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公开(公告)号：DE102004017151A1
公开(公告)日：2005-10-27
申请号：DE102004017151
申请日：2004-04-07
Applicant: BASF AG
Inventor： OLBERT GERHARD , HECHLER CLAUS
Abstract: Reactor comprises square heat transfer sheet modules which form a slit which can be filled with a heterogeneous particulate catalyst and through which the reaction mixture flows, a sleeve which depressurizes the heat transfer sheet modules and fully surrounds the modules, and sealing elements. The fluid reaction mixture flows only through the slit, except through the reaction interior spaces. Reactor comprises square heat transfer sheet modules (1) comprising two or more right-angled heat transfer sheets (2) parallel to each other, to form a slit (3) which can be filled with a heterogeneous particulate catalyst and through which the reaction mixture flows, a sleeve which depressurizes the heat transfer sheet modules and fully surrounds the modules, and sealing elements (7) arranged so that the fluid reaction mixture flows only through the slit, except through the reaction interior spaces, defined by the caps. The sleeve comprises a cylinder casing (4) and caps (15, 16) to close the casing at both ends.
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公开(公告)号：DE10316039A1
公开(公告)日：2004-10-21
申请号：DE10316039
申请日：2003-04-07
Applicant: BASF AG
Inventor： SCHINDLER GOETZ-PETER , MACHHAMMER OTTO , MUELLER-ENGEL KLAUS JOACHIM , HECHLER CLAUS , PETZOLDT JOCHEN , ADAMI CHRISTOPH , HARTH KLAUS
IPC: B01J23/62 , B01J23/63 , C07C45/33 , C07C45/34 , C07C45/35 , C07C51/25 , C07C253/26 , C07C255/08 , C07B35/04
Abstract: Preparation of at least one partial oxidation and/or ammoxidation product of a hydrocarbon involves partially dehydrogenating at least one saturated hydrocarbon under heterogeneous catalysis and using the resulting product gas mixture for heterogeneously catalyzed partial oxidation and/or ammoxidation of the partially dehydrogenated hydrocarbon present in the product gas mixture. Preparation of at least one partial oxidation and/or ammoxidation product of a hydrocarbon involves: (a) dehydrogenating a saturated hydrocarbon (preferably propane or isobutene) using a heterogeneous catalyst in the gas phase to form a product gas mixture, comprising one or more partially dehydrogenated hydrocarbon, leaving constituents present in the product gas mixture, other than the saturated hydrocarbon and the partially dehydrogenated hydrocarbon; or partly or fully removing them to obtain a product gas mixture; and (b) partial oxidizing and/or ammoxidizing the product gas mixtures using one or more heterogeneous catalyst. The method includes at least one mechanical separation operation so that solid particles present in the gas mixtures can be removed.
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63.发明专利
公开(公告)号：AU2003277867A8
公开(公告)日：2004-04-23
申请号：AU2003277867
申请日：2003-09-18
Applicant: BASF AG
Inventor： PETZOLDT JOCHEN , MULLER-ENGEL KLAUS JOACHIM , MACHHAMMER OTTO , SCHINDLER GOTZ-PETER , MARTAN HANS , HECHLER CLAUS , ADAMI CHRISTOPH
IPC: B01J23/00 , B01J23/887 , C07C5/32 , C07C5/48 , C07C7/05 , C07C11/06 , C07C27/00 , C07C45/35 , C07C51/215 , C07C51/25 , C07C235/24 , C07C253/24 , C07C253/26 , C07C255/08 , C07D301/10
Abstract: In a process for preparing at least one partial oxidation and/or ammoxidation product of propylene, the propylene is obtained from crude propane by dehydrogenating and subjected in the presence of unconverted propane as a constituent of a gas mixture 2 which comprises a total C 4 -hydrocarbon content of
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公开(公告)号：AU2003224144A1
公开(公告)日：2003-11-11
申请号：AU2003224144
申请日：2003-05-06
Applicant: BASF AG
Inventor： MACHHAMMER OTTO , ZEHNER PETER , HECHLER CLAUS , SCHLIEPHAKE VOLKER , THIEL JOACHIM , ADAMI CHRISTOPH , BOHLING RALF
IPC: C07C51/25 , C07C51/36 , C07C51/44 , C07C67/303 , C07C57/07 , C07C53/122 , C07C57/05 , C07C67/08 , C07C69/24 , C07C69/54
