公开(公告)号：WO9621689A2

公开(公告)日：1996-07-18

申请号：PCT/EP9502493

申请日：1995-06-27

Applicant: BASF AG ,  WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  BAUMANN EDWIN ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

Inventor： WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  BAUMANN EDWIN ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

IPC: C08G18/60 ,  C08G69/44 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30

CPC classification number: C08G69/44 ,  C08G18/606 ,  Y02W30/43

Abstract: The invention concerns biologically degradable polyester amides P1 obtainable through reaction of a mixture consisting essentially of the following: (a1) a mixture consisting essentially of: 35-95 mol % adipic acid or ester-forming derivatives thereof or mixtures thereof, 5-65 mol % terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and 0-5 mol % a compound containing sulphonate groups (the sum of the individual molar percentages is 100); (a2) a mixture consisting essentially of: (a21) 99.5-0.5 mol % a dihydroxy compound chosen from the group comprising C2-C6 alkane diols and C5-C10 cycloalkane diols, (a22) 0.5-99.5 mol % an amino C2-C12 alkanol or an amino-C5-C10 cycloalkanol, (a23) 0-50 mol % a diamino C1-C8 alkane; and (a24) 0-50 mol % a 2,2`-bisoxazoline of general formula (I), in which R is a single bond, a (CH2)q-alkylene group in which q = 2, 3 or 4, or a phenylene group (the sum of the individual molar percentages is 100 and the molar ratio of a1 to a2 is in the range 0.4:1 - 1.5:1). The polyester amides P1 will have a molecular weight (Mn) in the range 4000-40,000 g/mol, a viscosity number in the range 30-350 g/ml (measured in o-dichlorobenzene/phenol (weight ratio 50/50) at a concentration of 0.5 wt.% polyester amide P1 at a temperature of 25 DEG C) and a melting point in the range 50-220 DEG C; and a quantity of a compound D equivalent to 0-5 mol % of the molar quantity of components (a1) must also be used for the production of the polyester amides P1, said compound D having at least three groups capable of ester formation. The invention also concerns other biologically degradable polymers and thermoplastic moulding materials, processes for manufacturing the same, the use thereof for producing biologically degradable moulded articles and adhesives, and biologically degradable moulded articles, foams and blends with starch which can be obtained from the polymers or moulding materials according to the invention.

Abstract translation: 可生物降解的聚酯酰胺通过基本上由混合物反应P1获得（a1）的基本上35由〜95摩尔％的己二酸或它们的酯形成性衍生物或者它们的混合物，5〜65摩尔％的对苯二甲酸或其酯形成性衍生物的混合物 或其混合物，和0〜5摩尔％磺酸酯化合物的，单独的摩尔百分比的总和为100摩尔％，和（a2）从99.5基本上由（A21）〜0.5摩尔的混合物 - （A22）0.5选自C2-C6烷二醇和C5-C10-环烷二醇的组中选择的二羟基化合物，的％至99.5摩尔％的氨基C2-C12链烷醇或氨基-C5的 C10-环烷醇，以及（A23）0〜50摩尔％的二氨基C1-C8烷烃，（A24）0〜50摩尔％通式（I）的2,2'-二恶唑啉，其中R <1 >一个单键，（CH 2）●亚烷基其中q = 2，3或4，或亚苯基，其中装置 各个摩尔百分比的总和为100摩尔％，并且其中的（a1）至（A2）的范围为0.4的摩尔比：1至1.5：1种选择，条件是该聚酯酰胺P1的分子量 （Mn）的范围为4000至40,000克/摩尔，在30至350范围内的粘度数克/毫升（在以0.5重量％的浓度的邻二氯苯/苯酚（50/50重量比）进行测定。 - ％聚酯酰胺P1在25℃的温度），并在50至220℃的范围内的熔点，并与一个从0〜5摩尔％基于组分的摩尔量进一步的条件（A1 ），与能够对聚酯酰胺的制备酯的形成至少三个基团的化合物D P1中使用的以及其它可生物降解的聚合物和热塑性模塑组合物，涉及它们的制备方法，它们用于制备可生物降解的模制品和粘合剂，生物可降解的成型品使用， 泡沫和从本发明的聚合物或模塑组合物获得的淀粉混合物。

