61.
    发明专利
    未知

    公开(公告)号:DE58908064D1

    公开(公告)日:1994-08-25

    申请号:DE58908064

    申请日:1989-08-19

    Applicant: BASF AG

    Abstract: The invention relates to compounds of the general formula (I) in which R and R in each case stand for H, Cl, alkyl, alkoxy, optionally substituted phenyl or phenylalkyl, R and R stand for H, alkyl, oxaalkyl, alkoxy, oxaalkoxy, optionally substituted phenyl, phenylalkyl, phenoxy, phenylalkoxy, alkylcarbonylamino, benzoylamino, alkanoyloxy or benzoyloxy, n is 1 or 2 and R - if n = 1 - stands for alkyl, hydroxyalkyl, cycloalkyl, alkenyl, oxaalkyl, phenylalkyl or for -(CH2)m-O- or or - if n = 2 - stands for alkylene, cycloalkylene, alkenylene, oxaalkylene or for or in which m denotes 2 to 4, R denotes alkyl, alkenyl, cycloalkyl, phenylalkyl, optionally substituted phenyl or naphthyl, and R denotes alkylene, alkenylene, cycloalkylene, optionally substituted phenylene, naphthylene, diphenylene, and The anilides (I) are effective photostabilisers for organic materials, in particular for polymers.

    67.
    发明专利
    未知

    公开(公告)号:DE3877918D1

    公开(公告)日:1993-03-11

    申请号:DE3877918

    申请日:1988-11-17

    Applicant: BASF AG

    Abstract: Multilayer electrophotographic material has (A) an electroconductive substrate and (B) one or more layers of (b1) binder(s), (b2) charge carrier generating cpd(s). or sensitiser(s), (b3) charge carrier transport cpd(s). or photoconductor(s) and opt. (b4) additives; (b2) are new 1-cyanomethylene-4'-aminophenyl)-isoindolenine dyestuffs of formula (I). In (IA), A = CN; X, Y and Z = H and -NR1R2 = a partly unsatd. 5-6-membered heterocycle; in general: a = CN, carbo-1-4 C-alkoxy, carbamoyl, N-1-4 C-alkylcarbamoyl (in which the alkyl gp. is opt. substd. ), N-phenylcarbamoyl (in which the phenyl gp. is opt. substd. ), acetyl, benzoyl, 4-nitrophenyl or 4-cyanophenyl; X = H, Cl, 1-4C alkyl or 1-4C alkoxy and the substits. can be the same or different if n = 2; n = 1 or 2; R1 = H, Me, Et or 2-hydroxyethyl; and R2 = Ph (opt. substd. ) or cyclohexyl; or R1 = H and R2 = 1-4C alkyl; or R1 and R2 = 1-6C alkyl; 1-4C alkyl substd. by Cl, CN, OH, 1-4C alkoxy, phenoxy, 2-5C alkanoyloxy (opt. substd. ) or carbo-1-4 C-alkoxy; ally; phenyl-1-4 C-alkyl; or -NR1R2 = a satd. or partly unsatd. 5-6-membered heterocycle, Y = H; OH; Me; Et; -OCOR3; -NR4-CO-R5; -NR4-SO2-R7; N-1-4 C-alkylamino ir R1 and R2 = 1-4C alkyl; or N,N-di-1-4 C-alkylamino, N-pyrrolidinyl, N-piperidinyl or N-morpholinyl if -NR1N2 is the same as Y; R3 = linear or branched 1-12C alkyl; or Ph, opt. substd. by 1-4C alkyl or 1-4C alkoxy; R4 = H or 1-4C alkyl; R5 = H 1-12C alkyl; CF3; chloromethyl; 1-4C alkoxymethyl; phenoxymethyl (in which the PhO gp. opt. has 1 or 2 H atoms replaced ); phenylthiomethyl (in which the Ph is opt. substd.); benzyl; phenylether; 3-7C cycloalkyl; Ph, opt. substd. by 1-12C alkyl, 1-12C alkoxy or NO2; C6H5-CH=CH-; or -CH2-PO(OR6)2; R6 = 1-4C alkyl; R7 = 1-12C alkyl; or Ph, opt. substd. by 1-12C alkyl; Z = H; or if R1 ano R2 = 1-4C alkyl or allyl and Y = -NR4-COR5, Z can also = MeO or EtO.EtO.

