidazolyl or triazolyl each substituted by C1-C3alkyl, C1-C3alkoxy, C1-C3haloalkyl having from 1 to 3 halogen atoms, halogen, nitro or by cyano. The novel active ingredients have plant-protecting properties and are suitable especially for the preventive protection of plants against attack by phytopathogenic microorganisms such as fungi, bacteria and viruses.
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公开(公告)号:ZA8902214B
公开(公告)日:1989-11-29
申请号:ZA8902214
申请日:1989-03-23
Applicant: CIBA GEIGY AG
Inventor: ZONDLER HELMUT , HELMUT ZONDLER , KUNZ WALTER , WALTER KUNZ
IPC: C07D249/08 , A01N43/40 , A01N43/50 , A01N43/653 , C07D213/79 , C07D233/54 , C07D401/12 , C07D405/12 , C07D409/12 , C07D521/00 , C07D , A01N
CPC classification number: C07D213/79 , A01N43/40 , A01N43/50 , A01N43/653 , C07D231/12 , C07D233/56 , C07D249/08 , C07D405/12 , C07D409/12
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公开(公告)号:ZA8901767B
公开(公告)日:1989-11-29
申请号:ZA8901767
申请日:1989-03-08
Applicant: CIBA GEIGY AG
Inventor: ZONDLER HELMUT , HELMUT ZONDLER , MEYER ALFRED , ALFRED MEYER , ECKHARDT WOLFGANG , WOLFGANG ECKHARDT , KUNZ WALTER , WALTER KUNZ
IPC: A01N43/40 , A01N43/50 , A01N43/54 , A01N43/58 , A01N43/60 , A01N43/653 , C07D213/81 , C07D401/06 , C07D401/12 , C07D401/14 , C07D413/14 , C07D , A01N
CPC classification number: C07D213/81 , A01N43/40 , A01N43/50 , A01N43/54 , A01N43/58 , A01N43/60 , A01N43/653 , C07D401/06 , C07D401/12 , C07D401/14
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55.
公开(公告)号:CA1254560A
公开(公告)日:1989-05-23
申请号:CA461860
申请日:1984-08-27
Applicant: CIBA GEIGY AG
Inventor: HUBELE ADOLF , ECKHARDT WOLFGANG , STURM ELMAR , ZONDLER HELMUT
IPC: A01N43/54 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/48 , C07D239/50 , C07D239/52 , C07D239/56 , C07D401/12 , C07D405/12 , C07D239/28 , C07D401/04
Abstract: Novel N-(2-nitrophenyl)-4-aminopyrimidine derivatives of the general formula I (I) wherein R1 is NO2 or CF3, R2 is NO2 or CF3, R3 is hydrogen or halogen, R4 is hydrogen or the -C(O)R7 group, in which R7 is an unsubstituted or substituted radical selected from the group consisting of C1-C12alkyl, C2-C6alkenyl, C3-C7cyclo-alkyl, phenyl and heterocyclyl, R5, R6 and R7 are each independently halogen, cyano, thiocyano, nitro or a group selected from -N(R9)(R10), -R11, R12-O- or R13-S(O)n, in which R9 and R10 are each independently hydrogen or an unsubstituted or substituted radical selected from the group consisting of C1-C12alkyl, C3-C6alkenyl and phenyl, or together with the nitrogen atom form an unsubstituted or substituted heterocyclic ring, n is 0, 1 or 2, R11, R12 and R13 are each independently an unsubstituted or substituted radical selected from the group consisting of C1-C12 alkyl, C2-C6alkenyl, C3-C6cycloalkyl, phenyl or heterocyclyl; and in addition R5 can be hydrogen, R6 can be hydrogen, or two of R5, R6 and R8 may be hydrogen. Methods of preparing these compounds are disclosed, as are also agrochemical compositions which contain one of said compounds active ingredient. The use of the novel compounds and the compositions containing them in agriculture are also described. The novel compounds or the compositions containing them are used for the control of harmful micro-organisms.
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公开(公告)号:PH21689A
公开(公告)日:1988-01-13
申请号:PH32813
申请日:1985-09-19
Applicant: CIBA GEIGY AG
Inventor: ZONDLER HELMUT , NYFELER ROBERT , ECKHARDT WOLFGANG
IPC: A01N43/54 , C07D239/42 , C07D405/12 , C07D403/12 , C07D413/12 , C07D417/12 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/72 , A01N43/76 , A01N43/78 , A01N43/80 , A01N43/84 , A01N43/86
Abstract: There are described novel, microbicidally active 5-(arylmethylimino)-pyrimidines of the formula I (I) wherein Rn-A- is an unsubstituted or substituted phenyl, naphthyl, biphenyl, phenoxyphenyl or phenylthiophenyl, and R1 is an ether, thioether or amino function, these substances being produced according to the invention by substitution of the halogen atom in the claimed intermediates of the formula II (II) The use of these substances in plant protection, and also further important intermediates, are likewise described.
