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公开(公告)号:JPH02265738A
公开(公告)日:1990-10-30
申请号:JP8936689
申请日:1989-04-06
Applicant: TORAY INDUSTRIES
Inventor: TANAKA YOSHIO , OKA TETSUO
Abstract: PURPOSE:To obtain a transparent gas barrier film with few pinholes, being capable of decreasing electric conductivity and with excellent gas barrier characteristics for steam, oxygen, etc., by constituting a gas barrier layer of the transparent gas barrier film of an oxide layer of a metal consisting of In and/or Sn and incorporating a specified fluorine in said oxide layer. CONSTITUTION:A gas barrier layer 2 is laminated on one face of a base consisting of a plastic film 1 such as polyethylene and polyester. This gas barrier layer is a metal oxide of a single metal such as In or Sn or an alloy thereof and this oxide layer is bound with 0.05-1 atom of fluorine to an atom of the metal. Surface electric resistance can be made higher with this fluorine without spoiling gas barrier characteristics. In addition, if necessary, a thermoplastic adhesive layer 3 is laminated on one face of the transparent gas barrier film. The gas barrier layer 2 is formed by means of a vacuum thin film forming method such as sputtering. A package film for food packagings, drugs, electronic parts, etc., for moisture proofing an oxidation-proofing can be obtd. thereby.
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公开(公告)号:JPH01152054A
公开(公告)日:1989-06-14
申请号:JP31162687
申请日:1987-12-09
Applicant: TORAY INDUSTRIES
Inventor: WATANABE YUJI , HAYASHI KENJI , TANAKA YOSHIO
Abstract: PURPOSE:To obtain transparency and extremely high gas barrier properties, by providing at least two metallic oxide layer each of which comprises a metal selected from the group consisting of In, Sn, Zn, Zr and Ti and has a specified thickness, on one side of a plastic film. CONSTITUTION:A layer of a metallic oxide comprising at least one metal selected from the group consisting of In, Sn, Zn, Zr and Ti is provided on at least one side of a plastic film base. The metallic oxide layer may be provided by vacuum deposition, ion plating, sputtering or the like. Among others, a sputtering method is most preferred from the viewpoint of control of the film thickness and composition of the metallic oxide, in the case where at least two metallic oxide layers are provided, with a thickness of 5-200Angstrom as a unit of one layer. The number of the metallic oxide layers provided in a laminate form is appropriately selected in consideration the required gas barrier properties and economy. The transparent gas-barrier film thus obtained is used preferably after being laminated with a heat-sealable thermoplastic adhesive layer.
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公开(公告)号:JPS63237940A
公开(公告)日:1988-10-04
申请号:JP7154587
申请日:1987-03-27
Applicant: TORAY INDUSTRIES
Inventor: HAYASHI KENJI , WATANABE YUJI , TANAKA YOSHIO
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公开(公告)号:JP2003227928A
公开(公告)日:2003-08-15
申请号:JP2002025327
申请日:2002-02-01
Applicant: TORAY INDUSTRIES
Inventor: TANAKA YOSHIO , TSUNASHIMA KENJI , NAKAJIMA YUICHI
IPC: G02B5/30 , G02F1/1335
Abstract: PROBLEM TO BE SOLVED: To provide a polarizing plate which has a protective sheet of a polarizer exhibiting excellent mechanical and environmental characteristics without making the characteristics of the PVA (polyvinyl alcohol) polarizer degenerate for a long period of time. SOLUTION: The polarizing plate comprises a polarizer P having protective sheets A each of which is composed of a base layer B and a hot melt adhesive layer C laminated on both surfaces thereof. The base layers B and the polarizer P are stuck together via the hot melt adhesive layers C so as to form the laminated sheet. COPYRIGHT: (C)2003,JPO
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公开(公告)号:JP2002090515A
公开(公告)日:2002-03-27
申请号:JP2001211323
申请日:2001-07-11
Applicant: TORAY INDUSTRIES
Inventor: MIMURA TAKASHI , TANAKA YOSHIO , OWATARI HISASHI
Abstract: PROBLEM TO BE SOLVED: To provide a reflecting member for a surface light source showing only a small deterioration of luminance with the lapse of time even in long-time use and capable of holding high image quality over a long period of time. SOLUTION: A coating layer containing a light stabilizer is disposed on at least one face of a while film containing air bubbles to obtain the objective white film for the reflecting member of a surface light source.