公开(公告)号：NZ289824A

公开(公告)日：1998-11-25

申请号：NZ28982495

申请日：1995-06-27

Applicant: BASF AG

Inventor： WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  BAUMANN EDWIN ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

IPC: C08G18/60 ,  C08G69/44 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30 ,  C08G69/48 ,  C08G69/42 ,  C08G81/00 ,  C08G18/65 ,  C08G63/85

Abstract: Biodegradable polyesteramides as defined in the specification are obtained by reacting a mixture consisting essentially ofa1) a mixture consisting essentially of35 to 95 mol % of adipic acid or ester-forming derivatives thereof,5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof, and0 to 5 mol % of a compound containing sulfonate groups,a2) a mixture consisting essentially of95.5 to 0.5 mol % of a dihydroxy compound,0.5 to 99.5 mol % of an amino-C2-C12-alkanol or an amino-C5-C10-cycloalkanol,0 to 50 mol % of a diamino-C1-C8-alkane, and0 to 50 mol % of a 2,2'-bisoxazoline of the formula I wherein R1 is as set forth in the specification, anda3) 0 to 5 mol %, based on a1), of a compound D as set forth in the specification;and other biodegradable polymers and thermoplastic molding compositions, their manufacture and their use for producing biodegradable moldings, adhesives, foams, and coatings.

公开(公告)号：DE59600362D1

公开(公告)日：1998-08-27

申请号：DE59600362

申请日：1996-01-09

Applicant: BASF AG

Inventor： WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  KRONER MATTHIAS ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

IPC: A61L15/00 ,  A61L15/26 ,  A61L15/62 ,  B65D65/46 ,  C08G69/40 ,  C08G69/44 ,  C08G69/48 ,  C08G73/04 ,  C08K5/09 ,  C08L3/02 ,  C08L77/12 ,  C08L101/16 ,  C09D177/12 ,  C09J177/12

Abstract: PCT No. PCT/EP96/00064 Sec. 371 Date Jul. 3, 1997 Sec. 102(e) Date Jul. 3, 1997 PCT Filed Jan. 9, 1996 PCT Pub. No. WO96/21691 PCT Pub. Date Jul. 18, 1996Biodegradable polyetheresteramides Q1 with a molecular weight (Mn) in the range from 6000 to 80,000 g/mol, a viscosity number in the range from 30 to 450 g/ml (measured in o-dichlorobenzene/phenol (50/50 ratio by weight) at a concentration of 0.5% by weight polyetheresteramide Q1 at 25 DEG C.), and a melting point in the range from 50 DEG to 200 DEG C., obtained by reacting a1) from 95 to 99.9% by weight polyetheresteramide P1, obtained by reacting a mixture of b1) 20-95 mol % adipic acid or ester-forming derivatives thereof, and 5-80 mol % terephthalic acid or ester-forming derivatives thereof, and b2) a mixture of a dihydroxy compound selected from C2-C6-alkanediols and C5-C10-cycloalkanediols, b22) a dihydroxy compound which contains ether functionalities and has the formula IHO-((CH2)n-O))m-HIwhere n is 2, 3 or 4 and m is an integer from 2 to 250, and b23) from 0.5 to 80 mol % of an amino-C2-C12-alkanol or an amino-C5-C10-cycloalkanol, with or without b24) a diamino-C1-C8-alkane, and/or b25) a 2,2'-bisoxazoline where the molar ratio of (b1) to (b2) is in the range from 0.4:1 to 1.5:1, and a2) from 0.1 to 5% by weight of a divinyl ether C1.

