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    62.
    发明专利
    未知

    公开(公告)号：PT927212E

    公开(公告)日：2000-12-29

    申请号：PT97943850

    申请日：1997-09-19

    Applicant: BASF AG

    Inventor： BAUER PETER ,  BUCHMANN BERND ,  WARZELHAN VOLKER ,  KOWITZ CHRISTOPH ,  BEIMBORN DIETER BERNHARD ,  FALLER UWE ,  LAUN MARTIN ,  PAGGA UDO ,  PIPPER GUNTER

    IPC: C08J5/00 ,  C08G18/42 ,  C08G18/76 ,  C08G18/79 ,  C08G63/20 ,  C09D5/00 ,  C09D167/00 ,  C09D175/04 ,  D01F6/84 ,  D01F6/92

    Abstract: PCT No. PCT/EP97/04908 Sec. 371 Date Mar. 17, 1999 Sec. 102(e) Date Mar. 17, 1999 PCT Filed Sep. 19, 1997 PCT Pub. No. WO98/12242 PCT Pub. Date Mar. 20, 1998Biodegradable polyesters based on A) 95-99.99 mol % of at least one polyester A containing as monomeric building blocks of an acid component comprising a11) 20-95 mol % of at least one aliphatic or cycloaliphatic dicarboxylic acid or its ester-forming derivative and a12) 5-80 mol % of at least one aromatic dicarboxylic acid or its ester-forming derivative and at least one dihydroxy compound or at least one amino alcohol or their mixtures, and B) 0.01-5 mol % of a mixture comprising mono-, bi-, tri-, tetra- and higher-nuclear isocyanurates or corresponding compounds containing two, three or four functional groups capable of reacting with the end groups of polyester A, or mixtures of the isocyanurates and the corresponding compounds, as well as molding compositions comprising said polyesters, their manufacture and their use in the manufacture of moldings, filsm, fibers and coatings.

    Polymerization of conjugated dienes in a vinyl aromatic compound, useful for the production of toughened polystyrene, uses a lanthanide metal alkenyl complex and organoaluminum or boron co-catalyst
    63.
    发明专利
    Polymerization of conjugated dienes in a vinyl aromatic compound, useful for the production of toughened polystyrene, uses a lanthanide metal alkenyl complex and organoaluminum or boron co-catalyst 未知

    公开(公告)号：DE19926283A1

    公开(公告)日：2000-12-14

    申请号：DE19926283

    申请日：1999-06-09

    Applicant: BASF AG

    Inventor： JUENGLING STEPHAN ,  SCHADE CHRISTIAN ,  GAUSEPOHL HERMANN ,  WARZELHAN VOLKER

    IPC: C08F12/04 ,  C08F36/04 ,  C08L55/02 ,  C08F4/52 ,  C08F297/04

    Abstract: Solution polymerization of conjugated dienes in a vinyl aromatic compound is carried out using a lanthanide metal alkenyl complex and organoaluminum or boron co-catalyst. A process for the solution of conjugated dienes in a vinyl aromatic compound in the presence of a catalyst is claimed. The catalyst is prepared by reaction of an alkenyl complex of a lanthanide metal with a co-catalyst comprising: (A) an organoaluminum compound of formula (1)-(6); and (B) a boron compound of formula (7). AlR (1) HAlR (2) R AlOR (3) RAl(OR) (4) R Al(OAl(R))nOAlR (5) (OAl(R))n+2 (6) B(Y)p(C6H5-qR q)3-p (7) (DkH) (BYp(C6H5-qR q)4-p (8) R = 1-12C alkyl; n = 1-50; R = fluorine or 1-10C fluoroalkyl; Y = alkyl, C R 5, a sulfonate O3SR or O3SR , an amide NR 2, a pyridyl NC5R 5, a dipyridyl N2C10R 8, a pyrazolate N2C3R 3, a pyrazolylborate R B(N2C3R 3)3, a benzamidinate (R N)2CC6H5R , an alcoholate or phenolate OR , a siloxane OSiR 3, a thiolate SR , a cyclopentadienyl C5HrR 5-r, an indenyl C9H7-sR s, a fluorenyl C13H9-tR t, a phenyl C6HrR25-r, 1-20 C alkyl, alkenyl or alkinyl; R = H or 1-30C alkyl, 6-30C aryl or an optionally substituted silyl group; r,s = 0-5; t = 0-9; p = 0-2; q = 1-5; D = neutral donor ligand; k = 0-10.