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公开(公告)号:JP2001246687A
公开(公告)日:2001-09-11
申请号:JP2000058351
申请日:2000-03-03
Applicant: TORAY INDUSTRIES
Inventor: TANAKA YOSHIO , MIMURA TAKASHI
IPC: C08J7/04 , B32B7/02 , B32B27/18 , B32B27/30 , C08F220/34
Abstract: PROBLEM TO BE SOLVED: To provide a laminate film for a photo-catalyst coating which shows excellence in weather resistance, transparence and adhesion. SOLUTION: A laminate film for a photo-catalyst coating has an ultraviolet ray absorbing layer of a thickness of not less than 0.5 μm to not more than 10 μm laminated at least on one side of a thermoplastic film, wherein an acrylic resin copolymerized with a benzotriazole-based ultraviolet ray absorbing monomer is preferably employed as the ultraviolet ray absorbing layer.
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公开(公告)号:JP2001239740A
公开(公告)日:2001-09-04
申请号:JP2000056930
申请日:2000-03-02
Applicant: TORAY INDUSTRIES
Inventor: TANAKA YOSHIO , MIMURA TAKASHI
Abstract: PROBLEM TO BE SOLVED: To provide an offset printing film excellent in printing sharpness, ink setting properties, color developability, ink adhesion and further transparency. SOLUTION: This offset printing film is produced by providing an ink fixing layer mainly consisting of a styrene-butadiene copolymer and deformed particles on at least one side of a thermoplastic film. As the styrene-butadiene copolymer, a soap-free latex is preferably employed.
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公开(公告)号:JPH09239921A
公开(公告)日:1997-09-16
申请号:JP5582596
申请日:1996-03-13
Applicant: TORAY INDUSTRIES
Inventor: MIMURA TAKASHI , TANAKA YOSHIO
Abstract: PROBLEM TO BE SOLVED: To obtain a laminated film having excellent weatherability, excellent transparency, flaw resistance, and stain resistance by adding an ultraviolet absorbing substance in surface hardening layer of the laminated film and specifying a ratio between fluorine atoms and carbon atoms in the surface of the surface hardening layer. SOLUTION: In a laminated film, a surface hardening layer having a pencil hardness H or above is provided on at least one face of a thermoplastic film. The surface hardening layer contains an ultraviolet absorbing substance. Also, a ration between fluorine atoms and carbon atoms in the surface hardening layer by X-ray optoelectronic spectroscopic method is 0.2 or higher. The surface hardening layer having the pencil hardness H or above has a layer having acrylic, urethane, melamine, organic silicate, and silicone resin as a main component on a base material thermoplastic film. Particularly, the acrylic resin is preferable in terms of processability, hardness, and durability. Above all, an activating ray curing acrylic is preferable.
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公开(公告)号:JPH09183199A
公开(公告)日:1997-07-15
申请号:JP34411895
申请日:1995-12-28
Applicant: TORAY INDUSTRIES
Inventor: TANAKA YOSHIO , MIMURA TAKASHI
Abstract: PROBLEM TO BE SOLVED: To improve the weatherability, the tranparency, the anti-blocking property, and the antifouling property by laminating a layer consisting of a benzotriazole based monomer copolymerized acryl resin, silicone and/or a wax, on a thermoplastic film. SOLUTION: This film is constituted by laminating a layer consisting of a benzotriazole based monomer copolymerized acryl resin, silicone and/or a wax, on a thermoplastic film. The contact angle of the water drop when purified water is dripped on the surface of this film is measured, and that the contact angle between the laminated film surface and the water is 70 deg. or higher is preferable. Also, using a polyester film as the thermoplastic film, is preferable. The laminated film being constituted in such a manner can be stably used for outdoor applications for a long period of time because of the excellent weatherability, compared with general synthetic resin films.
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公开(公告)号:JPH08142250A
公开(公告)日:1996-06-04
申请号:JP28956394
申请日:1994-11-24
Applicant: TORAY INDUSTRIES
Inventor: NAGAI ITSUO , TANAKA YOSHIO , UEDA TOMOAKI
Abstract: PURPOSE: To reduce deterioration of gas barrier performance due to post- processing, in a gas barrier film consisting of a plastic film and an aluminum oxide thin film formed at its single surface, by taking the thickness and refractive index of the aluminum oxide thin film as particular values. CONSTITUTION: This gas barrier film is provided with an aluminum oxide thin film formed on at least the single surface of a plastic film consisting of a polypropylene film or a polyethylene terephthalate film by means of a physical deposition method or a chemical deposition method. The thickness of the aluminum oxide thin film is 8-50nm. The film thickness smaller than 8nm will not meet the gas barrier performance, while the film thickness larger than 50nm will generate a curling, and degrade the gas barrier performance rapidly at the time of processing. The refractive index of the aluminum oxide thin film is 1.70-1.90. The refractive index of not more than 1.70 makes the aluminum oxide thin film porous to be insufficient in gas barrier performance, while the refractive index of not less than 1.90 makes it difficult to ensure transparency.
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