公开(公告)号：FI972963A

公开(公告)日：1997-07-11

申请号：FI972963

申请日：1997-07-11

Applicant: BASF AG

Inventor： WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  BAUMANN EDWIN ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

IPC: C08G18/60 ,  C08G69/44 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30 ,  C08G

Abstract: Biodegradable polyesteramides as defined in the specification are obtained by reacting a mixture consisting essentially ofa1) a mixture consisting essentially of35 to 95 mol % of adipic acid or ester-forming derivatives thereof,5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof, and0 to 5 mol % of a compound containing sulfonate groups,a2) a mixture consisting essentially of95.5 to 0.5 mol % of a dihydroxy compound,0.5 to 99.5 mol % of an amino-C2-C12-alkanol or an amino-C5-C10-cycloalkanol,0 to 50 mol % of a diamino-C1-C8-alkane, and0 to 50 mol % of a 2,2'-bisoxazoline of the formula I wherein R1 is as set forth in the specification, anda3) 0 to 5 mol %, based on a1), of a compound D as set forth in the specification;and other biodegradable polymers and thermoplastic molding compositions, their manufacture and their use for producing biodegradable moldings, adhesives, foams, and coatings.

公开(公告)号：CA2006697A1

公开(公告)日：1990-06-28

申请号：CA2006697

申请日：1989-12-27

Applicant: BASF AG

Inventor： GENZ MANFRED ,  LEPPKES REINHARD ,  LUTTER HEINZ-DIETER ,  RAMLOW GERHARD ,  REICH ERHARD

IPC: C08G18/10 ,  C08G18/18 ,  C08G18/40 ,  C08G18/65 ,  C08K5/3492 ,  B29C67/22

Abstract: PROCESS FOR THE PREPARATION OF FLAME RESISTANT ELASTIC POLYURETHANE FLEXIBLE FOAMS AND LOW VISCOSITY MELAMINE POLYETHER POLYOL DISPERSIONS THEREFOR The present invention deals with a process for the preparation of flame resistant, elastic polyurethane flexible foams, comprising reacting: a) organic and/or modified organic polyisocyanate; with b) higher molecular weight polyols; and c) 1,6-hexanediol and/or trimethylolpropane; in the presence of d) melamine or mixtures of melamine and other flame retardants; e) at least one blowing agent; and f) at least one catalyst; and optionally g) auxiliaries and/or additives. In addition the present invention deals with suitable low viscosity melamine and polyetherpolyol dispersions for the process of the present invention comprising melamine, 1,6hexanediol and/or trimethylolpropane and at least one polyetherpolyol.

公开(公告)号：FI116842B

公开(公告)日：2006-03-15

申请号：FI972963

申请日：1997-07-11

Applicant: BASF AG

Inventor： WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  BAUMANN EDWIN ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

IPC: C08G69/44 ,  C08G18/60 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30

Abstract: Biodegradable polyesteramides as defined in the specification are obtained by reacting a mixture consisting essentially ofa1) a mixture consisting essentially of35 to 95 mol % of adipic acid or ester-forming derivatives thereof,5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof, and0 to 5 mol % of a compound containing sulfonate groups,a2) a mixture consisting essentially of95.5 to 0.5 mol % of a dihydroxy compound,0.5 to 99.5 mol % of an amino-C2-C12-alkanol or an amino-C5-C10-cycloalkanol,0 to 50 mol % of a diamino-C1-C8-alkane, and0 to 50 mol % of a 2,2'-bisoxazoline of the formula I wherein R1 is as set forth in the specification, anda3) 0 to 5 mol %, based on a1), of a compound D as set forth in the specification;and other biodegradable polymers and thermoplastic molding compositions, their manufacture and their use for producing biodegradable moldings, adhesives, foams, and coatings.

公开(公告)号：NO311032B1

公开(公告)日：2001-10-01

申请号：NO973228

申请日：1997-07-11

Applicant: BASF AG

Inventor： WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  BAUMANN EDWIN ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

IPC: C08G18/60 ,  C08G69/44 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30

Abstract: Biodegradable polyesteramides as defined in the specification are obtained by reacting a mixture consisting essentially ofa1) a mixture consisting essentially of35 to 95 mol % of adipic acid or ester-forming derivatives thereof,5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof, and0 to 5 mol % of a compound containing sulfonate groups,a2) a mixture consisting essentially of95.5 to 0.5 mol % of a dihydroxy compound,0.5 to 99.5 mol % of an amino-C2-C12-alkanol or an amino-C5-C10-cycloalkanol,0 to 50 mol % of a diamino-C1-C8-alkane, and0 to 50 mol % of a 2,2'-bisoxazoline of the formula I wherein R1 is as set forth in the specification, anda3) 0 to 5 mol %, based on a1), of a compound D as set forth in the specification;and other biodegradable polymers and thermoplastic molding compositions, their manufacture and their use for producing biodegradable moldings, adhesives, foams, and coatings.

