公开(公告)号：FI904090A0

公开(公告)日：1990-08-17

申请号：FI904090

申请日：1990-08-17

Applicant: BASF AG

Inventor： REHMER GERD ,  AUCHTER GERHARD

IPC: C08F220/18 ,  C08F224/00 ,  C08F226/06 ,  C08F228/06 ,  C08F246/00 ,  C09D157/04 ,  C09J157/04 ,  C08F

Abstract: The invention relates to copolymers built up from A) from 99.5 to 75 % of olefinically unsaturated monomers containing hetero atoms, B) from 0.5 to 25 % of unsaturated compounds of the formula I and C) from 0 to 20 % of further olefinically unsaturated monomers where X is O, S or NR and R is optionally substituted C2-C6-alkylene, and R is C1- to C8-alkyl or phenyl. The products according to the invention are suitable as coating and impregnation compositions and in particular as contact adhesives.

公开(公告)号：AU4733789A

公开(公告)日：1990-07-05

申请号：AU4733789

申请日：1989-12-29

Applicant: BASF AG

Inventor： REHMER GERD ,  BOETTCHER ANDREAS ,  AUCHTER GERHARD

IPC: C08F212/08 ,  C08F2/46 ,  C08F20/10 ,  C08F20/26 ,  C08F20/52 ,  C08F212/00 ,  C08F220/18 ,  C08F220/30 ,  C08F220/58 ,  C08F290/00 ,  C08F290/06 ,  C08F299/00 ,  C09D4/00 ,  C09D133/04 ,  C09J4/00 ,  C09J133/04 ,  C08F220/16 ,  C09J3/16 ,  C09D3/80 ,  C08L33/10

Abstract: UV-crosslinkable materials based on (meth)acrylate copolymers contain copolymerized monomers of the general formula I (I) where R is a certain alkyl radical, an aryl radical or a radical R1 and R1 is a radical where R2 to R6 are each H, alkyl, a non-ortho OH group, OCH3, OC2H3, SH, SCH3, Cl, F, CN, COOH, COO(C1-C3-alkyl), CF3, N(CH3)2, N(C2H5)2, N(CH3)C6H5, +N(CH3)3X- or +N(CH3)XX-, where X- is an acid anion, and one or more of the radicals R2 to R6 are each a radical or or where Sp is one of the spacer groups of the following type and R', R'' and R''' are each H or a certain hydrocarbon, and where the radicals X may be identical or different and are each a divalent, alkylene radical, a cycloalkylene radical or phenylene radical, which are bonded directly to one another and/or are bonded to one another by identical or different groups Y, and Y is a divalent radical from the group consisting of and k and m are each from 1 to 10 and 1 and n are each from 0 to 25.

公开(公告)号：CA2002400A1

公开(公告)日：1990-05-09

申请号：CA2002400

申请日：1989-11-07

Applicant: BASF AG

Inventor： HORN PETER ,  REHMER GERD ,  LUTTER HEINZ-DIETER ,  RAMLOW GERHARD ,  HINZ WERNER ,  SCHMIDT HANS U

IPC: C08F216/14 ,  C08F218/10 ,  C08F220/28 ,  C08F220/58 ,  C08F222/20 ,  C08F226/00 ,  C08F226/06 ,  C08F290/06 ,  C08F299/02 ,  C08G18/40 ,  C08G18/62 ,  C08L75/04 ,  C09K23/52

Abstract: The novel copolymers having K values of from 5 to 80 are prepared by free-radical polymerisation of A) 20 to 80% by weight, based on the total weight of (A) and (B), of at least one olefinically unsaturated polyoxyalkylene alcohol or polyester alcohol adduct, (B) 80 to 20% by weight, based on the total weight of (A) and (B), of at least one vinyl monomer from the group comprising N-vinylformamide, -2-pyrrolidone, -2-piperidone, -2-caprolactam, -imidazole, -2-ethyleneurea and -2-propyleneurea, C) 0.05 to 40 parts by weight of glycidyl acrylate and/or glycidyl methacrylate, D) 0 to 10 parts by weight of at least one alpha , beta -monoolefinically unsaturated acid and E) 0 to 30 parts by weight of at least one olefinically unsaturated carboxamide and/or carboxylate and/or styrene, the parts by weight of (C), (D) and (E) in each case being based on 100 parts by weight of the monomers (A) and (B). The copolymers are used as assistants and/or additives, for example as dispersion and/or emulsification assistants, or as additives for improving the mechanical properties, in formulations for the preparation of polyisocyanate polyaddition products.