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公开(公告)号:GB2179659A
公开(公告)日:1987-03-11
申请号:GB8622763
申请日:1986-09-22
Applicant: CIBA GEIGY AG
Inventor: NYFELER ROBERT , ZONDLER HELMUT , STURM ELMAR
IPC: A01N31/04 , A01N31/14 , A01N43/64 , C07D249/08 , A01N43/653 , B01J27/10 , B01J31/10 , B01J31/22 , C07B61/00 , C07C20060101 , C07C33/20 , C07C41/00 , C07C41/03 , C07C43/13 , C07C43/178 , C07C43/23 , C07C43/295 , C07C43/315 , C07C67/00 , C07C201/00 , C07C201/12 , C07C205/34 , C07C253/00 , C07C253/30 , C07C255/54 , C07D253/00 , C07D521/00 , C07C33/025
Abstract: New glycol monoethers have the formula I: in which R1 is C1-C6-alkyl which is substituted by C1-C6-alkoxy or C3-C6-cycloalkyl, C3-C8-cycloalkyl, phenyl, phenyl which is monosubstituted to trisubstituted by halogen, C1-C6-halogenoalkyl, C1-C6-halogenoalkoxy, C1-C6-alkoxy, C1-C6-alkyl, nitro and/or cyano, phenyl which is substituted by phenoxy, halogenophenoxy, phenyl, halogenophenyl, benzyl or halogenobenzyl, benzyl or benzyl which is monosubstituted to trisubstituted by halogen, C1-C6-halogenoalkyl, C1-C6-halogenoalkoxy, C1-C6-alkoxy, C1-C6-alkyl, nitro and/or cyano; R2 is C1-C12-alkyl or a radical indicated under R1; and R3 is C1-C6-alkyl, C1-C6-alkyl which is substituted by C1-C3-alkoxy, C3-C4-alkenyl, benzyl or halogenobenzyl. Process for producing the new ethers is also described. The ethers are useful e.g. as intermediates for 1-triazolylethyl ethers having value as agrochemically active materials.
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公开(公告)号:CA1218370A
公开(公告)日:1987-02-24
申请号:CA459440
申请日:1984-07-23
Applicant: CIBA GEIGY AG
Inventor: ZONDLER HELMUT , HUBELE ADOLF , NYFELER ROBERT
IPC: A01N43/54 , C07D239/28 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/48 , C07D239/50 , C07D239/52 , C07D239/56 , C07D239/58 , C07D239/60
Abstract: N-(2-Nitrophenyl)-5-aminopyrimidine derivatives, the preparation and use thereof The invention discloses novel N-(2-nitrophenyl)-5-aminopyrimidine derivatives of the general formula (I) wherein R1 and R2 are each independently NO2 or CF3, or one of R1 and R2 is hydrogen, R3 is hydrogen or halogen, R4 is hydrogen or the -C(O)R' group, in which R' is C1-C4alkyl which is unsubstituted or substituted by halogen, C1-C3alkoxy or C1-C3alkylthio, R5,R6 and R7 are each independently hydrogen, halogen, nitro, cyano, ehiocyano, mercapto, C1-C6alkyl, C1-C6haloalkyl,C1-C6alkoxy, C1-C6alkoxy which is substituted by halogen, nitro, cyano, C1-C3alk-oxy, C1-C3alkylthio and/or N(C1-C4alkyl)2; or are C3-C6cycloalkoxy, C3-C6alkenyloxy, C3-C6alkynyloxy, C1-C6alkylthio, C3-C6alkenylthio, C1-C6alkylsulfonyl, C1-C6alkylsulfoxyl, C3-C6alkenyl, C3-C6haloalk-enyl, C3-C6alkynyl, C3-C6haloalkynyl or the N(C1-C4alkyl)2 group, and R5 may additionally be a phenyl or benzyl group which is unsubstituted or substituted by one to three identical or different members selected from halogen, nitro, cyano, C1-C4alkyl, C1-C3halo-alkyl N-(C1-C3alkyl)2, and/or C1-C3 alkoxy. The preparation of these compounds and their use in agriculture are also disclosed.
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公开(公告)号:DD242956A5
公开(公告)日:1987-02-18
申请号:DD28074985
申请日:1985-09-18
Applicant: CIBA GEIGY AG
Inventor: ZONDLER HELMUT , ECKHARDT WOLFGANG , NYFELER ROBERT
IPC: A01N43/54 , A01N20060101 , A01N37/34 , C07D20060101 , C07D211/00 , C07D239/00 , C07D239/42 , C07D401/12
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公开(公告)号:CS247200B2
公开(公告)日:1986-12-18
申请号:CS578285
申请日:1985-08-08
Applicant: CIBA GEIGY AG
Inventor: NYFELER ROBERT , ZONDLER HELMUT , STURM ELMER
IPC: C07D249/08 , A01N31/04 , A01N31/14 , A01N43/64 , A01N43/653 , B01J27/10 , B01J31/10 , B01J31/22 , C07B61/00 , C07C20060101 , C07C33/20 , C07C41/00 , C07C41/03 , C07C43/13 , C07C43/178 , C07C43/23 , C07C43/295 , C07C43/315 , C07C67/00 , C07C201/00 , C07C201/12 , C07C205/34 , C07C253/00 , C07C253/30 , C07C255/54 , C07D253/00 , C07D521/00
Abstract: Essentially, a process is described for the preparation of the 1-triazolylethyl ether derivatives, defined in claim 1, of the general formula I (I) which consists in (a) reacting an oxirane of the formula II (II) at temperatures of -20 DEG to +100 DEG C., in the presence of an acid catalyst or an acid condensation agent, with an alcohol of the formula III R3-OH (III) to give a glycol monoether of the formula IV (IV) and (b) subsequently reacting the glycol monoether of the formula IV or one of its esters, in the presence of an acid-binding agent or condensation agent, at temperatures of 0 DEG to 150 DEG C., with a triazole of the formula V (V) the substituents R1, R2 ; amd R3 in the formula II to IV being as defined under formula I and M in formula V being hydrogen or a metal atom. The novel compounds within the scope of formula I and their use are also described.
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