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公开(公告)号：BR0111702A
公开(公告)日：2003-10-07
申请号：BR0111702
申请日：2001-06-13
Applicant: BASF AG
Inventor： MACHHAMMER OTTO , ADAMI CHRISTOPH , HECHLER CLAUS , ZEHNER PETER
IPC: C07C27/14 , B01J23/00 , B01J23/28 , B01J23/31 , B01J23/34 , B01J23/652 , B01J23/656 , B01J23/88 , B01J27/057 , B01J37/02 , C07B61/00 , C07C5/333 , C07C5/48 , C07C7/11 , C07C11/06 , C07C27/00 , C07C45/33 , C07C45/35 , C07C47/22 , C07C51/215 , C07C51/25 , C07C57/04 , C07C57/05 , C07C57/07
Abstract: Acrolein and acrylic acid are produced from propane and propene by absorption/desorption of propane and propene from a gas mixture followed by oxidation, in which no heterogeneously catalyzed dehydrogenation of propane occurs between the desorption and oxidation stages without addition of oxygen. Acrolein and acrylic acid are produced from propane and propene by: (a) separation of propane and propene from a gas mixture (A) by absorption in an absorption medium; (b) separation of propane and propene from the absorbent to give a mixture (B) containing propane and propene; and (c) using mixture (B) for oxidation to the required product(s). In this process, no catalytic dehydrogenation of propane without the addition of oxygen is carried out between stages (b) and (c).
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Patent Agency Ranking
公开(公告)号：DE19955168A1
公开(公告)日：2001-05-17
申请号：DE19955168
申请日：1999-11-16
Applicant: BASF AG
Inventor： TENTEN ANDREAS , HIBST HARTMUT , MACHHAMMER OTTO , HECHLER CLAUS , MUELLER-ENGEL KLAUS JOACHIM , UNVERRICHT SIGNE
IPC: C07C51/215 , C07B61/00 , C07C51/25 , C07C57/04 , C07C57/05
Abstract: The invention relates to a method for carrying out the two-stage catalytic gas phase oxidation of propene to form acrylic acid. The inventive method provides that, in a multitube fixed-bed reactor, the reaction gas starting mixture having a propene load >/= 160 Nl propene / l.h is firstly conducted over a fixed-bed catalyst feed material (1), which is located in two successive temperature zones A, B, and afterwards, is conducted over a fixed-bed catalyst feed material (2), which is accommodated either in another temperature zone C or in two additional temperature zones D, E. The temperature of zone A is maintained at a lower temperature than that of zone B, and the temperature of zone D is maintained at a lower temperature than that of zone E.
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公开(公告)号：BRPI0417856B1
公开(公告)日：2015-03-17
申请号：BRPI0417856
申请日：2004-12-21
Applicant: BASF AG
Inventor： OLBERT GERHARD , HECHLER CLAUS , LÖWEN DIETMAR
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公开(公告)号：CA2532646C
公开(公告)日：2012-09-11
申请号：CA2532646
申请日：2004-07-21
Applicant: BASF AG
Inventor： OLBERT GERHARD , HECHLER CLAUS
Abstract: The invention relates to a reactor for partial oxidation of a fluid reaction mixture in the presence of a heterogeneous particulate catalyst. Said reactor comprises one or several cuboid heat-transfer sheet modules (1) which are each composed of two or several right-angled heat-transfer sheets (2), arranged parallel to each other such as to form a slit (3) which can be filled with the heterogeneous particulate catalyst and through which the fluid reaction mixture flows, the heat of reaction being absorbed by a heat carrier which flows through the heat-transfer sheets (2) and at least partially evaporates. Said reactor also comprises a mainly cylindrical envelope (4, 15, 16) which depressurizes the heat-transfer sheet modules and fully surrounds said modules, said envelope being composed of a cylinder casing (4) and of caps (15, 16), closing said casing at both ends, the longitudinal axis of which extends parallel to the plane of said heat-transfer sheets (2). Said reactor finally comprises one or several sealing elements (7, 23), arranged so that the fluid reaction mixture flows only through the slit (3), except through the reactor interior spaces, defined by the caps (15, 16).