    65.
    发明专利
    未知

    公开(公告)号：ES2147918T3

    公开(公告)日：2000-10-01

    申请号：ES96903976

    申请日：1996-02-03

    Applicant: BASF AG

    Inventor： WARZELHAN VOLKER ,  PIPPER GUNTER ,  SEELIGER URSULA ,  BAUER PETER ,  PAGGA UDO ,  YAMAMOTO MOTONORI

    IPC: A61L15/26 ,  A61L15/62 ,  C08G63/183 ,  C08J5/00 ,  C08G63/20 ,  C08G63/60 ,  C08G63/668 ,  C08G63/672 ,  C08G63/688 ,  C08G63/91 ,  C08J9/00 ,  C08J9/04 ,  C08L67/00 ,  C08L101/16 ,  C09J167/00 ,  D21H19/28

    Abstract: PCT No. PCT/EP96/00457 Sec. 371 Date Aug. 14, 1997 Sec. 102(e) Date Aug. 14, 1997 PCT Filed Mar. 5, 1996 PCT Pub. No. WO96/25446 PCT Pub. Date Aug. 22, 1996Biodegradable polyesters having a molecular weight (Mn) of from 5000 to 50,000 g/mol (measured by gel permeation chromatography), a viscosity number of from 30 to 350 g/ml (measured in 50:50 by weight of o-dichlorobenzene/phenol at a concentration of 0.5% by weight of polyester at 25 DEG C.), and a melting point of from 50 to 170 DEG C., and having both hydroxyl and carboxyl end groups, the molar ratio of carboxyl end groups to hydroxyl end groups being greater than one, which is obtained by reacting a mixture consisting essentially of a1) a mixture consisting essentially of from 45 to 80 mol % of adipic acid or ester-forming derivatives thereof, or mixtures thereof, from 20 to 55 mol % of terephthalic acid or ester-forming derivatives thereof, or mixtures thereof, and from 0 to 5 mol % of a sulfonate compound, where the sum of the individual mole percentages is 100 mol %, and a2) a dihydroxy compound selected from the group consisting of C2-C6-alkanediols and C5-C10-cycloalkanediols, in the presence of from 0.01 to 5 mol %, per mol of component a1), of a compound D having at least three groups capable of ester formation, the molar ratio of a1) to a2) being from 0.4:1 to 1.5:1, polymers and biodegradable thermoplastic molding compositions, processes for their preparation and their use for producing biodegradable moldings, adhesives, foams and blends with starch obtained from the polymers or molding compositions.

    70.
    发明专利
    未知

    公开(公告)号：DE19825485A1

    公开(公告)日：1999-12-09

    申请号：DE19825485

    申请日：1998-06-08

    Applicant: BASF AG

    Inventor： MC KEE GRAHAM EDMUND ,  JUENGLING STEPHAN ,  WARZELHAN VOLKER ,  GAUSEPOHL HERMANN

    IPC: C08L67/02 ,  C08L69/00 ,  C08F220/18 ,  C08J3/20 ,  C08J5/00 ,  C08J5/18 ,  C08L33/04 ,  C08L33/20 ,  D01F6/92

    Abstract: Polymer mixtures, containing the following essential ingredients: A) 1-99 wt.% polycarbonates or polyester; B) 1-99 wt.% acrylate rubber modified moulding material, produced by b1) anionic polymerisation of monomers selected from the group consisting of i) (meth)acrylic acid esters of general formula (I) CH2=C(R )-CO2R , and ii) (meth)acrylic acid esters of general formula (II) CH2=C(R )-C(O)O-CR R R in a solvent containing vinyl aromatic compounds of general formula (III) and b2) by adding to the reaction mixture obtained according to b1) b21) acrylonitrile, methacrylonitrile, C1-C8 methacrylates or mixtures thereof and optionally, other radically polymerisable monomers selected from the group consisting of b22) vinyl aromatic compounds according to general formula (III), (C1-C8 alkyl) (meth)acrylic acid esters or the mixtures thereof, b23) other olefinically unsaturated compounds that are different from acrylonitrile or methacrylonitrile or vinyl aromatic compound (III), b3) radical polymerisation of the mixture obtained according to b2), in addition b4 to isolating the rubber modified moulding material obtained according to b3); C) 0-50 wt.% acrylate rubber modified moulding material, whereby at least the rubber phase is produced by means of emulsion polymerisation; D) 0-50 wt.% inorganic filler and E) 0-50 wt.% additives and auxiliary agents.

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