公开(公告)号：CA2000736A1

公开(公告)日：1990-04-30

申请号：CA2000736

申请日：1989-10-16

Applicant: BASF AG

Inventor： REHMER GERD ,  BOETTCHER ANDREAS ,  PFOEHLER PETER ,  AYDIN ORAL ,  NESTLER GERHARD

IPC: C08J5/18 ,  C08F220/18 ,  C08L23/00 ,  C08L33/04 ,  C08L33/06 ,  C09J133/06 ,  C08F2/26 ,  C09J161/00 ,  C09J131/02

Abstract: O.Z. 0050/40301 Materials which are crosslinkable by ultraviolet radiation under atmospheric oxygen and are based on (meth)acrylate copolymers having a X value of from 10 to 100 are obtained by free radical polymerization, in the presence or absence of a solvent, of a) from 5 to 97.4% by weight of isoamyl acrylate and/or isoamyl methacrylate, b) from 0 to 89.9% by weight of (meth)acrylates whose homopolymers have a glass transition temperature below -30.degree.C, c) from 2.5 to 30% by weight of .alpha.,.beta.-monoolefinically unsaturated compounds whose homopolymers have a glass transition temperature above -30.degree.C, d) from 0 to 10% by weight of monoolefinically unsaturated acids and/or their anhydrides and e) from 0 to 20% by weight of further olefinically unsaturated monomers having one or more of the following functional groups: hydroxyl, amide, epoxide, ether, ester, urethane, urea, primary, secondary and tertiary amine and ether groups, and f) from 0.1 to 5% by weight of a copolymerizable benzophenone derivative or acetophenone derivative, the sum of the percentages by weight X (= a + b + c + d + f) being 100 in each case.

公开(公告)号：NO893302L

公开(公告)日：1990-02-19

申请号：NO893302

申请日：1989-08-17

Applicant: BASF AG

Inventor： REHMER GERD ,  SCHWARTZ MANFRED ,  DOTZAUER BERNHARD

IPC: B05D3/06 ,  B05D7/00 ,  B05D7/24 ,  C04B41/48 ,  C04B41/63 ,  C08L33/04 ,  C08L33/14 ,  C04B41/83 ,  C09D133/06

公开(公告)号：FI893839A

公开(公告)日：1990-02-19

申请号：FI893839

申请日：1989-08-15

Applicant: BASF AG

Inventor： REHMER GERD ,  SCHWARTZ MANFRED ,  DOTZAUER BERNHARD

IPC: B05D3/06 ,  B05D7/00 ,  B05D7/24 ,  C04B41/48 ,  C04B41/63 ,  C08L33/04 ,  C08L33/14 ,  C04B

公开(公告)号：FI895024A0

公开(公告)日：1989-10-23

申请号：FI895024

申请日：1989-10-23

Applicant: BASF AG

Inventor： REHMER GERD ,  BOETTCHER ANDREAS ,  PFOEHLER PETER ,  AYDIN ORAL ,  NESTLER GERHARD

IPC: C08J5/18 ,  C08F220/18 ,  C08L23/00 ,  C08L33/04 ,  C08L33/06 ,  C09J133/06 ,  C08L

Abstract: Compositions which can be crosslinked under an atmospheric oxygen atmosphere by means of ultraviolet irradiation and are based on (meth)acrylate copolymers having a K value of from 10 to 100, obtained by free-radical polymerisation in solid phase or solution of a) 5 to 97.4% by weight of i-amyl acrylate and/or i-amyl methacrylate and b) 0 to 89.9% by weight of (meth)acrylates whose hompolymers have a glass transition temperature of below -30 DEG C, c) 2.5 to 30% by weight of alpha , beta -monoolefinically unsaturated compounds whose homopolymers have a glass transition temperature of above - 30 DEG C, d) 0 to 10% by weight of monoolefinically unsaturated acids and/or anhydrides thereof, e) 0 to 20% by weight of further olefinically unsaturated monomers containing at least one of the following functional groups: hydroxyl, amide, epoxide, ether, ester, urethane, urea, primary, secondary or tertiary amine and ether, and f) 0.1 to 5% by weight of a copolymerisable benzophenone or acetophenone derivative, the sum of the percentages by weight x = a + b + c + d + f in each case being 100.

