67.
    发明专利
    未知

    公开(公告)号:DE58901691D1

    公开(公告)日:1992-07-23

    申请号:DE58901691

    申请日:1989-09-04

    Applicant: DEGUSSA

    Abstract: Aluminium oxide which is amorphous according to X-ray diffraction, has an extremely high water content and has a specific surface area (BET) in accordance with DIN 66 131 of > 10 m /g, a mean particle size of >/= 0.1 mu m and a water content of > 10% gives, through calcination, an aluminium oxide which comprises >/= 90% by weight of alpha -aluminium oxide and has a specific surface area (BET) in accordance with DIN 66 131 of > 5 m /g and a mean particle size of >/= 0.1 mu m. … The aluminium oxide which is amorphous according to X-ray diffraction can be prepared by reacting steam and vapour-form aluminium trichloride in a molar ratio of 1.5 to 10:1, preferably 7 +/- 1 : 1 = H2O : AlCl3 at a temperature of 200 to 1000 DEG C, preferably 600 +/- 50 DEG C, and at a resonance time of > 1 second, preferably 3.5 +/- 1 second, and at a pressure of 100 +/- 10 mm water column.

    69.
    发明专利
    未知

    公开(公告)号:DE3866677D1

    公开(公告)日:1992-01-16

    申请号:DE3866677

    申请日:1988-10-08

    Applicant: DEGUSSA

    Abstract: A novel crystalline zirconium oxide powder has a BET specific surface of less than 30 (pref. 10-20) sq.m./g., a primary particle size of 0.1-0.5 microns, a monoclinic crystal structure and opt. a content of 1-10 wt. % Y2O3 and/or 1-10 wt. % MqO. Prodn. of the powder involves addinq an aq. Zr salt soln., opt. contg. Y and/or Mq ions, with stirrinq to an aq. base soln., e.q. caustic soda with an NaOH excess correspondinq to 0.5 mol/lNaOH, hydrothermally treating the reaction mixt. at 200-400 deg. C, filtering off the resulting product, water washinq free of chloride and drying at 10O-120 deg. C.

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