63.
    发明专利
    未知

    公开(公告)号:DE4426002A1

    公开(公告)日:1996-01-25

    申请号:DE4426002

    申请日:1994-07-22

    Applicant: BASF AG

    Abstract: The invention concerns a process for preparing aqueous aminoplastic resins which are suitable as binders for producing derived timber products. The process is characterized in that: a) 1 mole melamine; b) a concentrated aqueous solution of 0.5 to 5 moles urea and 3 to 6 moles formaldehyde per mole of urea, in which urea and formaldehyde can also be present in the form of their reaction products, c) 0.01 to 0.5 moles phenol or a phenol derivative which can be polycondensed, d) 0 to 9 moles formaldehyde, and e) 0 to 1 mole of a further compound which can be polycondensed are reacted with one another at 50 to 100 DEG C and a pH of 7.5 to 10.0 until the solution attains a viscosity of 10 to 1500 mPa.s, after which this solution is left to cool, and f) is mixed with 0.55 to 0.75 moles urea per mole of the total amount of urea used as components (b) and (f).

    Prepn. of vinyl] polymers of low mol. wt.

    公开(公告)号:DE4203278A1

    公开(公告)日:1993-08-12

    申请号:DE4203278

    申请日:1992-02-06

    Applicant: BASF AG

    Abstract: The continuous polymerisation of vinyl monomers by formation of vinyl polymers (I) with a mol. wt. of 1000-20,000 is claimed. The polymerisation is carried out at 110-270 deg. C in a ring slit (slit width 0.5-1.00 mm) that is bounded on the inner side by a rotor. Also claimed is the use of (I) as binding agents for paints, protective coatings, paper coating materials and printing inks. The reaction temp. is 150-270 deg. C and the polymer dispersivity (Mw/Mn) of (I) is less than 3.5. A portion of the volumetric flow is recirculated through the ring slit such that the recycle ratio of recirculated volumetric flow to throughput is 2-35. The rotor promotes reacton by thorough mixing and has a tangential avelocity of 0.5-2 m/s. The reaction is carried out in 0-40% of a solvent (w.r.t. monomer). The mixt. of monomers comprises 60-100 wt.% (meth)acrylic acid esters. Polymerisation initiator is added in a molar ratio of 0.0005:1 to 0.1:1 (w.r.t. monomer).

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