公开(公告)号：AU1234388A

公开(公告)日：1988-09-01

申请号：AU1234388

申请日：1988-02-26

Applicant: BASF AG

Inventor： DEGEN HANS-JUERGEN ,  PFOHL SIGBERG ,  WEBERNDOERFER VOLKMAR ,  REHMER GERD ,  KROENER MICHAEL ,  STANGE ANDREAS

IPC: D21H17/34 ,  D21H17/28 ,  D21H17/29 ,  D21H17/37 ,  D21H17/45 ,  D21H17/56 ,  D21H21/18 ,  D21H3/28

Abstract: Paper and paperboard of high dry strength are produced by adding a dry strength enhancer to the paper stock and dewatering the paper stock with sheet formation by using as the dry strength enhancer a mixture of a cationic polymer which contains as characteristic monomers copolymerized units of (a) diallyldimethylammonium chloride, (b) N-vinylamine or (c) a substituted or unsubstituted N-vinylimidazoline and has a K value of not less than 30, and natural potato starch which is converted into a water-soluble form by heating in an aqueous medium at above the gelatinization temperature of natural potato starch in the absence of any oxidizing agents or alkali.

公开(公告)号：NO880856L

公开(公告)日：1988-08-29

申请号：NO880856

申请日：1988-02-26

Applicant: BASF AG

Inventor： DEGEN HANS-JUERGEN ,  PFOHL SIGBERG ,  WEBERNDOERFER VOLKMAR ,  REHMER GERD ,  KROENER MICHAEL ,  STANGE ANDREAS

IPC: D21H17/34 ,  D21H17/28 ,  D21H17/29 ,  D21H17/37 ,  D21H17/45 ,  D21H17/56 ,  D21H21/18 ,  D21H3/28

Abstract: Paper and paperboard of high dry strength are produced by adding a dry strength enhancer to the paper stock and dewatering the paper stock with sheet formation by using as the dry strength enhancer a mixture of a cationic polymer which contains as characteristic monomers copolymerized units of (a) diallyldimethylammonium chloride, (b) N-vinylamine or (c) a substituted or unsubstituted N-vinylimidazoline and has a K value of not less than 30, and natural potato starch which is converted into a water-soluble form by heating in an aqueous medium at above the gelatinization temperature of natural potato starch in the absence of any oxidizing agents or alkali.

公开(公告)号：FI880836A

公开(公告)日：1988-08-29

申请号：FI880836

申请日：1988-02-23

Applicant: BASF AG

Inventor： DEGEN HANS-JUERGEN ,  PFOHL SIGBERG ,  WEBERNDOERFER VOLKMAR ,  REHMER GERD ,  KROENER MICHAEL ,  STANGE ANDREAS

IPC: D21H17/34 ,  D21H17/28 ,  D21H17/29 ,  D21H17/37 ,  D21H17/45 ,  D21H17/56 ,  D21H21/18 ,  D21H

Abstract: Paper and paperboard of high dry strength are produced by adding a dry strength enhancer to the paper stock and dewatering the paper stock with sheet formation by using as the dry strength enhancer a mixture of a cationic polymer which contains as characteristic monomers copolymerized units of (a) diallyldimethylammonium chloride, (b) N-vinylamine or (c) a substituted or unsubstituted N-vinylimidazoline and has a K value of not less than 30, and natural potato starch which is converted into a water-soluble form by heating in an aqueous medium at above the gelatinization temperature of natural potato starch in the absence of any oxidizing agents or alkali.