    68.
    发明专利
    未知

    公开(公告)号:DE3782407D1

    公开(公告)日:1992-12-03

    申请号:DE3782407

    申请日:1987-12-15

    Applicant: BASF AG

    Abstract: New cpds. (I) are of formula (I) where n = 1-70; R1, R2 = H, 1-6C alkyl, 7-12C aralkyl, aryl, or carbon ester, or R1 with R2 = tetra- to hexa-methylene gp. or opt. substd. fluorene-typering of specified formula; X, Y = O, S, or NR7 where R7 = H, 1-8C alkyl, or 7-12C aralkyl; M = (II) where R3, R4, R5, R6 = alkyl, or R3 with R4, and R5 with R6, form with attached C atom, 5 or 6-membered ring, R8 = H or alkyl, or with attached C atom, denotes =C:O, and R9 = H or further bond to spiro-linked bridge member -B- (A then denoting direct bond); each D= -(CH2)m-, where m = 1-20, or, if residue M is joined with A through N atom, can also be a direct bond, at least one gp. -M-D being present, with M in this gp. being linked to D via N atom; each A = opt. substd. N, COOH, CO, SO2, SO2NH2, or direct bond; B = bridge member or direct bond; C has 20 meanings, e.g., H, acyl, Cl, OH, NH2, or gp. of formula (III) wherein each R13 = H or CH2OR14 where R14 = H or 1-22C alkyl opt. interrupted by ether O, N or S, or the R13 together denote -CH2-N (R15)-CH2 where R15 has 28 meanings, e.g., 1-22C alkyl. Alternatively, -M-A-B-A-C-represents gp. of formula (IV)-(VI) where R16-R20 together have over 50 meanings. Acid addn. salts and hydrates of (I) are also claimed. Polyalkylpiperidines of specified general formulae, as intermediates for (I), and their acid addn. salts and hydrates, are also claimed.

    Polycondensates with macrocyclic gps. in the main chain - by polycondensation of di:hydroxy cpds. with di:chloro-phthalocyanine(s) contg. central silicon atom.

    公开(公告)号:DE4001239A1

    公开(公告)日:1991-07-25

    申请号:DE4001239

    申请日:1990-01-18

    Applicant: BASF AG

    Abstract: Polycondensates (I) with repeating units of formula -(-O-Pc(Si)O-D)n- in the main chain are claimed; Pc(Si) = phthalocyanine residue with a central Si atom; n = 5 or above; D = (D1); 3-5 ring arylene, opt. substd. with Cl, F or 1-4C alkyl; (D2); 1-2 ring arylene, opt. substd. with Cl, F, NH2 or 1-4C alkyl; (D3); 5- or 6-membered N-, O- or S-heterocycle with a conjugated pi-electron system; (D4); -CO-R1-CO- (with R1 = 1-18C alkylene or 6-12C arylene); or (D5); a gp. of formula (I) (with X = -O-, -CO-, -CMe2-, -S-, -SO2- or -CO-C6H4-q(R4)q-CO-; R2, R3, R4 = 1-4C alkyl or Hal; k, m, q = 0 or 1-4; p = 0 or 1). USE/ADVANTAGE - (I) are useful for the prodn. of moulded prods. (claimed). The invention provides polycondensates with new, quasi-aromatic, axially-centred macrocyclic gps. (I) have the advantageous properties of the polymer type on which they are based (polycarbonate, polyester, polyether or polysulphone), and are useful for the prodn. of fibres, film or antistatic coating materials, and as catalysts, sensors, and electrodes for batteries and photovoltaic cells.

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