公开(公告)号：PL321297A1

公开(公告)日：1997-12-08

申请号：PL32129795

申请日：1995-06-27

Applicant: BASF AG

Inventor： WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  BAUMANN EDWIN ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

IPC: C08G18/60 ,  C08G69/44 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30

Abstract: Biodegradable polyesteramides as defined in the specification are obtained by reacting a mixture consisting essentially ofa1) a mixture consisting essentially of35 to 95 mol % of adipic acid or ester-forming derivatives thereof,5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof, and0 to 5 mol % of a compound containing sulfonate groups,a2) a mixture consisting essentially of95.5 to 0.5 mol % of a dihydroxy compound,0.5 to 99.5 mol % of an amino-C2-C12-alkanol or an amino-C5-C10-cycloalkanol,0 to 50 mol % of a diamino-C1-C8-alkane, and0 to 50 mol % of a 2,2'-bisoxazoline of the formula I wherein R1 is as set forth in the specification, anda3) 0 to 5 mol %, based on a1), of a compound D as set forth in the specification;and other biodegradable polymers and thermoplastic molding compositions, their manufacture and their use for producing biodegradable moldings, adhesives, foams, and coatings.

公开(公告)号：FI972963A0

公开(公告)日：1997-07-11

申请号：FI972963

申请日：1997-07-11

Applicant: BASF AG

Inventor： WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  BAUMANN EDWIN ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

IPC: C08G18/60 ,  C08G69/44 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30 ,  C08G

Abstract: Biodegradable polyesteramides as defined in the specification are obtained by reacting a mixture consisting essentially ofa1) a mixture consisting essentially of35 to 95 mol % of adipic acid or ester-forming derivatives thereof,5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof, and0 to 5 mol % of a compound containing sulfonate groups,a2) a mixture consisting essentially of95.5 to 0.5 mol % of a dihydroxy compound,0.5 to 99.5 mol % of an amino-C2-C12-alkanol or an amino-C5-C10-cycloalkanol,0 to 50 mol % of a diamino-C1-C8-alkane, and0 to 50 mol % of a 2,2'-bisoxazoline of the formula I wherein R1 is as set forth in the specification, anda3) 0 to 5 mol %, based on a1), of a compound D as set forth in the specification;and other biodegradable polymers and thermoplastic molding compositions, their manufacture and their use for producing biodegradable moldings, adhesives, foams, and coatings.

公开(公告)号：AU2978295A

公开(公告)日：1996-07-31

申请号：AU2978295

申请日：1995-06-27

Applicant: BASF AG

Inventor： WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  BAUMANN EDWIN ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

IPC: C08G18/60 ,  C08G69/44 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30

Abstract: Biodegradable polyesteramides as defined in the specification are obtained by reacting a mixture consisting essentially ofa1) a mixture consisting essentially of35 to 95 mol % of adipic acid or ester-forming derivatives thereof,5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof, and0 to 5 mol % of a compound containing sulfonate groups,a2) a mixture consisting essentially of95.5 to 0.5 mol % of a dihydroxy compound,0.5 to 99.5 mol % of an amino-C2-C12-alkanol or an amino-C5-C10-cycloalkanol,0 to 50 mol % of a diamino-C1-C8-alkane, and0 to 50 mol % of a 2,2'-bisoxazoline of the formula I wherein R1 is as set forth in the specification, anda3) 0 to 5 mol %, based on a1), of a compound D as set forth in the specification;and other biodegradable polymers and thermoplastic molding compositions, their manufacture and their use for producing biodegradable moldings, adhesives, foams, and coatings.