公开(公告)号：PL323389A1

公开(公告)日：1998-03-30

申请号：PL32338996

申请日：1996-05-07

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM ,  FLICK KLEMENS

IPC: C07D201/08

Abstract: Production of cyclic lactams by the reaction of amino carboxylic acid nitriles with water, performed in the liquid phase in the presence of heterogeneous catalysts based on titanium dioxide with a rutile content in the range from 0.1 to 95 wt.% and an anatase content in the range from 99.9 to 5 wt.% in relation to the total titanium dioxide content.

公开(公告)号：PL323359A1

公开(公告)日：1998-03-30

申请号：PL32335996

申请日：1996-05-04

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  ZIMMERMANN HORST ,  WITZEL TOM ,  BREITSCHEIDEL BORIS ,  BECKER RAINER ,  HEUHAUSER HORST

IPC: B01J23/40 ,  C07C213/02 ,  C07C213/06

Abstract: PCT No. PCT/EP96/01861 Sec. 371 Date Jan. 23, 1998 Sec. 102(e) Date Jan. 23, 1998 PCT Filed May 4, 1996 PCT Pub. No. WO96/36589 PCT Pub. Date Nov. 21, 1996A process for preparing N-methyl-2-(3,4-dimethoxyphenyl)-ethylamine comprises hydrogenating 3,4-dimethoxyphenylacetonitrile with a methylamine of the general formula I (I) where R1 is hydrogen, benzyl or tert-butyl, and hydrogen in the presence of a supported catalyst which comprises from 0.05 to 50% by weight of copper chromite, copper, silver, gold, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum or mixtures thereof, in the presence or absence of water at from 20 DEG to 200 DEG C. under from 1 to 300 bar.

公开(公告)号：TR9701451T1

公开(公告)日：1998-03-21

申请号：TR9701451

申请日：1996-05-24

Applicant: BASF AG

Inventor： HOLDERBAUM MARTIN ,  BECK KARL ,  AUMUELLER ALEXANDER ,  WITZEL TOM ,  VOIT GUIDO

IPC: C07C253/30 ,  C07C255/41

CPC classification number: C07C253/30

公开(公告)号：TR9701373T1

公开(公告)日：1998-02-21

申请号：TR9701373

申请日：1996-05-04

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  ZIMMERMANN HORST ,  WITZEL TOM ,  BREITSCHEIDEL BORIS ,  HEUHHAUSER HORST ,  BECKER RAINER

IPC: B01J23/40 ,  C07C213/02 ,  C07C213/06

CPC classification number: C07C213/06 ,  B01J23/40 ,  C07C213/02

公开(公告)号：TR199701373T1

公开(公告)日：1998-02-21

申请号：TR9701373

申请日：1996-05-04

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  ZIMMERMANN HORST ,  WITZEL TOM ,  BREITSCHEIDEL BORIS ,  HEUHHAUSER HORST ,  BECKER RAINER

IPC: B01J23/40 ,  C07C213/02 ,  C07C213/06

Abstract: PCT No. PCT/EP96/01861 Sec. 371 Date Jan. 23, 1998 Sec. 102(e) Date Jan. 23, 1998 PCT Filed May 4, 1996 PCT Pub. No. WO96/36589 PCT Pub. Date Nov. 21, 1996A process for preparing N-methyl-2-(3,4-dimethoxyphenyl)-ethylamine comprises hydrogenating 3,4-dimethoxyphenylacetonitrile with a methylamine of the general formula I (I) where R1 is hydrogen, benzyl or tert-butyl, and hydrogen in the presence of a supported catalyst which comprises from 0.05 to 50% by weight of copper chromite, copper, silver, gold, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum or mixtures thereof, in the presence or absence of water at from 20 DEG to 200 DEG C. under from 1 to 300 bar.

公开(公告)号：AU3168797A

公开(公告)日：1998-01-05

申请号：AU3168797

申请日：1997-05-28

Applicant: BASF AG

Inventor： JULIUS MANFRED ,  RUST HARALD ,  KRAUSE ALFRED ,  SIEGEL HARDO ,  SIEGEL WOLFGANG ,  WITZEL TOM

IPC: C07B63/04 ,  C07D211/58 ,  C07D211/72 ,  C07D221/20 ,  C08K5/3435

Abstract: PCT No. PCT/EP97/02763 Sec. 371 Date Nov. 12, 1998 Sec. 102(e) Date Nov. 12, 1998 PCT Filed May 28, 1997 PCT Pub. No. WO97/46528 PCT Pub. Date Dec. 11, 1997The invention relates to a process for reducing the dimerization of piperidines of the formula I where R1 to R4 are C1- to C6-alkyl, R1 and R2 and/or R3 and R4 together are a CH2 chain having 2 to 5 carbon atoms, which comprises adding to the piperidine from 0.001 to 0.2% by weight of a reducing agent of the formula MXH4-mYm, where M is an alkali metal, NR4, where R are identical or different C1-C4-alkyl groups, or an equivalent of an alkaline earth metal or an equivalent of zinc, X is boron or aluminum, Y is H or CN and m is 0 or 1. The invention also relates to a mixture of piperidines of the formula I, from 0.001 to 0.2% by weight of a reducing agent and from 1 to 1000 ppm of dimers of the piperidines of the formula I, and to the preparation of hindered amine light stabilizers therefrom.