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公开(公告)号：RU2391330C9
公开(公告)日：2011-05-10
申请号：RU2007103607
申请日：2005-05-17
Applicant: BASF AG
Inventor： MACHHAMMER OTTO , SCHINDLER GOTZ-PETER , ADAMI CHRISTOPH , HECHLER CLAUS , DIETERLE MARTIN
IPC: C07B61/00 , C07C45/35 , C07C47/22 , C07C51/235 , C07C51/25 , C07C57/05 , C07C57/055
Abstract: Изобретениеотноситсяк усовершенствованномуспособуполученияакролеина, акриловойкислотыилиихсмесиизпропана. ВсоответствиисоспособомА) впервуюреакционнуюзонуА вводятпоменьшеймередвасодержащихпропангазообразныхпитающихпотока, поменьшеймереодинизкоторыхсодержитсвежийпропан, ивведенныйв этуреакционнуюзонупропанподвергаютгетерогеннокатализируемомудегидрированиюсостационарнымслоемкатализатора, получаясодержащуюпропани пропиленгазообразнуюсмесьпродуктовА, В, которуювыводятизреакционнойзоныА, впервойзонеразделенияА выделяютизнеепоменьшеймеречастьсодержащихсяв нейкомпонентов, отличающихсяотпропанаи пропилена, аостающуюсяприэтомгазообразнуюсмесьпродуктовА′, содержащуюпропани пропилен, С) используютвовторойреакционнойзонеВ дляпитанияпоменьшеймереодногореактораокисления, ипропилен, содержащийсяв газообразнойсмесипродуктовА′, поменьшеймерев одномреактореокисленияподвергаютгетерогеннокатализируемомудвухступенчатомугазофазномучастичномуокислениюмолекулярнымкислородомв акриловуюкислотуилисмесьакролеинаи акриловойкислоты, вкачествецелевогопродукта, атакжев содержащуюизбытокмолекулярногокислородагазообразнуюсмесьпродуктовВ, D), которуювыводятизреакционнойзоныВ, вовторойзонеразделенияВ выделяютсодержащийсяв нейцелевойпродуктметодомабсорбцииилифракционирующейконденсации, ипоменьшеймеречастьостающегосяпослеэтогоостаточногогаза, содержащегонепревращенныйпропан, молекулярныйкислород, атакжепринеобходимостинепревращенныйпропилен, рециркулируютв реакци
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公开(公告)号：MY140316A
公开(公告)日：2009-12-31
申请号：MYPI20052282
申请日：2005-05-19
Applicant: BASF AG
Inventor： MACHHAMMER OTTO , SCHINDLER GOTZ-PETER , ADAMI CHRISTOPH , HECHLER CLAUS , DIETERLE MARTIN
Abstract: A PROCESS FOR PREPARING ACROLEIN OR ACRYLIC ACID OR A MIXTURE THEREOF FROM PROPANE, IN WHICH THE PROPANE IS INITIALLY DEHYDROGENATED UNDER HETEROGENEOUS CATALYSIS TO GIVE PROPENE, SECONDARY COMPONENTS ARE REMOVED AND THE REMAINING GAS MIXTURE, COMPRISING PROPANE AND PROPENE, IS SUBJECTED TO THE HETEROGENEOUSLY CATALYZED PARTIAL OXIDATION TO ACROLEIN OR ACRYLIC ACID OR A MIXTURE THEREOF AS THE TARGET PRODUCT, TARGET PRODUCT IS REMOVED FROM THE PRODUCT GAS MIXTURE AND THE REMAINING RESIDUAL GAS, COMPRISING EXCESS OXYGEN AND UNCONVERTED PROPANE, IS RECYCLED INTO THE PROPANE DEHYDROGENATION IN SUCH A WAY THAT THE OTHER PROPANE FED TO THE DEHYDROGENATION IS AT LEAST PARTLY CONVERTED UNDER DEHYDROGENATING CONDITIONS AT THE RECYCLE POINT.
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