公开(公告)号：BR9510133A

公开(公告)日：1997-12-30

申请号：BR9510133

申请日：1995-12-22

Applicant: BASF AG

Inventor： ACHHAMMER GUNTHER ,  BASSLER PETER ,  FISCHER ROLF ,  FUCHS EBERHARD ,  LUYKEN HERMANN ,  SCHNURR WERNER ,  WITZEL TOM

IPC: C07D201/02 ,  C07C209/48 ,  C07C211/12 ,  C07D201/08 ,  C07D223/10

Abstract: The invention concerns the simultaneous preparation of caprolactam and hexamethylene diamine from adipodinitrile, by the following steps: (a) the adipodinitrile is partially hydrogenated, producing a mixture substantially containing 6-aminocapronitrile, hexamethylene diamine, ammonia, adipodinitrile and hexamethylene imine (= "the mixture"); (b) the mixture obtained in step (a) is distilled, producing ammonia, as the forerunnings, and a residue I, in the presence of a compound A which is inert in the distillation conditions, the ammonia not being separated totally; (c) the residue I, substantially containing "the mixture", inert compound A and ammonia, the ammonia content being less than that of the mixture used in step (b), is subjected to a second distillation, producing a mixture of the inert compound A and ammonia, as the forerunnings, and a residue II; (d) the base II, substantially containing "the mixture" and inert compound A, is subjected to distillation in a third column, producing the inert compound A, as the forerunnings, and a residue III; (e) the base III, substantially containing "the mixture" and optionally an inert compound B, is subjected to distillation in a fourth column, producing forerunnings KP1, which substantially contain hexamethylene imine, optionally inert compound B and hexamethylene diamine, and a residue IV; (f) the forerunnings KP1 are subjected in a fifth column to distillation, producing forerunnings KP2, which substantially contain hexamethylene imine and optionally inert compound B, and a residue V, which substantially contains hexamethylene diamine with a degree of purity of at least 95 %, the forerunnings KP2 being fed to the third column or optionally only partially fed to the third column, and the rest being discarded; and (g) the residue IV, substantially containing 6-aminocapronitrile and adipodinitrile, is subjected in a sixth column to distillation, producing 6-aminocapronitrile with a degree of purity of at least 95 %, as forerunnings, and adiponitrile in the residue. The resultant 6-aminocapronitrile is cyclized to form caprolactam.

公开(公告)号：NO975268L

公开(公告)日：1997-11-17

申请号：NO975268

申请日：1997-11-17

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM ,  FLICK KLEMENS

IPC: C07D201/08

Abstract: Production of cyclic lactams by the reaction of amino carboxylic acid nitriles with water, performed in the liquid phase in the presence of heterogeneous catalysts based on titanium dioxide with a rutile content in the range from 0.1 to 95 wt.% and an anatase content in the range from 99.9 to 5 wt.% in relation to the total titanium dioxide content.

公开(公告)号：BR9408099A

公开(公告)日：1997-08-05

申请号：BR9408099

申请日：1994-11-15

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM

IPC: C07D223/10 ,  C07D201/08

Abstract: PCT No. PCT/EP94/03782 Sec. 371 Date May 16, 1996 Sec. 102(e) Date May 16, 1996 PCT Filed Nov. 15, 1994 PCT Pub. No. WO95/14665 PCT Pub. Date Jun. 1, 1995Cyclic lactams are prepared by reacting amino carbonitriles with water in liquid phase in a fixed bed reactor in the presence of heterogeneous catalysts which have no soluble constituents under the reaction conditions.

公开(公告)号：FI972762A

公开(公告)日：1997-06-26

申请号：FI972762

申请日：1997-06-26

Applicant: BASF AG

Inventor： MELDER JOHANN-PETER ,  SCHNURR WERNER ,  FLICK KLEMENS ,  EBEL KLAUS ,  WITZEL TOM ,  FISCHER ROLF ,  HARDER WOLFGANG ,  REHFINGER ALWIN

IPC: B01J23/76 ,  B01J23/89 ,  B01J23/889 ,  B01J27/18 ,  B01J37/02 ,  C07B61/00 ,  C07C253/30 ,  C07C255/24 ,  C07C

Abstract: Aliphatic alpha,omega-aminonitriles are prepared by partial hydrogenation of aliphatic alpha,omega-dinitriles at elevated temperatures and superatmospheric pressure in the presence of a solvent and of a catalyst by a process which comprises using a catalyst which (a) contains a compound based on a metal selected from the group consisting of nickel, cobalt, iron, ruthenium and rhodium and (b) contains from 0.01 to 25% by weight, based on (a), of a promoter based on a metal selected from the group consisting of palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, zinc, cadmium, lead, aluminum, tin, phosphorus, arsenic, antimony, bismuth and rare earth metals and (c) from 0 to 5% by weight, based on (a), of a compound based on an alkali metal or on an alkaline earth metal. with the proviso that the component (a) is not based on iron or iron and one of the metals selected from the group consisting of cobalt, ruthenium and rhodium when (b) is a promoter based on a metal selected from the group consisting of titanium, manganese, chromium and molybdenum, and with the further proviso that, when a compound based on only ruthenium or rhodium or ruthenium and rhodium or nickel and rhodium is selected as component (a), the promoter (b) may be dispensed with.